The Ideal Gas equation | A level Chemistry

The Chemistry Tutor
8 Jun 202024:21

Summary

TLDRThis chemistry video tutorial delves into the ideal gas equation, a fundamental concept in A-Level chemistry. It explains the equation's derivation through everyday examples like party balloons, illustrating how gas behavior relates to temperature (Charles's Law), pressure (Boyle's Law), and the number of gas molecules. The video meticulously covers unit conversions crucial for using the equation correctly, such as converting Pascals, cubic meters, and Kelvin. It also guides through solving practical problems using the ideal gas equation, including calculating moles of gas and applying it to chemical reactions, ensuring a comprehensive understanding of this essential chemistry topic.

Takeaways

  • 🎈 The ideal gas equation, PV=nRT, is derived from observing how gases behave under different conditions, such as temperature and pressure changes.
  • 🔍 Charles's Law states that the volume of a gas is directly proportional to its temperature (V∝T).
  • 📉 Boyle's Law indicates that the pressure of a gas is inversely proportional to its volume (P∝1/V) when temperature is constant.
  • 🌡️ The number of moles of a gas is directly proportional to the volume it occupies, which is a fundamental concept in the ideal gas law.
  • 📐 The ideal gas equation is applicable to all gases under ideal conditions, regardless of the type of gas.
  • ⚖️ The units for the ideal gas equation are crucial: pressure (Pascals), volume (cubic meters), moles (moles), temperature (Kelvin), and the gas constant (8.31 J/K/mol).
  • 🔄 Understanding unit conversions is vital for correctly applying the ideal gas equation, especially between Kelvin and Celsius, and cubic meters with other volume units.
  • 🔢 The ideal gas equation can be rearranged to solve for different variables, such as pressure, volume, or the number of moles.
  • 🧪 Practical applications of the ideal gas equation include calculating moles of gases in reactions, determining temperatures in chemical processes, and finding the molar mass of volatile liquids.
  • 🔄 The ideal gas equation can be combined with chemical equations to perform stoichiometric calculations and find the amounts of reactants or products in chemical reactions.

Q & A

  • What is the ideal gas equation?

    -The ideal gas equation is PV = nRT, where P is the pressure, V is the volume, n is the number of moles of gas, R is the gas constant, and T is the temperature in Kelvin.

  • What is Charles's law as mentioned in the script?

    -Charles's law states that the volume of a gas is proportional to its temperature, when the pressure is held constant.

  • What is Boyle's law and how does it relate to the volume of a gas?

    -Boyle's law states that the pressure of a gas is inversely proportional to its volume, provided the temperature and the amount of gas remain constant.

  • How does the number of moles of gas affect its volume according to the script?

    -The volume of a gas is directly proportional to the number of moles of gas it contains, assuming the temperature and pressure are constant.

  • What does the ideal gas equation assume about the behavior of gases?

    -The ideal gas equation assumes that all gases behave in the same ideal way, regardless of their composition, obeying the rules of direct or inverse proportionality with volume, pressure, and temperature.

  • What is the value of the gas constant R in the ideal gas equation?

    -The gas constant R in the ideal gas equation is 8.31 joules per Kelvin per mole.

  • How can you convert pressure from kilopascals to pascals?

    -To convert pressure from kilopascals to pascals, you multiply by 1,000 (since 1 kilopascal is equal to 1,000 pascals).

  • What is the Kelvin temperature scale and how does it relate to the Celsius scale?

    -The Kelvin scale is a temperature scale that starts at absolute zero (0 K) and increases by the same amount as the Celsius scale. To convert Celsius to Kelvin, you add 273.15.

  • How do you convert cubic centimeters to cubic meters?

    -To convert cubic centimeters to cubic meters, you divide by one million, because one cubic meter is equal to one million cubic centimeters.

  • What is the significance of the units used in the ideal gas equation?

    -The units used in the ideal gas equation (Pascals for pressure, cubic meters for volume, Kelvin for temperature) are significant because they ensure the equation's balance and allow for accurate calculations of gas properties.

  • How can the ideal gas equation be rearranged to solve for different variables?

    -The ideal gas equation can be rearranged algebraically to solve for different variables such as pressure (P = nRT/V), volume (V = nRT/P), temperature (T = PV/nR), and the number of moles (n = PV/RT).

Outlines

00:00

🎈 Introduction to the Ideal Gas Equation

This paragraph introduces the Ideal Gas Equation, a fundamental concept in A-Level Chemistry, specifically in the chapter on the amount of substance. The origin of the equation is explained through a relatable example involving party balloons and their behavior under different conditions. The script discusses how balloons expand in warm environments due to increased temperature (Charles's Law), contract when cooled (inversely related to volume), and increase in volume when more gas is added (directly related to the number of moles). These observations lead to the formulation of the Ideal Gas Equation: PV=nRT, where P is pressure, V is volume, n is the number of moles, R is the gas constant, and T is temperature in Kelvin. The importance of memorizing this equation for exams is emphasized, along with understanding the units for each variable.

05:02

🔍 Understanding Units in the Ideal Gas Equation

This section delves into the units used in the Ideal Gas Equation, focusing on pressure in Pascals (Pa), volume in cubic meters (m³), and temperature in Kelvin (K). The script clarifies common unit conversions, such as kiloPascals to Pascals and the conversion between Celsius and Kelvin scales. It also addresses the less familiar unit of volume, cubic meters, and provides conversions to more commonly used units like cubic centimeters and cubic decimeters. The goal is to ensure that students can comfortably work with the units required for the Ideal Gas Equation in various exam scenarios.

10:05

🧪 Manipulating the Ideal Gas Equation

The script explains how to manipulate the Ideal Gas Equation to solve for different variables, such as pressure, volume, or the number of moles. It emphasizes the importance of rearranging the equation to isolate the desired variable and then substituting the known values. The process involves converting all quantities to their SI units before solving. An example calculation for the number of moles of oxygen gas is provided, demonstrating the step-by-step approach, including unit conversions and the final calculation.

15:06

🔬 Applications of the Ideal Gas Equation

This part of the script explores practical applications of the Ideal Gas Equation, such as determining the molar mass (M R) of a volatile liquid. The process involves measuring the volume of gas produced when a liquid evaporates and the mass loss of the liquid container. The Ideal Gas Equation is used to calculate the number of moles of the gas, which then allows for the calculation of the M R. The script also discusses how the Ideal Gas Equation can be combined with chemical equations to perform stoichiometric calculations, such as determining the number of moles of reactants or products based on the gas laws.

20:09

📚 Advanced Problems Using the Ideal Gas Equation

The final paragraph presents more complex problems that involve using the Ideal Gas Equation to find the volume of gases produced in chemical reactions. It covers scenarios where the reaction conditions (temperature and pressure) are given, and the task is to calculate the volume of gas produced from a known mass of a reactant. The script demonstrates how to use the Ideal Gas Equation to find the number of moles of a gas, and then how to use stoichiometry to find the volume of another gas in the reaction. This section showcases the application of the Ideal Gas Equation in solving multi-step chemical problems.

Mindmap

Keywords

💡Ideal Gas Equation

The Ideal Gas Equation is a fundamental concept in chemistry that describes the behavior of an ideal gas. It is represented as PV=nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin. The video uses this equation to explain how gases behave under different conditions, such as changes in temperature and pressure. The Ideal Gas Equation is central to the video's theme as it serves as the basis for understanding gas behavior.

💡Charles's Law

Charles's Law states that the volume of a gas is proportional to its temperature, provided the pressure and the amount of gas are held constant. This law is named after Jacques Charles and is demonstrated in the video through the example of balloons expanding in a warm environment and shrinking in a cold one. It is a key component of the Ideal Gas Equation and helps to establish the relationship between temperature and volume.

💡Boyle's Law

Boyle's Law explains the inverse relationship between the pressure and volume of a gas when the temperature and the amount of gas are constant. If the pressure increases, the volume decreases, and vice versa. The video illustrates this by squeezing a balloon, showing that applying pressure reduces its volume. This law is essential for understanding how pressure affects the size of a gas container.

💡Moles

Moles are a measure used in chemistry to express quantities of a chemical substance, defined as the number of particles in a substance divided by the number of particles in 12 grams of carbon-12. In the context of the video, the number of moles (n) is a variable in the Ideal Gas Equation and is directly proportional to the volume of a gas. The video uses the concept of adding more air to a balloon to explain how an increase in moles leads to an increase in volume.

💡Pascal

Pascal is the SI unit of pressure, named after the French mathematician and physicist Blaise Pascal. The video mentions Pascal in the context of expressing pressure measurements in the Ideal Gas Equation. It also discusses the conversion between different units of pressure, such as kilopascals to pascals, which is important for using the Ideal Gas Equation correctly in calculations.

💡Kelvin

Kelvin is the base unit of temperature in the International System of Units (SI) and is one of the seven base units. The video explains that temperature in the Ideal Gas Equation must be expressed in Kelvin, not in degrees Celsius. It provides a method for converting degrees Celsius to Kelvin by adding 273, which is crucial for accurately using the Ideal Gas Equation.

💡Gas Constant (R)

The Gas Constant (R) is a fundamental constant in the kinetic theory of gases, commonly used in the Ideal Gas Law. It is the same for all gases and has a value of 8.314 J/(mol·K). The video emphasizes the importance of remembering this constant for solving problems using the Ideal Gas Equation, as it relates the energy of a gas to its temperature and the amount of substance.

💡Unit Conversions

Unit Conversions are discussed in the video as an essential skill when working with the Ideal Gas Equation. The video provides examples of converting pressure from kilopascals to pascals and volume from cubic centimeters to cubic meters. Understanding these conversions is necessary for ensuring that all variables in the equation are expressed in the correct SI units.

💡Volume

Volume in the context of the video refers to the amount of space occupied by a gas, which is a variable in the Ideal Gas Equation. The video explains that volume is typically measured in cubic meters and provides conversions to other units like cubic centimeters. The concept is used to demonstrate how the volume of a gas changes with temperature and pressure.

💡Molar Mass

Molar Mass is the mass of one mole of a substance and is used in the video to calculate the number of moles of a gas. It is an important concept when relating mass to the number of moles using the Ideal Gas Equation. The video demonstrates how to use the molar mass to find the moles of a gas, which is then used to calculate other properties like volume.

💡Chemical Reactions

Chemical Reactions are discussed in the video in relation to how they can be analyzed using the Ideal Gas Equation. The video provides an example of octane burning in air to produce carbon dioxide and water, and how to calculate the number of moles of carbon dioxide produced. This illustrates how the Ideal Gas Equation can be applied to real-world chemical processes.

Highlights

Introduction to the ideal gas equation in A-Level Chemistry

Explaining the origin of the ideal gas equation using party balloons

Charles's law: Volume of a gas is proportional to temperature

Boyle's law: Pressure is inversely proportional to volume

Volume is proportional to the number of moles of gas

Combining relationships to form the ideal gas equation PV=NRT

Importance of remembering the ideal gas equation for exams

Units for each quantity in the ideal gas equation

Conversion of pressure units from kilopascals to pascals

Understanding Kelvin scale and its conversion from Celsius

Volume units in cubic meters and their conversions

Rearrange the ideal gas equation to solve for different variables

Calculating the number of moles of oxygen gas using the ideal gas equation

Determining the temperature in degrees Celsius using the ideal gas equation

Using the ideal gas equation to find the molar mass of a volatile liquid

Combining the ideal gas equation with chemical equations for combustion reactions

Calculating the total volume of gas produced from a cracking reaction

Transcripts

play00:00

hello everybody and welcome to this a

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level chemistry video about the ideal

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gas equation this is one of these sub

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topics in the amount of substance

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chapter 4 a level chemistry and in this

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video we'll look briefly at the origin

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of the ideal gas equation we'll look in

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depth at how you use the ideal gas

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equation including unit conversions and

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then we'll finish by looking at how we

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can work with gases in equations

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including a couple of questions to that

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effect the origin of the ideal gas

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equation can be explained using a simple

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example of party balloons if we take a

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number of identical party balloons with

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an identical number of molecules of air

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inside them we can subject these

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balloons to different conditions and see

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how they behave and their behavior

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allows us to come up with some

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scientific rules that form the ideal gas

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equation first of all if we place a

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party balloon in a warm environment say

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a boiler cupboard then the party

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balloons will expand and then they might

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pop you can see this same effect if

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people have put party balloons outside

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their house for somebody's birthday and

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it's a hot day and the balloons will pop

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in the same way but the opposite way

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around if you took a party balloon and

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put it inside a freezer that party

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balloon would shrivel up maybe not go

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shrivel down to nothing but it would

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definitely get smaller and what this

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allows us to realize is that the volume

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of space a gas occupies the gas inside

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the balloon is proportional to the

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temperature of those gasses so the

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volume V is proportional to the

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temperature T and this is actually known

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as Charles's law after one of the

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scientists who did a lot of work in this

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area if we took another party balloon

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and we just simply squeezed it as we've

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all done probably when we were younger

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we can say that that party balloon

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assuming that we're squeezing it and

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stopping it moving out from between our

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fingers

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that party balloons actually going to

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get smaller and what that means is that

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the pressure that we exert on gases is

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influencing the volume and the pressure

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is inversely proportional to the volume

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what that means is if we increase the

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pressure the volume gets smaller and so

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this is Boyle's law pressure is

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inversely proportional to the volume and

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then last of all if we were to carefully

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undo the knot in the balloon and breathe

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out more air into that balloon we would

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find that the balloon of course would

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get larger the volume would increase and

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what that means is we've put more

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molecules of gas into the balloon more

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moles and so the volume of that balloon

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is increasing because volume is

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proportional to the number of moles of

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gas inside the balloon and this these

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three relationships that we've got here

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on the slide that combine together to

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give us the ideal gas equation and it's

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called the ideal gas equation because

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all gases are assumed to behave in this

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same ideal way regardless of whether

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they're carbon dioxide or oxygen or

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nitrogen they all obey these rules where

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their volume is proportional to a number

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of different factors so this is the

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ideal gas equation PV equals NRT it's

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got quite a nice rhythm to it when you

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say it like that you need to remember

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this so you can use it in exam questions

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because it won't be given to you and

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you'll get a mark for remembering it not

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only do you need to remember it you need

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to be able to understand it and use it

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including understanding the units for

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each of these quantities so P is

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pressure and that's measured in Pascal's

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and Pascal's is the international symbol

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international unit for pressure V is

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volume measured in cubic meters n stands

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the number of moles T is the temperature

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measured in Kelvin which has got a

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symbol K and last of all R is the gas

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constant and it's got a number 8.31

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joules per Kelvin per mole and you need

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to remember those numbers 8.31 because

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that is a constant which means that

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whatever the gas is it will always have

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that many joules of energy per Kelvin

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per mole that means if you've got one

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mole of a substance at 20 Kelvin it will

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have 8.31 times by 20 that's how much

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energy that gas will have let's move

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back to the units Pascal's cubic meters

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and kelvins probably not units that we

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use frequently so let's have a look at

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each of those now let's start with our

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units by looking at pressure in Pascal's

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in exam questions they like to try and

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trip you up by giving you the units in

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something that is not the SI form not

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the standard way of giving it to you so

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they might give it to you in kiloPascals

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and if that's the case well that's

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really lovely because they might give

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you a pressure of 3 kilo Pascal's which

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to convert into Pascal's you simply

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multiply by a thousand in the same way

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that three thousand grams is three

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kilograms or three kilograms is three

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thousand grams so that's nice

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atmospheric pressure is taken to be 101

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kiloPascals so they might talk to you

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about atmospheric pressure that would be

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a bit mean expecting you to remember 101

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kiloPascals but that is atmospheric

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pressure sometimes approximated to 100

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kilo Pascal's so to convert killer

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Pascal's into Pascal's you just simply

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multiply by 1,000 now temperature

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temperature is in Kelvin and that is an

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entirely new temperature scale named

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after a scientist Lord Kelvin who

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all sorts of crazy experiments in his

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country house but essentially the Kelvin

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scale is a recalibrated degrees Celsius

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scale that starts at zero you might have

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wondered why we have a temperature scale

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that goes negative wouldn't it be easier

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if we have one that starts at zero and

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that's what the Kelvin scale does it

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starts at zero and that is referred to

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as absolute zero that is as cold as it

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is theoretically possible to get we've

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got below 1 Kelvin

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I believe but never down to zero it's a

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theoretical temperature now the good

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news for you and your exams is it's not

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a really tricky conversion to work

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between degrees Celsius and Kelvin zero

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degrees Kelvin is minus 273 degrees

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Celsius 20 Kelvin is minus 253 degrees

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Celsius so you can see that what we're

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doing is we're adding 273 on to the

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degree Celsius scale to get us into our

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kelvin scale so zero degrees Celsius is

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273 Kelvin 50 Celsius is 323 Kelvin and

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so the scale is nice that's plus 273 or

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minus 273 depending on which way you're

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converting most likely you'll be adding

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273 to convert into Kelvin but what's

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really nice is that that increase of one

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degree Celsius from say 50 to 51 is the

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same as one Kelvin from three to three

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to three to four so these first two

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conversions aren't too bad let's take a

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look at volume volume is usually taken

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to be the trickiest one now the units of

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volume for the ideal gas equation are in

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meters cubed and a cubic metre is

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actually really quite big and the reason

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that we have these big volumes is

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because gases occupy a lot of space now

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you can just accept that the volume is

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in cubic meters and you can also accept

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the conversions so I'll start with the

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conversions to convert to be centimeters

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which is quite common through given a

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volume in cubic centimeters into cubic

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meters you divide by a million and

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that's because a cubic centimeter is

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tiny compared to a cubic meter so a

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beaker that holds 500 cubic centimeters

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of volume would actually only be 5 times

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10 to the minus 4 cubic meters with the

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volume so centimeters cubed 2 meters

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cubed you divide by a million and then

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centimeters cubed to decimeters cubed

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you divide by 1,000 the origin of that

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can be explained using cubes here we've

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got a cube which I will take to be one

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meter by one meter by one meter so that

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is one cubic meter now a decimeter is

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1/10 of a meter so this 1 meter

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dimension here is actually 10 decimeters

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and so is this one and so it's this one

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so the volume is 10 by 10 by 10 which is

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1,000 cubic decimeters so one cubic

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meter is 1000 cubic decimeters but we

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also know that one meter is 100

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centimeters so this dimension could also

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be referred to as 100 centimeters and

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this one 100 centimeters of this one 100

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centimeters as well so the volume in

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cubic centimeters we is 100 times 100

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times 100 so a million and that's the

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origin of these conversions cm cubed 2

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meters cubed we multiply by 10 to the

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minus 6 or divide by a million DM cubed

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into meters cubed we divide by a

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thousand and it's the opposite going the

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other way

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so those are the really important

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conversions to remember let's get back

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to the ideal gas equation itself PV

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equals NRT and let's explore the

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different forms of this equation because

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you might be asked to work out P and

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then you need to have an equation where

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P equals something so you might prefer

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to write that equation and then

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substitute numbers into it and then

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rearrange numbers people often find that

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easier and so that would be possibly

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what I recommend remember what the units

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are

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then alternatively you could use algebra

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as your method so PV equals NRT if I've

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been asked to work out what P is I need

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to divide both sides of this equation by

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V and then the V's on the left hand side

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cancel out and we're left with NRT

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divided by V and making V the subjects

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of the equation works in the exact same

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way however if we wanted to work out a

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number of moles we would need to divide

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both sides of the equation by RT and

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then the RT would cancel on the right

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hand side and would be left with PV

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divided by RT equals N and so that's the

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rearranging of the ideal gas equation

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either by subbing the numbers in at the

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beginning or by doing the algebraic

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method so let's take a look at a couple

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of questions here how many moles are

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there in 0.050 cubic meters of oxygen

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gas at a temperature of 450 Kelvin and

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60,000 Pascal's so the first thing that

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I recommend you do is you write the

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ideal gas equation out PV equals NRT you

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rearrange it to make n the subject N

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equals PV over RT and then you write the

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quantities V equals T equals P equals

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and then you do the conversions because

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getting into this routine like this

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encourages you to remember to do the

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conversions and if you make a slip-up

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you're more likely to get method marks

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when you say use the wrong volume later

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that you've shown that you think it's

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the volume whereas if you just use the

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wrong volume later without saying what

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it is that you're doing you're less

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likely to get method marks so convert

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each of those quantities like this now

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on this occasion no conversions are

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necessary because all of the units are

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in the correct form but it's a really

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good habit to force yourself into then

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plug those numbers into the equation you

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get your answer and don't forget to put

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the unit's in and in this second

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question

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what was the temperature in degree C of

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a gas that has got a pressure of 110,000

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Pascal's 0.4 moles of gas occupying a

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volume of 1600 cubic centimeters so

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again my suggestion is that you write

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the ideal gas equation this time with T

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as a subject so T equals PV divided by n

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R we write down our quantities and then

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we take a moment to look at the units

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and this time we find out that the

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volume is not in the SI units that we

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need it's in cubic centimeters so we

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need to divide that by a million and get

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the correct number of meters cubed so

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dividing 1600 by a million we get one

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point six times ten to the minus three

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cubic meters and so we plug those

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numbers into the equation and we get a

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temperature now we should note I said

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before don't forget to put the unit's

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the temperature units are in Kelvin but

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this question asked for the temperature

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in degrees Celsius so our value in

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Kelvin remember is 273 bigger than our

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value in degree C would be so we need to

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subtract 273 off this to get our

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temperature in degrees C so this is our

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answer here another application of the

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ideal gas equation is that you can use

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it to find the M R of a volatile liquid

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and to do this what you have is you have

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a canister that contains the volatile

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liquid and you inject some of it through

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a syringe into a second chamber and the

play15:09

second chamber is inside an oven and

play15:11

volatile means it turns into a gas

play15:14

easily and so once the liquid has moved

play15:16

into the oven it will evaporate and

play15:19

become a gas and so we can measure the

play15:23

volume of gas that is produced in this

play15:27

chamber and we can take a look at what

play15:31

the mass has dropped by from this

play15:34

canister

play15:34

so if the canister lost a certain mass

play15:38

we will know that that canisters mass

play15:41

loss is all to do with the fact that the

play15:43

liquid left through the syringe and into

play15:46

the oven and then it became a gas whose

play15:49

volume we measured so let's say that we

play15:53

collected 1,000 cubic centimeters of gas

play15:57

inside the oven and that the mass of the

play16:00

canister began at 30 point-0 grams but

play16:03

then it dropped and it dropped down to

play16:06

twenty-five point four two grams and so

play16:09

we can work out what mass has been

play16:13

injected and that mass is four point

play16:16

five eight grams and that four point

play16:20

five eight grams of the liquid has got a

play16:23

volume once vaporized of one thousand

play16:26

cubic centimeters so the first thing

play16:28

that we need to do to work out what the

play16:30

M R is is to work out how we're going to

play16:31

calculate the M R at the end

play16:33

and since moles equals mass over M R

play16:37

that means that M R is mass over moles

play16:41

and so the final calculation that we're

play16:43

going to do is mass divided by moles to

play16:45

work out what the mr is and so that

play16:48

means that the previous step must be to

play16:50

work out what the moles is because we

play16:52

know what mass has been lost four point

play16:54

five eight grams but we don't know the

play16:56

moles and so we need to use the ideal

play16:58

gas equation to work out the moles so

play17:00

that's in the form n equals PV divided

play17:03

by RT we've got our volume of one

play17:06

thousand centimeters cubed we need to

play17:09

convert that into meters cubed by

play17:12

dividing by a million and we need to

play17:15

take the temperature of the oven and

play17:18

that is at only forty four degrees C and

play17:24

so 44 degrees C we need to convert that

play17:27

into Kelvin by adding 273 on to it and

play17:34

then the pressure is 101 kiloPascals

play17:37

which we then multiply by a thousand to

play17:40

get one hundred and one thousand

play17:42

Pascal's we plug those numbers into the

play17:45

equation

play17:45

remembering the value for R is eight

play17:47

point three

play17:48

and we get a value for our moles we then

play17:52

take this value of moles and we put it

play17:54

into the equation down here and we

play17:56

divide our 4.5 eight grams by the moles

play17:59

we've just calculated and we get our M R

play18:02

value you don't normally need to use the

play18:06

units of M R grams per mole but I like

play18:09

to put it in because I think it helps

play18:11

give em our more meaning we're going to

play18:15

finish this video by taking a look at

play18:17

how we can combine the ideal gas

play18:19

equation with other calculations and

play18:22

with other chemical equations so we've

play18:26

got a situation here where octane a

play18:28

hydrocarbon with a molecular formula

play18:29

c8h18 burns completely in air to give

play18:32

water and carbon dioxide

play18:34

there's the chemical equation for it

play18:37

here we can see the numbers in the

play18:39

equation nine eight one and one and then

play18:44

we've been given some data a sample of

play18:46

octane burns completely in air the

play18:49

carbon dioxide produced occupies a

play18:51

volume of twenty thousand cubic

play18:53

centimeters and has a temperature of 55

play18:56

degrees C and 101 kiloPascals of

play19:00

pressure we have to calculate the number

play19:01

of moles of carbon dioxide present to do

play19:05

this we need to use the ideal gas

play19:06

equation PV equals NRT we're going to

play19:09

rearrange it in the form n equals PV

play19:12

divided by RT in our data volume is

play19:18

twenty thousand cubic centimeters which

play19:20

we need to divide by a million to get

play19:23

into cubic meters so 0.020

play19:27

cubic meters the temperature is 55

play19:31

degrees Celsius which we need to add on

play19:34

to 73 to get 328 Kelvin and last of all

play19:41

the pressure is 101 kiloPascals and we

play19:46

just simply need to multiply that by

play19:49

1,000 to get one hundred and one

play19:52

thousand Pascal's of pressure and then

play19:55

we need to substitute these values into

play19:57

the calculation and this

play20:01

final answer of 0.074 1 moles of carbon

play20:08

dioxide and then there's a follow-up

play20:11

question asks us to calculate a number

play20:13

of moles of octane burnt and if we look

play20:16

at the chemical equation the ratio of

play20:18

octane to carbon dioxide is 1 octane for

play20:22

8 carbon dioxide and so to convert the

play20:26

moles of carbon dioxide into moles of

play20:27

octane which is what we need to do we

play20:29

need to divide it by 8 so our answer

play20:32

from the previous question needs to be

play20:34

divided by 8 and when we do that we get

play20:37

9 point 2 6 times 10 to the minus 3

play20:41

moles of octane and so you can use the

play20:46

coefficients in the equation those

play20:48

multipliers to work with moles without

play20:51

having to use moles mass and M are you

play20:53

just simply use their proportions from

play20:56

the multiples in the equation okay we'll

play21:00

take a look at one last question now a

play21:02

sample of decane is cracked to produce

play21:04

butane and ethene as shown in the

play21:07

equation below and we've got decane on

play21:10

the left and we've got butane on the

play21:12

right and three moles of ethene and

play21:16

that's really important that the decane

play21:19

produces one mole of butane and three

play21:23

moles of ici now the reaction is carried

play21:26

out it's 550 degrees Celsius that's T

play21:28

and 200 kilo Pascal's so there is P and

play21:31

our command is if eleven point six grams

play21:34

of butane are produced what is the total

play21:37

volume of gas in cubic centimeters

play21:38

that's so important let's highlight that

play21:41

now what we need to do first is we need

play21:44

to go PV equals NRT our final answer

play21:49

needs to be for the volume so V equals

play21:52

NRT divided by P which means that we

play21:55

need to know n RT and P so n is the

play22:00

number of moles we actually don't have

play22:01

that yet so that's going to be something

play22:03

we're going to need to calculate using

play22:05

the mass R we know is eight point three

play22:08

one might give it to you

play22:09

they might not temperature is 550

play22:12

degrees Celsius which is

play22:15

823 Kelvin remember we need to add 273 P

play22:20

is 200 kilo Pascal's which is 200,000

play22:26

Pascal's now n is the moles of gas and

play22:30

this is the tricky bit here we've got

play22:34

two gases we've got ething and we've got

play22:37

butane and so what we're going to need

play22:40

to do here is we're going to need to

play22:41

work out the total moles of gas before

play22:45

we need to then work out the total

play22:47

volume of gas and so we've got the mass

play22:51

of butane 11.6 so mass divided by M R is

play22:57

moles of butane and the moles of butane

play23:01

is therefore eleven point six divided by

play23:04

58 which is the M R of butane which

play23:07

gives us an answer of not 0.2 moles so

play23:10

this is how many moles of butane we've

play23:12

got then we need to look up at the

play23:14

equation and the ratio is one to three

play23:17

so we forgot to not point to moles of

play23:19

butane we will have naught point six

play23:22

moles of ethene because it needs to be

play23:25

three times as big and so therefore the

play23:27

total moles is 0.8 and so this now can

play23:32

be plugged in for our value of N and so

play23:35

to finish off we need to calculate not

play23:38

0.8 times by 8.3 1 times by 8 - 3

play23:43

divided by 200,000 which comes out at

play23:49

0.027 for cubic meters and that's not

play23:53

quite our final answer because they

play23:55

asked for it in cubic centimeters so now

play23:58

we need to multiply that by a million

play24:00

and we've got 27,400

play24:03

cubic centimeters and so that's the end

play24:06

of this question we've got our final

play24:08

answer there this would probably be a

play24:11

four or five mark question at the very

play24:12

least ok that's the end of this ideal

play24:16

gas equation run through hope it was

play24:18

useful I'll see you next time

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