Double Displacement Reactions

Mugsy Carter
19 Feb 201319:03

Summary

TLDRThis educational video script details a chemistry experiment exploring double displacement reactions. Six test tubes with salt water (sodium chloride) are exposed to various reactants, including calcium hydroxide, copper sulfate, hydrochloric acid, sodium hydroxide, calcium chloride, and potassium chloride. The reactions are observed for signs of precipitate, color change, or gas release. The script explains why certain reactions occur, such as the formation of insoluble calcium sulfate from copper sulfate and calcium hydroxide, and the neutralization reaction between hydrochloric acid and sodium hydroxide, forming water and salt. The experiment highlights the conditions necessary for a double displacement reaction to take place.

Takeaways

  • πŸ§ͺ The experiment involves testing double displacement reactions between salt water and six different compounds.
  • πŸ”¬ Salt water, primarily sodium chloride, is mixed with calcium hydroxide, copper sulfate, hydrochloric acid, sodium hydroxide, calcium chloride, and potassium chloride to observe reactions.
  • πŸŒ€ No visible reactions were observed initially with the addition of the second reactants to the salt water.
  • πŸ“š Double displacement reactions occur if a gas, solid, or covalent compound like water is formed.
  • 🚫 The reactions with calcium hydroxide and sodium chloride did not proceed because both resulting compounds, calcium chloride and sodium hydroxide, are soluble in water.
  • 🌈 Copper sulfate and sodium hydroxide reacted to form copper hydroxide precipitate and sodium sulfate, with the former being insoluble.
  • πŸ’§ Hydrochloric acid and calcium hydroxide reacted to form water and calcium chloride, with the former being a covalent compound indicating a reaction.
  • πŸ€” The lack of visible reaction with sodium hydroxide and hydrochloric acid was confirmed using phenolphthalein as an indicator, revealing a neutralization reaction.
  • 🧩 The experiment demonstrates the concept of solubility and reactivity in chemical reactions, showing that not all compounds will react with each other.
  • πŸ“‰ Calcium chloride reacted with sodium hydroxide to form calcium hydroxide precipitate, indicating a successful double displacement reaction.
  • πŸ”„ The experiment concludes that reactions occurred with copper sulfate and hydrochloric acid, but not with sodium, calcium, or potassium chloride due to the lack of formation of a precipitate, gas, or covalent compound.

Q & A

  • What is the purpose of adding different reactants to the test tubes containing salt water?

    -The purpose is to check for a double displacement reaction among the reactants and salt water.

  • Which reactants were added to the test tubes containing salt water?

    -Calcium hydroxide, copper sulfate, hydrochloric acid, sodium hydroxide, calcium chloride, and potassium chloride were added.

  • What was observed in the test tubes after adding the reactants to the salt water?

    -No color change, no bubbles indicating gas, and no precipitate at the bottom were observed, suggesting no reaction occurred.

  • Why did the reaction between sodium chloride and calcium hydroxide not proceed?

    -The potential products, calcium chloride and sodium hydroxide, are both water-soluble, providing no reason for the reaction to proceed.

  • What conditions are necessary for a double displacement reaction to occur?

    -A double displacement reaction will occur if a gas is formed, a solid precipitate is formed, or a covalent compound like water is formed.

  • What happened when copper sulfate was added to the test tubes containing calcium hydroxide?

    -A reaction occurred, forming a precipitate of calcium sulfate, which is insoluble in water.

  • What was the observed reaction when hydrochloric acid was added to calcium hydroxide?

    -A reaction occurred, forming calcium chloride, which is water-soluble, and water, a covalent compound.

  • What is the significance of the reaction between copper sulfate and sodium hydroxide?

    -The reaction forms copper hydroxide, which is insoluble and forms a precipitate, and sodium sulfate.

  • Why was there no visible reaction when hydrochloric acid was added to sodium hydroxide?

    -The reaction between hydrochloric acid and sodium hydroxide is a neutralization reaction forming water and sodium chloride, which may not be visibly obvious without an indicator.

  • How was the neutralization reaction between hydrochloric acid and sodium hydroxide confirmed?

    -The reaction was confirmed by using phenolphthalein as an indicator, which turned the solution pink in the presence of the base, sodium hydroxide.

  • What was the observed reaction when calcium chloride was added to sodium hydroxide?

    -A reaction occurred, forming a precipitate of calcium hydroxide, which is insoluble in water.

  • Why did the addition of potassium chloride to sodium hydroxide not result in a reaction?

    -Both potassium chloride and sodium hydroxide are chlorides, so there is no reason for the chloride ions to switch and no reaction occurs.

Outlines

00:00

πŸ§ͺ Double Displacement Reactions with Salt Water

This paragraph describes an experiment involving six test tubes filled with salt water to which various reactants are added to test for double displacement reactions. The reactants include calcium hydroxide, copper sulfate, hydrochloric acid, sodium hydroxide, calcium chloride, and potassium chloride. The experiment shows no visible reaction, indicating that none of these substances react with salt water under the conditions provided. The explanation provided is that a double displacement reaction requires the formation of a gas, solid, or covalent compound like water, which did not occur in these cases.

05:03

πŸ”¬ Reaction Series with Calcium Hydroxide and Copper Sulfate

In this section, the experimenter adds different reactants to test tubes containing calcium hydroxide and copper sulfate. The addition of copper sulfate to calcium hydroxide results in the formation of calcium sulfate, which is insoluble and forms a 'snotty' precipitate. Hydrochloric acid reacts with calcium hydroxide to form calcium chloride and water, which is a covalent compound, indicating a neutralization reaction. Other reactants like sodium hydroxide, calcium chloride, and potassium chloride show no visible reaction, suggesting that no double displacement occurred due to the lack of formation of a precipitate, gas, or covalent compound.

10:11

πŸŒ€ Copper Sulfate Activity Series and Reaction Observations

The paragraph details the reactions of copper sulfate with various substances, including hydrochloric acid, sodium hydroxide, calcium chloride, and potassium chloride. Sodium hydroxide reacts with copper sulfate to form copper hydroxide precipitate and sodium sulfate. Calcium chloride also shows a reaction with copper sulfate, forming a precipitate. However, hydrochloric acid and potassium chloride do not show an immediate reaction. The use of phenolphthalein as an indicator confirms the neutralization reaction between sodium hydroxide and hydrochloric acid, despite the lack of visible change.

15:13

πŸ“‰ Hydrochloric Acid and Sodium Hydroxide Neutralization

This paragraph focuses on the neutralization reaction between hydrochloric acid and sodium hydroxide, which results in the formation of water and sodium chloride. The experiment shows that calcium chloride reacts with sodium hydroxide to form calcium hydroxide precipitate. Potassium chloride does not react with sodium hydroxide, as both are already bonded to chlorine, and there is no driving force for a reaction. The use of phenolphthalein as an indicator helps to confirm the occurrence of the neutralization reaction, which was not initially visible.

Mindmap

Keywords

πŸ’‘Double Displacement Reaction

A double displacement reaction, also known as a metathesis reaction, occurs when two compounds exchange components to form two new compounds. In the context of the video, this concept is central to understanding the experiments being conducted with various reactants in test tubes. For instance, the script describes how sodium chloride (salt water) does not react with other compounds because the resulting products would be soluble, hence no double displacement reaction occurs.

πŸ’‘Reactants

Reactants are the initial substances that are combined in a chemical reaction. The video script mentions several reactants, such as calcium hydroxide, copper sulfate, and hydrochloric acid, which are added to test tubes containing salt water to observe potential reactions. The reactants are crucial to the experiments' outcomes and the demonstration of chemical principles.

πŸ’‘Precipitate

A precipitate is a solid that forms in a solution when a solute becomes undissolved due to a chemical reaction. In the video, the script describes the formation of a precipitate when copper sulfate reacts with calcium hydroxide, resulting in calcium sulfate, which is insoluble and thus forms a visible solid in the test tube.

πŸ’‘Soluble

Solubility refers to the ability of a substance to dissolve in a solvent. The script discusses the solubility of various compounds, such as calcium chloride and sodium hydroxide, which are both soluble in water. This property is important in determining whether a double displacement reaction will occur, as reactions are more likely when an insoluble product is formed.

πŸ’‘Covalent Compound

A covalent compound is formed when two or more non-metal atoms share electrons. The video script explains that a double displacement reaction is likely to occur if a covalent compound, such as water, is formed. For example, the reaction between hydrochloric acid and calcium hydroxide produces water and calcium chloride, indicating a reaction has taken place.

πŸ’‘Indicator

An indicator is a substance that changes color in response to changes in pH, helping to identify whether a reaction has occurred. In the script, phenolphthalein is used as an indicator to confirm the neutralization reaction between hydrochloric acid and sodium hydroxide, as it turns pink in basic conditions.

πŸ’‘Neutralization Reaction

A neutralization reaction is a chemical reaction in which an acid and a base react to form a salt and water. The video describes this type of reaction occurring between hydrochloric acid and sodium hydroxide, resulting in the formation of sodium chloride and water, which is evidenced by the change in color of the phenolphthalein indicator.

πŸ’‘Insoluble

Insoluble substances do not dissolve well in a given solvent. The script mentions calcium hydroxide as being insoluble in water, which is why it settles at the bottom of the beaker. The concept of insolubility is important for understanding which substances will form precipitates in a reaction.

πŸ’‘Sodium Chloride

Sodium chloride, commonly known as table salt, is a compound consisting of sodium and chlorine. In the video, sodium chloride is used as the base substance in the test tubes. The script discusses how it does not react with certain other compounds because the potential products would also be soluble, thus not meeting the criteria for a double displacement reaction.

πŸ’‘Activity Series

The activity series is a list of metals arranged in order of their reactivity. While not explicitly mentioned in the script, the concept is implied in the reactions observed, such as the reaction between copper sulfate and calcium hydroxide, where the calcium displaces the copper to form calcium sulfate. Understanding the activity series helps predict which metals will react with certain compounds.

Highlights

Experiment begins with six test tubes containing salt water and various reactants to check for double displacement reactions.

No visible reaction observed with the addition of calcium hydroxide, copper sulfate, hydrochloric acid, sodium hydroxide, calcium chloride, and potassium chloride to salt water.

Explanation of why no reaction occurred with sodium chloride and the six compounds based on solubility and the criteria for double displacement reactions.

Copper sulfate and calcium hydroxide reaction produces a precipitate, indicating a reaction between the two.

Hydrochloric acid reacts with copper sulfate, forming a precipitate almost immediately, unlike other reactants.

Sodium hydroxide and hydrochloric acid predicted to react in a neutralization reaction, forming water and sodium chloride.

Use of phenolphthalein as an indicator to confirm the neutralization reaction between sodium hydroxide and hydrochloric acid.

Observation of a precipitate forming in the reaction between copper sulfate and sodium hydroxide, indicating the formation of copper hydroxide.

No visible reaction with calcium chloride and copper sulfate initially, but a precipitate is later observed.

No reaction observed between hydrochloric acid and either calcium chloride or potassium chloride due to the lack of driving force.

Demonstration of the difficulty in observing reactions with insoluble calcium hydroxide in water.

Calcium hydroxide and copper sulfate reaction results in calcium sulfate, an insoluble compound that forms a distinct texture.

The importance of covalent compound formation, such as water, in driving double displacement reactions.

No reactions observed with sodium hydroxide, calcium chloride, and potassium chloride in the activity series.

Reaction between sodium hydroxide and calcium chloride, resulting in the formation of calcium hydroxide precipitate.

Final observation of no reaction between calcium chloride and potassium chloride due to both being chlorides.

Summary of the chemical reactions and the conditions necessary for them to occur, emphasizing the role of solubility and the formation of covalent compounds.

Transcripts

play00:13

okay as you can see here we've got our

play00:16

salt water so we have about somewhere

play00:19

between two and three mils of salt water

play00:20

in each of these six test tubes now

play00:24

going along with our reaction series

play00:25

we're going to add our second reactant

play00:28

to each of these test tubes to check for

play00:30

a double displacement reaction we've got

play00:33

calcium hydroxide copper sulfate

play00:36

hydrochloric acid sodium hydroxide

play00:39

calcium chloride and potassium chloride

play00:43

those are the six things that we're

play00:44

gonna add to these test tubes which all

play00:47

just contain salt water right now

play00:49

sodium chloride let's begin we'll start

play00:52

with our calcium hydroxide this is

play00:54

barely soluble in water most of it is

play00:57

settled to the bottom of the beaker so

play00:59

let's sprinkle some of that it next

play01:04

we'll do our copper sulfate

play01:11

next our hydrochloric acid

play01:17

our sodium hydroxide

play01:28

calcium chloride

play01:35

and potassium chloride

play01:42

okay I'm looking at these test tubes

play01:44

right now and I see no indication of a

play01:46

reaction no color change no bubbles to

play01:49

indicate a gas no precipitate at the

play01:51

bottom so it appears that none of the

play01:56

salt water has reacted with these other

play01:57

compounds

play02:07

all right so here's our saltwater and we

play02:11

saw that the saltwater didn't react with

play02:12

any of the six other compounds what I'm

play02:16

gonna do now is explain why so in our

play02:19

first speaker over here I'm sorry our

play02:21

first test-tube

play02:22

we've got calcium hydroxide in saltwater

play02:27

so the sodium chloride could react with

play02:29

the calcium hydroxide but then we'd have

play02:31

calcium chloride which is water soluble

play02:34

and sodium hydroxide which is also

play02:37

soluble so no reason for that reaction

play02:40

to go again a double displacement

play02:42

reaction will only occur if a gas is

play02:46

formed a solid is formed or a covalent

play02:50

compound is formed such as water so that

play02:53

first reaction didn't meet any of those

play02:55

criterion of those criteria so no

play02:58

reaction second reaction we have copper

play03:00

sulfate and in salt water that could

play03:03

form sodium sulfate and also copper

play03:07

chloride both of those things are water

play03:10

soluble so no reaction next one we have

play03:13

sodium chloride and hydrochloric acid

play03:16

there's no reason for this reaction to

play03:18

happen right we just be trading chlorine

play03:20

for chlorine so why bother same thing

play03:23

over here we have sodium chloride and

play03:25

sodium hydroxide both of these compounds

play03:27

have sodium in them

play03:28

so why would sodium switch with sodium

play03:31

and when you wouldn't change anything in

play03:33

the grand scheme of things

play03:34

same thing with calcium chloride it's

play03:36

got chloride in it same thing as sodium

play03:39

chloride so chlorine wouldn't switch

play03:41

with chlorine doesn't make any sense

play03:42

wouldn't contribute and finally same

play03:45

thing with potassium chloride chlorine

play03:47

chlorine no reason for the reaction to

play03:50

happen so there are the answers for our

play03:53

sodium chloride series now we're looking

play03:58

at our calcium hydroxide reaction series

play04:02

we've got about two to three milliliters

play04:04

of calcium hydroxide in each of these

play04:06

test tubes calcium hydroxide is pretty

play04:09

much insoluble in water so we basically

play04:11

have kind of a little bit of cloudiness

play04:13

in these most of the calcium hydroxide

play04:16

is settle to the bottom line container

play04:17

it looks like this

play04:19

so we're gonna see what we can see here

play04:25

we're gonna put our copper sulfate in

play04:27

the first one and then hydrochloric acid

play04:29

sodium hydroxide calcium chloride and

play04:31

potassium chloride let's start with our

play04:34

copper sulfate

play04:44

hydrochloric acid

play04:51

sodium hydroxide

play05:03

calcium chloride

play05:09

and potassium chloride

play05:26

okay looking at these don't see much

play05:31

indication of a reaction except looking

play05:35

at our copper sulfate here let's see if

play05:37

we can focus in on that there's some

play05:41

cloudiness it looks like a precipitate

play05:43

is forming

play05:57

see what happens if we add some of our

play05:59

solid to these

play06:18

oh yeah if you look at the copper

play06:20

sulfate it reacts pretty much instantly

play06:29

it's chunky

play06:38

kind of an inconsistent texture in there

play06:40

all the rest of these kind of look like

play06:44

we expect them to just kind of cloudy

play06:47

with the possible exception of with the

play06:49

HCL here with the HCL it precipitated

play06:54

almost immediately right out to the

play06:57

bottom so those two seem very different

play07:03

from the rest so the HCL in the copper

play07:05

sulfate seem to react right away the

play07:08

rest of these just kind of look cloudy

play07:09

and insoluble like copper sulfate

play07:12

typically does this is the calcium

play07:19

hydroxide up close calcium hydroxide

play07:24

that was formed in the reaction between

play07:25

I'm sorry not calcium hydroxide copper

play07:29

sulfate that was formed in the reaction

play07:30

between copper sulfate and calcium

play07:32

hydroxide it formed this calcium sulfate

play07:35

kind of snotty looking stuff in there

play07:46

okay so here are the answers for our

play07:50

calcium hydroxide activity series this

play07:53

is kind of a weird one to do because the

play07:55

calcium hydroxide is already insoluble

play07:57

in water so it's kind of hard to see any

play08:00

sort of reaction at all except in the

play08:02

case of the calcium hydroxide and the

play08:06

copper sulfate so in this one basically

play08:10

the calcium in the copper switched place

play08:12

and we end up with calcium sulfate which

play08:14

is insoluble which kind of forms this

play08:16

kind of like almost snot looking stuff

play08:19

you can see that they're real pretty

play08:25

with our hydrogen chloride or a

play08:27

hydrochloric acid you can see a reaction

play08:29

happen right away - and that it's

play08:31

settled much faster than all of our

play08:32

other ones with that particular reaction

play08:35

what happens is the calcium from the

play08:38

calcium hydroxide kind of gloms on to

play08:41

the chlorine from the hydrochloric acid

play08:44

we end up with calcium chloride which is

play08:46

water-soluble and the OAH from the

play08:52

calcium hydroxide gloms onto the

play08:53

hydrogen from the hydrochloric acid and

play08:55

we form water so what this does is it

play08:57

takes a lot of the stuff out of solution

play08:59

and makes it soluble and basically that

play09:02

that insoluble stuff is left in the

play09:04

bottom that's just unreacted calcium so

play09:07

if we formed soluble compounds why do we

play09:10

why did this reaction happen well it's

play09:11

because water was formed as you know

play09:14

water is a covalent compound and one of

play09:16

the reasons for a double displacement

play09:18

reaction to happen is the formation of a

play09:20

covalent compound so for this activity

play09:23

series we did not have any reactions

play09:25

with the three on the right that's the

play09:26

sodium hydroxide the calcium chloride

play09:28

and the potassium chloride we did have

play09:30

reactions with the copper sulfate where

play09:32

a solid was formed

play09:33

that's the calcium sulfate and with the

play09:36

hydrochloric acid where it basically

play09:38

neutralized to form water hydrochloric

play09:40

acid you'll learn later is a strong acid

play09:43

and the calcium hydroxide is a base so

play09:47

there you go

play09:50

all right next up we have our copper

play09:53

sulfate activity series the copper

play09:57

sulfate to begin with kind of has this

play09:58

beautiful blue color

play10:11

let's add our second reactants so we're

play10:14

going to start with some hydrochloric

play10:15

acid sodium hydroxide

play10:32

some calcium chloride

play10:38

and some potassium chloride

play10:47

well it looks like right away we have

play10:51

some reactions

play11:05

the most obvious of which would be the

play11:08

sodium hydroxide when the copper sulfate

play11:12

reacts with the sodium hydroxide we

play11:14

basically get copper hydroxide and

play11:17

sodium sulfate and the copper hydroxide

play11:19

is insoluble so we get this kind of

play11:22

goopy looking precipitate forming up at

play11:26

the top and a layer these other three

play11:31

show no change really they kind of all

play11:34

look the same

play11:37

in fact for copper sulfate and calcium

play11:43

chloride it looks just like water and

play11:53

for copper sulfate and potassium

play11:56

chloride again no significant change

play12:00

here no significant change interesting

play12:04

all right now we're looking back at our

play12:06

copper sulfate samples and we can see

play12:08

pretty clearly now that a reaction has

play12:11

occurred with the calcium chloride we're

play12:14

seeing precipitate form and start to

play12:16

fall to the bottom

play12:18

we already saw the reaction happen with

play12:20

the sodium hydroxide we can see a little

play12:22

better now but clearly that ones happen

play12:23

as well we still can't see the reaction

play12:27

with the hydrochloric acid we'll have to

play12:30

use some sort of indicator to suss that

play12:31

out okay now it's time for our

play12:37

hydrochloric acid tests we got some HCL

play12:40

in there so in there and

play12:48

some in there so the first one we're

play12:51

gonna add sodium hydroxide we predict

play12:56

your reaction here so do my Drock sides

play12:57

and base doesn't look like anything's

play13:01

going on let's add our calcium chloride

play13:03

and our potassium chloride and we see no

play13:16

visible reaction all right with our

play13:25

hydrochloric acid we predicted that the

play13:27

sodium hydroxide would react that the

play13:29

sodium would leave the hydroxide go to

play13:32

the chlorine form salt sodium chloride

play13:34

and we'd also get water covalent

play13:37

compound but we didn't see any evidence

play13:38

of that we predicted that these two both

play13:41

chloride compounds wouldn't react right

play13:44

because why would chlorine replace

play13:46

chlorine doesn't make any sense okay

play13:48

and I actually makes sure if this if

play13:50

didn't reaction didn't happen let's add

play13:52

a little bit of indicator so I'm gonna

play13:55

put in some phenolphthalein

play14:28

and in all three of these we get kind of

play14:31

a milky looking solution Fila failing is

play14:36

an indicator that should turn kind of

play14:37

bright pink eye in the presence of a

play14:41

base so let's add some base

play14:50

you can see as soon as I add the sodium

play14:53

hydroxide the solution turns pink but

play14:55

then it quickly turns back to this kind

play14:57

of milky color let's just keep adding

play15:05

starting to stay pink let's see if

play15:08

that's enough to make it stay nope keep

play15:12

going

play15:20

and now our solution has a nice rich

play15:23

pink color let's see if that's true with

play15:27

these other two keep adding some

play15:28

chlorine so calcium chloride nope I can

play15:36

add calcium chloride all day and I won't

play15:38

get that reaction sans try the same with

play15:41

potassium chloride nope and nope

play15:49

okay so adding those two until my

play15:51

heart's content I don't see the

play15:54

indicator work with the addition of the

play15:59

phenolphthalein it most definitely does

play16:01

work

play16:12

so there you go this one actually did

play16:14

have a chemical reaction even though we

play16:16

couldn't first see it we had to use some

play16:17

other chemical means to see that

play16:20

reaction and again with our sodium

play16:23

hydroxide and our hydrochloric acid this

play16:25

is called a neutralization reaction

play16:26

you'll learn about it later basically we

play16:30

take a base and an acid atom together

play16:32

and you get mostly water and all water

play16:35

if you do it perfectly and then some

play16:36

other sort of compound in this case it's

play16:38

salt sodium chloride okay there you go

play16:42

so here we have some hydrochloric acid

play16:45

we're gonna add some pure sodium

play16:46

hydroxide and see what happens

play17:46

okay now we have two test tubes filled

play17:49

with our sodium hydroxide let's put in

play17:52

some calcium chloride and some potassium

play17:58

chloride I don't see any evidence of a

play18:03

reaction right now but let's give it

play18:04

some time okay now we can see that no

play18:07

reaction happened with the potassium

play18:10

chloride but with the calcium chloride

play18:12

we have a lot of precipitate formed so

play18:14

definitely a reaction happened there

play18:25

with the sodium hydroxide reactions the

play18:29

reason it reacted with calcium chloride

play18:32

is because it forms calcium hydroxide

play18:35

and calcium hydroxide is not soluble in

play18:38

water so that's why we see this

play18:39

precipitate form our last reaction is

play18:41

calcium chloride we're gonna stick some

play18:43

potassium chloride in there and we see

play18:46

no reaction right both of them are

play18:49

chlorides so there's no reason to trade

play18:51

because they're both already bonded to

play18:52

chlorine so no reaction

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Related Tags
Chemical ReactionsSalt WaterDouble DisplacementCopper SulfateCalcium HydroxideHydrochloric AcidSodium HydroxideNeutralizationPrecipitate FormationScience Experiment