Fatty Acids, Glycerol, and Lipids | Biochemistry

Dr Matt & Dr Mike
28 Aug 201905:21

Summary

TLDRDr. Mike's video script delves into the chemistry of fats, or lipids, highlighting their composition of carbon, hydrogen, and a small amount of oxygen. He explains the structure of fatty acids, distinguishing between saturated, monounsaturated, and polyunsaturated types based on the presence and arrangement of hydrogen atoms and double bonds. The script further clarifies how these fatty acids combine with glycerol to form triglycerides, which the body stores as fat for energy, cushioning, or support. The video also touches on the physical properties of fats, such as being solid or liquid at room temperature, depending on their saturation levels.

Takeaways

  • 🧬 Fats, or lipids, are macromolecules composed mainly of carbon, hydrogen, and a small amount of oxygen, unlike carbohydrates where carbon and oxygen are usually in equal amounts.
  • πŸ” Fatty acids are the monomer units of fats, consisting of hydrocarbon chains with varying lengths and types of bonds.
  • πŸ”— Saturated fatty acids have single bonds between all carbon atoms, are linear, and are typically solid at room temperature, like most animal fats.
  • πŸŒ€ Monounsaturated fatty acids have one double bond, causing a kink in the chain, making them liquid at room temperature, like plant oils such as olive oil.
  • 🌐 Polyunsaturated fatty acids have multiple double bonds, leading to more kinks and also being liquid at room temperature.
  • πŸ’§ The body cannot store long fatty acid chains directly, so it combines three fatty acids with a glycerol molecule through a dehydration process to form triglycerides.
  • πŸ”— Triglycerides are the form in which the body stores fats, either for energy or for structural purposes like cushioning and support.
  • 🍫 Cocoa butter is an example of a fat with a mix of saturated, monounsaturated, and polyunsaturated fatty acids, which affects its physical properties.
  • 🌑 The physical state (solid or liquid) of fats at room temperature is influenced by the saturation level of the fatty acids they contain.
  • πŸ”‘ Fatty acids can vary in their attachment to glycerol, leading to different types of fats with distinct properties and functions in the body.

Q & A

  • What are fats also known as in the context of macromolecules?

    -Fats are also known as lipids when discussing macromolecules.

  • What are the basic elements that make up fats?

    -Fats are made up of carbon, hydrogen, and oxygen.

  • How do the molecular structures of fats differ from carbohydrates?

    -While both fats and carbohydrates are composed of carbon, hydrogen, and oxygen, fats predominantly consist of carbon and hydrogen with a very small amount of oxygen, whereas carbohydrates typically have a balance between carbon and oxygen atoms.

  • What is the basic monomer structure of fats called?

    -The basic monomer structure of fats is called a fatty acid.

  • What are the hydrocarbon chains in fatty acids?

    -Hydrocarbon chains in fatty acids are the carbon chains with hydrogen atoms attached to them.

  • What is the difference between saturated and unsaturated fatty acids?

    -Saturated fatty acids have all possible bonds filled with hydrogen atoms, making them straight and solid at room temperature. Unsaturated fatty acids have one or more double bonds, causing kinks in the chain and making them liquid at room temperature.

  • Why are saturated fatty acids typically solid at room temperature?

    -Saturated fatty acids are typically solid at room temperature because their linear structure allows them to stack closely together.

  • What is the role of the carboxyl functional group in fatty acids?

    -The carboxyl functional group in fatty acids contains the oxygen and is attached to the carbon chain, characterizing the fatty acid as an acid.

  • How does the presence of double bonds affect the physical state of fatty acids?

    -The presence of double bonds in unsaturated fatty acids introduces kinks in the hydrocarbon chain, preventing tight packing and resulting in a liquid state at room temperature.

  • What is the process by which the body stores fatty acids?

    -The body stores fatty acids by connecting three fatty acids to a molecule of glycerol through a dehydration process, forming triglycerides.

  • What are triglycerides and how are they related to body fat storage?

    -Triglycerides are compounds formed by three fatty acids attached to a glycerol backbone. They are stored as fat deposits in the body for energy use, cushioning, support, or anchoring organs in place.

  • Why can't the body store fatty acids in their long-chain form?

    -The body cannot store fatty acids in their long-chain form because these chains are too long to be efficiently stored or utilized directly.

Outlines

00:00

🧬 Understanding Fats and Fatty Acids

Dr. Mike introduces fats, also known as lipids, as a type of macromolecule composed of carbon, hydrogen, and oxygen. Unlike carbohydrates, fats have a higher proportion of carbon and hydrogen with less oxygen. He explains the structure of fatty acids, which are the monomers of fats, highlighting their hydrocarbon chains and the presence of a carboxyl group. Three types of fatty acids are discussed: saturated, monounsaturated, and polyunsaturated. Saturated fatty acids have all possible bonds filled with hydrogen, allowing them to stack neatly and be solid at room temperature, typical of animal fats. Monounsaturated fatty acids have a single double bond causing a kink, preventing tight stacking and thus being liquid at room temperature, like in peanut and olive oils. Polyunsaturated fatty acids have multiple double bonds, further disrupting stacking and maintaining a liquid state, even at room temperature. The body cannot store long fatty acid chains directly, so it combines three fatty acids with glycerol through a dehydration process to form triglycerides, which are stored as fat for energy or other functions.

05:00

πŸ”— The Role of Triglycerides in Fat Storage

This paragraph further elaborates on triglycerides, which are formed by the combination of three fatty acids with glycerol. The types of fatty acids that can be attached to glycerol vary, leading to fats that can be solid or liquid at room temperature. An example given is cocoa butter, which contains a mix of saturated, monounsaturated, and polyunsaturated fatty acids. The paragraph concludes by summarizing the discussion on triglycerides, fats, fatty acids, and their role as macromolecules in the body.

Mindmap

Keywords

πŸ’‘Fats

Fats, also known as lipids, are a type of macromolecule primarily composed of carbon, hydrogen, and oxygen. In the script, fats are distinguished from carbohydrates by their higher proportion of carbon and hydrogen atoms relative to oxygen. Fats play a crucial role in the video's theme as they are the main focus of the discussion, with their structure and types being central to understanding their function in the body.

πŸ’‘Macromolecule

A macromolecule refers to a very large molecule, typically formed by the polymerization of smaller subunits. In the context of the video, fats are described as macromolecules, emphasizing their complex structure and the fact that they are made up of smaller units like fatty acids and glycerol.

πŸ’‘Fatty Acids

Fatty acids are the basic monomer structures of fats, consisting of long chains of carbon atoms with hydrogen atoms attached. The video explains that the length of the carbon chain and the type of bonds between carbons differentiate one fatty acid from another. Fatty acids are central to the video's narrative as they are the building blocks of fats and are discussed in relation to their saturation levels.

πŸ’‘Saturated Fatty Acids

Saturated fatty acids are a type of fatty acid where every carbon atom has the maximum number of hydrogen atoms attached to it. The video uses palmitic acid as an example of a saturated fatty acid, explaining that these acids are linear and can stack neatly, making them solid at room temperature. This concept is important for understanding the properties of certain types of fats, such as animal fats.

πŸ’‘Monounsaturated Fatty Acids

Monounsaturated fatty acids have one double bond between carbon atoms, which prevents them from being saturated with hydrogen. The video uses oleic acid as an example, noting that the presence of a double bond introduces a kink in the fatty acid chain. This kink prevents tight packing, resulting in a liquid state at room temperature, which is relevant to understanding plant oils like olive oil.

πŸ’‘Polyunsaturated Fatty Acids

Polyunsaturated fatty acids contain two or more double bonds in their carbon chain. Linoleic acid is given as an example in the video, which has two double bonds. These multiple double bonds introduce more kinks, further preventing the fatty acids from stacking neatly, thus they remain liquid at room temperature. The video emphasizes that these acids are predominantly found in plant oils and are important for health.

πŸ’‘Triglycerides

Triglycerides are formed when three fatty acids are connected to a glycerol molecule through a dehydration process. The video explains that the body stores fats in the form of triglycerides, which can be either solid or liquid at room temperature depending on the types of fatty acids attached. Triglycerides serve as a form of energy storage and are also involved in cushioning and supporting body structures.

πŸ’‘Glycerol

Glycerol, also known as glycerin, is a simple polyol compound with a backbone of three carbon atoms. In the video, glycerol is described as the molecule to which fatty acids attach to form triglycerides. This process is crucial for fat storage in the body, and glycerol plays a central role in the structure of triglycerides.

πŸ’‘Dehydration Process

The dehydration process refers to a chemical reaction where water is removed, leading to the formation of a covalent bond between molecules. In the context of the video, the dehydration process is used to explain how fatty acids and glycerol combine to form triglycerides, which is a key mechanism in fat synthesis within the body.

πŸ’‘Energy Storage

Energy storage in the form of fats is a key concept discussed in the video. Triglycerides, composed of fatty acids and glycerol, serve as an energy reserve that the body can utilize when needed. The video highlights that fats are an efficient form of energy storage due to their high energy density, which is crucial for understanding the body's metabolic processes.

πŸ’‘Cocoa Butter

Cocoa butter is mentioned in the video as an example of a fat that contains a mix of different fatty acids, including saturated and unsaturated ones. This mixture gives cocoa butter its unique properties, such as being solid at room temperature. The discussion of cocoa butter illustrates the variability in fat composition and how it affects the physical state and uses of fats.

Highlights

Fats, also known as lipids, are a type of macromolecule made up of carbons, hydrogens, and oxygens.

Carbohydrates also consist of carbon, hydrogen, and oxygen, but fats have fewer oxygen molecules.

Fatty acids, the monomers of fats, are hydrocarbon chains predominantly made of carbons and hydrogens.

The difference between fatty acids lies in the length of the carbon chain and the types of bonds between the carbons.

Fatty acids have a carboxyl group attached, which contains oxygen.

Saturated fatty acids, like palmitic acid, have all possible carbon bonds filled with hydrogen atoms and are linear in structure.

Saturated fatty acids can stack closely together, making them solid at room temperature, such as in animal fats.

Monounsaturated fatty acids, such as oleic acid, have a double bond between two carbons, creating a kink in the structure.

Monounsaturated fats are liquid at room temperature due to their inability to stack closely, as seen in plant oils like olive oil.

Polyunsaturated fatty acids, like linoleic acid, contain multiple double bonds, adding more kinks and making them liquid at room temperature.

The body stores fatty acids as triglycerides, which are composed of three fatty acids attached to a glycerol molecule.

The dehydration process helps attach fatty acids to glycerol by removing water, forming triglycerides.

Triglycerides are stored for energy use, cushioning, or anchoring organs in place.

Different types of fatty acids can combine with glycerol, affecting whether the fat is solid or liquid at room temperature.

Cocoa butter contains a mix of saturated, monounsaturated, and polyunsaturated fatty acids, demonstrating how diverse fatty acid combinations can affect properties.

Transcripts

play00:02

[Music]

play00:09

hi everyone dr. Mike here let's talk

play00:12

about fats also known as lipids as a

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type of macromolecule okay first thing

play00:17

is that if we have a look at fats

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they're made up of carbons hydrogen's

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and oxygens that's it now I spoke about

play00:24

carbohydrates they also made up of

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carbon hydrogen and oxygen but what

play00:28

you'll find with carbs is that usually

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the amount of carbons are matched by the

play00:32

amount of oxygens now here for fat what

play00:35

you'll find is it's predominantly just

play00:36

carbons and hydrogen's with a very small

play00:39

amount of oxygen molecules attached now

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what you can see is I've drawn up the

play00:43

basic monomer structure so this is the

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smallest subunit of fats that we call

play00:48

fatty acids so I've drawn up three

play00:50

different types of fatty acids here and

play00:52

you can see that they're predominantly

play00:54

carbon chains with a bunch of hydrogen's

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attached to them so we call them

play00:58

hydrocarbon chains now the difference

play01:00

between one fatty acid and another is

play01:02

simply the length of this carbon chain

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and also the types of bonds between each

play01:08

of these carbons I'll talk more about

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that in a second you can say that each

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fatty acid also has this accessory group

play01:15

attached to it

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this functional group which is called a

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carboxyl which you can see contains the

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oxygen so that's all not much oxygen at

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all now what you can see is these three

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different fatty acids the first one I've

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drawn up is up what's called PAL midok

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acid and it's what we call a saturated

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fatty acid now when you've got a

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saturated fatty acid what it means is

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this every single carbon is attached to

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a hydrogen atom that means all the

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possible bonds that a carbon can make

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are going to be filled up by hydrogen

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atoms and you can say that all the way

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across now a saturated fatty acid you

play01:54

can see is linear it's straight and that

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means that if you have multiple fatty

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acids that are saturated and linear they

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can stack nicely on top of each other

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that means they are solid at room

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temperature because they stack nicely

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closely together it means that they are

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solid and they're solid at room

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temperature so this include

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most of the animal fats are saturated

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fats and as we move down you can see

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something called a mono unsaturated

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fatty acid the one I've drawn up here is

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a lake acid and you can see that it's

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very similar to the paramedic saturated

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acid except there's one difference that

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there is a double bond between two

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carbons now this double bond means that

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the carbon is not saturated with

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hydrogen ions and because there's only

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one double bond we call it a mono

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unsaturated fatty acid and what this

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double bond does as you can see it puts

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a kink in that fatty acid and that means

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that if you were to get multiple mono

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unsaturated fatty acids and stack them

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on top of each other they don't actually

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stack nice and tight because of these

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kinks present now this means that they

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are liquid at room temperature and what

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you'll find is these monounsaturated

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fatty acids are predominately plant oils

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so this includes peanut oils and olive

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oils as well again liquid at room

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temperature then we move down to

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something called a polyunsaturated fatty

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acid the one I've drawn up here is

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linoleic acid linoleic acid I should say

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and it's got two double bonds so

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polyunsaturated means many unsaturated

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carbons and you can see two double bonds

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and that puts more of a kink into the

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fatty acid and that means again it's

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going to be liquid at room temperature

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now what you'll find is that our body

play03:36

cannot store fatty acids in this form

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because these carbon chains are far too

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long so what our body does is it takes

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three fatty acids and it connects them

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to a molecule could glycerol and you can

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see glycerol here has three carbons it's

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got eight hydrogen's it's got three

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oxygens and what it does is through a

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dehydration process I spoke about this

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with carbohydrates removes an oxygen

play03:59

removes water in a dehydration process

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we remove these hydrogen's here from the

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glycerol then we remove the O H groups

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from three fatty acids and they click

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together and you can see we've got three

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fatty acids he clicked to a glycerol and

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now what we have is something called

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triglycerides so our body stores fatty

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acids connected to a glycerol backbone

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three of them as triglycerides and

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triglycerides are stored as fat

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deposition and so

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that's there for energy use in case we

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need it or it's also there for

play04:31

cushioning or support or even Anchorage

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holding organs into place now what

play04:36

you'll find is that the types of fatty

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acids we can attach to a glycerol are

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variable so you can have all saturated

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that makes it solid at room temperature

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you can have all mono or polyunsaturated

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liquid at room temperature for example

play04:50

if you look at cocoa butter what it has

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is it's got palmitic acid as one of the

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fatty acids it's got a lake acid as one

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of the fatty acids and it's got a

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polyunsaturated fatty acid which we

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haven't drawn up here but he connects

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and clicks into place

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okay so what we've spoken about here is

play05:11

triglycerides and fats and fatty acids

play05:14

and lipids and their use as a macro

play05:16

molecule

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Related Tags
FatsLipidsMacromoleculeSaturated Fatty AcidsUnsaturated Fatty AcidsTriglyceridesHealth EducationNutritional ScienceDr. MikeBiology