GCSE Chemistry - What is Corrosion and How to Stop it #71

Cognito
8 May 202006:19

Summary

TLDRThis educational video delves into the science of corrosion, focusing on rusting as a form of metal breakdown. It explains rusting as a redox reaction where iron reacts with oxygen and water to form hydrated iron oxide. The video demonstrates that rusting requires both oxygen and water, using a test tube experiment. It contrasts rusting with aluminum corrosion, highlighting how aluminum oxide forms a protective layer. Finally, it discusses prevention methods, including barrier methods like painting, oiling, and electroplating, and sacrificial methods like galvanizing, where a more reactive metal protects the iron.

Takeaways

  • 🔍 Corrosion is the gradual breakdown of metals through reactions with environmental substances, with rusting being a common example involving iron, oxygen, and water.
  • 🔬 Rusting is a redox reaction where iron atoms lose electrons to become iron ions and oxygen atoms gain electrons to form oxide ions.
  • 🌡️ The presence of both oxygen and water is necessary for rusting to occur, as demonstrated by the test tube experiment.
  • 🏗️ Rust affects only the surface of the metal initially, but over time, the rust flakes off to expose new metal, leading to further corrosion.
  • 📉 Unlike iron, metals like aluminum form a protective oxide layer when they corrode, which prevents further corrosion of the underlying metal.
  • 🛡️ Preventing rust involves two main methods: barrier methods that physically block oxygen and water from the metal, and sacrificial methods that use more reactive metals to protect the iron.
  • 🖌️ Painting is a common barrier method used to protect large iron structures from rusting by creating a protective coating.
  • 🛠️ Applying oil or grease can prevent rust on moving parts, such as a bicycle chain, by creating a barrier against environmental elements.
  • 🌐 Electroplating is a barrier method that uses electrolysis to cover iron with a thin layer of another metal, offering protection against corrosion.
  • ⚡️ Sacrificial methods involve adding reactive metals like zinc or aluminum to the iron, which will oxidize in place of the iron if exposed to oxygen.
  • 🛡️ Galvanizing is a process that combines both barrier and sacrificial methods by coating iron with zinc, which protects the iron and can still offer protection if the coating is scratched.

Q & A

  • What is corrosion in the context of the video?

    -Corrosion is the process by which metals are slowly broken down by reacting with substances in their environment, such as rusting which occurs when iron reacts with oxygen and water to form hydrated iron oxide, commonly known as rust.

  • What is the chemical reaction that occurs during rusting?

    -During rusting, iron atoms lose three electrons to become iron three plus ions, while oxygen atoms in the oxygen molecule gain a total of four electrons to become oxygen two minus ions, forming a redox reaction.

  • Why is the presence of both oxygen and water necessary for rusting?

    -Both oxygen and water are necessary for rusting because they are the reactants that interact with iron to form rust. Without either of these elements, the rusting process cannot occur.

  • How does the rusting process differ from other forms of corrosion?

    -Rusting specifically involves iron, whereas corrosion is a general term that can refer to the breakdown of various metals. Rusting results in the formation of hydrated iron oxide, while other metals may form different compounds during corrosion.

  • What is the significance of the test tubes experiment in the video?

    -The test tubes experiment demonstrates the conditions required for rusting by showing that rust only forms on the iron nail when both oxygen and water are present, illustrating the necessity of these elements for the rusting process.

  • Why does rusting only affect the surface of a metal?

    -Rusting only affects the surface of a metal because only the surface is exposed to environmental substances like water and oxygen, which are required for the rusting process to occur.

  • How does the rusting process lead to the gradual breakdown of iron?

    -As rust forms on the surface of iron, it gradually flakes off, revealing new metal underneath. This exposes the next layer to the environment, allowing it to rust as well, leading to the gradual breakdown of the entire piece of iron over time.

  • What is the difference between rusting of iron and corrosion of metals like aluminium?

    -When iron rusts, the rust flakes off, exposing new layers to rust, leading to the complete breakdown of the iron. In contrast, when aluminium corrodes, a protective layer of aluminium oxide forms on the surface, preventing further corrosion of the underlying metal.

  • What are the two main categories of methods to prevent iron from rusting mentioned in the video?

    -The two main categories of methods to prevent iron from rusting are barrier methods, which prevent oxygen and water from touching the iron, and sacrificial methods, which involve adding a more reactive metal to protect the iron from oxidation.

  • Can you explain the concept of barrier methods in rust prevention?

    -Barrier methods work by creating a physical barrier between the iron and the environment to prevent rusting. This can be done through painting, oiling or greasing, or electroplating a thin layer of another metal over the iron.

  • What is the sacrificial method in rust prevention, and how does it work?

    -The sacrificial method involves adding a more reactive metal, such as aluminium or zinc, to the iron. This reactive metal will be oxidized instead of the iron when exposed to oxygen, thus protecting the iron from rusting.

  • What is galvanizing, and how does it combine both barrier and sacrificial methods?

    -Galvanizing is a process where iron is coated in a layer of zinc, which acts as a barrier by preventing oxygen and water from reaching the iron. If the zinc coating is scratched, the zinc itself will react with any nearby oxygen due to its reactivity, serving as a sacrificial layer to protect the underlying iron from rusting.

Outlines

00:00

🛠️ Understanding Corrosion and Rusting

This video delves into the concept of corrosion, with a specific focus on rusting, a common form of corrosion. Rusting occurs when iron reacts with oxygen and water, forming hydrated iron oxide or rust. At the atomic level, iron atoms lose electrons to become iron ions, while oxygen molecules gain electrons to become oxide ions. This process is a redox reaction, involving both oxidation (iron losing electrons) and reduction (oxygen gaining electrons). The video then discusses the conditions necessary for rusting, highlighting that both oxygen and water must be present. It explains this through an experiment with iron nails in three different environments: one with only water, one with only air, and one with both. Only the nail in the environment containing both oxygen and water rusts. Additionally, the video mentions that only the surface of metals undergoes corrosion, but in the case of iron, the rust flakes off, exposing new metal to rust, which can lead to the complete breakdown of the metal over time. In contrast, metals like aluminum form a protective oxide layer, preventing further corrosion.

05:00

🛡️ Preventing Rust: Barrier and Sacrificial Methods

This section of the video explains various methods to prevent rusting in iron. These methods are categorized into barrier methods and sacrificial methods. Barrier methods prevent oxygen and water from contacting the iron, thereby preventing rust. These include painting, which is ideal for large structures like ships; oiling or greasing, which is useful for moving parts such as bike chains; and electroplating, which uses electrolysis to coat iron with a protective metal layer. Sacrificial methods involve adding a more reactive metal, like aluminum or zinc, to the iron, which will oxidize instead of the iron when exposed to oxygen. A practical example combining both methods is galvanizing, where iron is coated with a layer of zinc. This acts as a barrier method by protecting the iron with a zinc coating. If the zinc layer is scratched, exposing the iron, the zinc still protects the iron by oxidizing first due to its higher reactivity, demonstrating the sacrificial method. The video concludes by encouraging viewers to like and subscribe.

Mindmap

Keywords

💡Corrosion

Corrosion is a natural process where metals slowly break down due to their reaction with substances in the environment. In the context of the video, it is the overarching theme that explains how metals, particularly iron, are affected over time. The script discusses how corrosion can lead to the formation of rust, which is a specific type of corrosion involving iron.

💡Rusting

Rusting is a specific form of corrosion that occurs when iron reacts with oxygen and water to form hydrated iron oxide, commonly known as rust. The video script uses rusting as an example to illustrate the process of corrosion, highlighting the chemical reaction at the atomic level that leads to the formation of rust.

💡Redox Reaction

A redox reaction, short for reduction-oxidation reaction, involves the transfer of electrons between two species. The script explains that rusting is a redox reaction where iron atoms lose electrons (are oxidized) and oxygen atoms gain electrons (are reduced), resulting in the formation of rust.

💡Hydrated Iron Oxide

Hydrated iron oxide is the chemical name for rust, which is formed when iron reacts with oxygen and water. The video script mentions this term to describe the chemical product of the rusting process, emphasizing the scientific nature of the corrosion phenomenon.

💡Iron

Iron is a metal that is prone to corrosion, particularly rusting, as it reacts with oxygen and water. The script uses iron as a primary example to explain the process of corrosion, detailing how iron atoms lose electrons to form iron ions, which then combine with oxygen and water to form rust.

💡Oxygen

Oxygen is one of the essential elements required for the rusting process, as it reacts with iron and water to form rust. The video script discusses the role of oxygen in the redox reaction, where it gains electrons and is reduced to form part of the rust compound.

💡Water

Water is another key component in the rusting process, as it participates in the chemical reaction with iron and oxygen. The script illustrates the necessity of water for rusting to occur, using an experiment with test tubes to demonstrate that rust forms only in the presence of both oxygen and water.

💡Barrier Methods

Barrier methods are techniques used to prevent rusting by creating a physical barrier between the iron and the environment. The script mentions three types of barrier methods: painting, oiling or greasing, and electroplating. These methods prevent oxygen and water from reaching the iron, thereby inhibiting rust formation.

💡Sacrificial Methods

Sacrificial methods involve using a more reactive metal that will oxidize in place of the iron when exposed to oxygen, thus protecting the iron from rusting. The script explains this concept by describing the use of metals like aluminum or zinc, which are more willing to lose electrons and be oxidized, protecting the underlying iron.

💡Galvanizing

Galvanizing is a specific anti-corrosion method that combines both barrier and sacrificial methods. The script describes galvanizing as the process of coating iron with a layer of zinc, which acts as a barrier to prevent rusting. If the zinc layer is scratched, the zinc itself will oxidize preferentially, protecting the iron due to its higher reactivity.

💡Aluminum Oxide

Aluminum oxide is a protective layer that forms on the surface of aluminum when it corrodes. Unlike rust, which flakes off and exposes new iron to corrosion, aluminum oxide forms a stable protective layer that prevents further corrosion of the underlying metal. The script contrasts the behavior of rust with that of aluminum oxide to illustrate different corrosion outcomes for different metals.

Highlights

Corrosion is the process by which metals are slowly broken down by reacting with substances in their environment.

Rusting is a specific type of corrosion where iron reacts with oxygen and water to form hydrated iron oxide.

At the atomic level, rusting involves iron atoms losing electrons and oxygen atoms gaining electrons, making it a redox reaction.

Rusting requires both oxygen and water to be present; an experiment with test tubes illustrates this requirement.

Corrosion only affects the surface of metals, as it's the surface that's exposed to environmental substances.

Rust formation on iron leads to the gradual flaking off of the surface, exposing new metal to rust over time.

Aluminium corrosion differs from iron as it forms a protective oxide layer that prevents further corrosion of the metal beneath.

Methods to prevent iron from rusting are categorized into barrier methods and sacrificial methods.

Barrier methods prevent oxygen and water from touching the iron, such as painting, oiling, or electroplating.

Sacrificial methods involve adding a more reactive metal like aluminium or zinc to the iron, which oxidizes in place of the iron.

Galvanizing is an example that uses both barrier and sacrificial methods by coating iron with zinc.

If the zinc coating on galvanized iron is scratched, the zinc still protects the iron by reacting with any nearby oxygen.

The video concludes with a call to action for viewers to like and subscribe for more content.

Transcripts

play00:04

in this video we're going to look at

play00:06

corrosion

play00:07

and in particular at why things rust

play00:11

and how we can prevent it

play00:16

corrosion is a general term that refers

play00:19

to the process by which metals are

play00:21

slowly broken down by reacting with

play00:24

substances in their environment

play00:27

one example of this is rusting

play00:30

which is where iron reacts with oxygen

play00:33

and water from the environment

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to form hydrated iron oxide

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which is more commonly known as rust

play00:43

if we think about what's happening here

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at the atomic level the iron atoms in

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our original block of metal are each

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losing three electrons to become iron

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three plus ions

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and at the same time the two oxygen

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atoms in each oxygen molecule

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are gaining two electrons so a total of

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four electrons

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to become oxygen two minus ions

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so the ion is being oxidized because it

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lost electrons

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while the oxygen is being reduced

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because it's gaining electrons

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and this means that the overall reaction

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is a redox reaction

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because both oxidation and reduction are

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taking place in the same reaction

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the next thing we need to cover are the

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conditions that are required for rusting

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to take place

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we said earlier that rusting involves

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iron reacting with oxygen and water from

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the environment

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so both of these have to be present for

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rusting to take place

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to see this in practice let's imagine

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three test tubes

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each one with an iron nail in it

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the first test tube contains water but

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no oxygen

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this is because the water has been

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boiled to remove any of the oxygen that

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was previously dissolved in it

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and this layer of oil at the top stops

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any new oxygen that in the air from

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dissolving into the water

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the second test tube contains air and so

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oxygen

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but no water

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and this is achieved by having the

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calcium chloride at the bottom

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which will remove any water vapor from

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the air

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and then the final test tube contains

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both air so oxygen

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and water

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so if we now left these test tubes for a

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while

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only this nail in the last tube would

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rust

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because it's the only one that contains

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both oxygen and water

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one important thing to understand with

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corrosion

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is that it's only the surface of a metal

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that corrodes

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this is because only the surface is

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exposed to substances in the environment

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like water and oxygen

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when iron rusts though the rust that

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forms at the surface gradually flakes

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off

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revealing new metal underneath

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this means that the next layer can also

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rust

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and over time that bit will fall away as

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well

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so if left long enough the entire chunk

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of iron can break down until there's

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nothing left

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in contrast when metals like aluminium

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corrode

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it's only the surface atoms that are

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affected

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this is because when the top layer of

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aluminium atoms is oxidized to form

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aluminium oxide

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they effectively form a protective layer

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around the piece of aluminium

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which protects the rest of the metal

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from the environment

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the last thing we need to look at is how

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we can prevent iron from rusting

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generally speaking we can split the

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methods into two main categories

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barrier methods

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and sacrificial methods

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the barrier methods

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work by preventing the oxygen and water

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from ever touching the iron

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so that rusting can't take place

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and there are three main types to know

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one is to paint it

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which works well for really big pieces

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of iron like the side of a ship

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the second is to oil or grease it

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which is necessary if the object is

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moving parts like a bike

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chain and the third type of barrier

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protection is electroplating

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which is kind of complicated but

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basically involves using electrolysis

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to cover the iron in a thin layer of

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another metal

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which will protect the iron underneath

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the other option is called the

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sacrificial method

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this involves adding a more reactive

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metal like aluminium or zinc to the iron

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this means that if the object gets

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exposed to oxygen

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the more reactive metal will be oxidized

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instead of the iron

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and so the iron won't rust

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an example that uses both of these

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methods is galvanizing

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this involves coating the iron object in

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a layer of zinc

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which is effectively the barrier method

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because it's forming a protective

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coating around the entire nail

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however if the zinc coating gets

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scratched and the underlying iron gets

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exposed

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the zinc will still react with any

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oxygen that goes near the nail because

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the zinc is so much more reactive

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so it's actually an example of the

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sacrificial method as well

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anyway that's everything for this video

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so if you enjoyed it then please do give

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us a like and subscribe

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and we'll see you again soon

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Ähnliche Tags
Corrosion PreventionMetal RustingChemical ReactionsRedox ProcessesEnvironmental FactorsProtective CoatingsBarrier MethodsSacrificial MethodsGalvanizationElectroplating
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