Sel Elektrokimia (1) | Sel Volta Dan Sel Elektrolisis | Rangkaian Sel

Kimatika
3 Aug 202210:10

Summary

TLDRThis educational video explores the principles of electrochemistry, focusing on the similarities and differences between a voltaic cell and an electrolytic cell. It explains that a voltaic cell converts chemical energy into electrical energy through spontaneous redox reactions, while an electrolytic cell uses electrical energy to drive non-spontaneous redox reactions. Key points include the use of electrodes, the role of electrolytes, and the direction of electron flow. The video also touches on practical applications, such as batteries for voltaic cells and metal refining for electrolytic cells, providing a foundational understanding of electrochemical cells.

Takeaways

  • πŸ”¬ Electrochemical cells, such as voltaic cells and electrolytic cells, are devices that convert chemical energy into electrical energy or vice versa.
  • πŸ”‹ A voltaic cell generates electrical energy from spontaneous redox reactions, while an electrolytic cell uses electrical energy to drive non-spontaneous redox reactions.
  • πŸ”Œ Both types of cells use electrodes, with the cathode involved in reduction reactions and the anode in oxidation reactions.
  • ⚑ In a voltaic cell, the cathode is the positive terminal and the anode is the negative, whereas in an electrolytic cell, the roles are reversed.
  • πŸ’§ Electrolytes, which can be in liquid or aqueous form, are used in both cell types to facilitate the flow of ions.
  • πŸ” The electromotive force (EMF) of a voltaic cell is positive, indicating a spontaneous reaction, whereas an electrolytic cell has a negative EMF as it requires external energy.
  • πŸ”§ Applications of voltaic cells include batteries and accumulators, while electrolytic cells are used in metal refining and plating processes.
  • πŸ”„ The arrangement of a voltaic cell can involve two separate compartments, each containing an electrolyte solution and an electrode, connected externally to complete the circuit.
  • πŸ”§ In an electrolytic cell, a single container with an electrolyte and two electrodes is used, with the electrodes connected to an external power source.
  • πŸ”¬ The principles of operation for both cell types involve the movement of electrons and ions, leading to the generation or consumption of electrical energy through redox reactions.

Q & A

  • What is the main difference between a voltaic cell and an electrolytic cell?

    -A voltaic cell converts chemical energy into electrical energy through spontaneous redox reactions, while an electrolytic cell uses electrical energy to drive non-spontaneous redox reactions.

  • What are the similarities between a voltaic cell and an electrolytic cell?

    -Both use electrodes (cathode and anode) and an electrolyte, which can be in the form of a solution or a molten substance.

  • How do you remember which electrode undergoes reduction and which undergoes oxidation in a voltaic cell?

    -You can remember it with the acronym 'CRAW': Cathode Reduction, Anode Oxidation.

  • What is the role of the electrolyte in a voltaic cell?

    -The electrolyte in a voltaic cell allows ions to move between the two half-cells to maintain electrical neutrality and facilitate the flow of electrons through the external circuit.

  • What is the significance of the electric potential difference in a voltaic cell?

    -The electric potential difference, or electromotive force (EMF), of a voltaic cell is positive when the cell is producing electricity, indicating that the cell is undergoing a spontaneous redox reaction.

  • What are the applications of voltaic cells in everyday life?

    -Common applications of voltaic cells include batteries and accumulators, which are used to store and provide electrical energy.

  • How is the direction of electron flow in a voltaic cell described?

    -In a voltaic cell, electrons flow from the anode (negative electrode) through the external circuit to the cathode (positive electrode).

  • What is the purpose of the salt bridge in a voltaic cell?

    -The salt bridge in a voltaic cell allows ions to move between the two half-cells to balance the charges and maintain the flow of electrons.

  • What happens at the anode and cathode during the operation of an electrolytic cell?

    -In an electrolytic cell, the anode is connected to the positive terminal of the power source and undergoes oxidation, while the cathode is connected to the negative terminal and undergoes reduction.

  • Why are electrolytic cells considered non-spontaneous?

    -Electrolytic cells are non-spontaneous because they require an external power source to drive the redox reactions, which would not occur naturally without the input of electrical energy.

Outlines

00:00

πŸ”‹ Understanding Electrochemical Cells

This paragraph introduces the topic of electrochemistry, focusing on the concepts of voltaic cells and electrolysis. The video aims to teach the differences and similarities between these two types of electrochemical cells. A voltaic cell is explained as a device that converts chemical energy into electrical energy through spontaneous redox reactions, while electrolysis involves using electrical energy to drive non-spontaneous chemical reactions. The paragraph emphasizes the importance of understanding redox reactions as a foundation for studying electrochemistry. It also outlines the similarities between the two cells, such as the use of electrodes (cathode and anode) and electrolytes, and provides a mnemonic 'Craw' to remember the reactions at the electrodes.

05:02

πŸ”¬ Exploring the Working Principles of Electrochemical Cells

This paragraph delves into the working principles of voltaic cells, explaining how they generate electrical current from chemical reactions. It describes the setup of a voltaic cell, which includes two half-cells containing different electrolyte solutions and electrodes made of metals like zinc and copper. The paragraph explains the flow of electrons from the anode (where oxidation occurs) to the cathode (where reduction occurs), creating an electric current. It also discusses the role of a salt bridge in maintaining charge balance within the cell. The paragraph further clarifies the differences between voltaic cells and electrolytic cells in terms of electrode potentials, spontaneity of reactions, and their practical applications, such as in batteries for voltaic cells and metal refining for electrolytic cells.

10:02

πŸ“š Conclusion and Blessings

The final paragraph of the script concludes the educational video with a summary and blessings. It thanks the viewers for watching and ends with traditional Islamic greetings, emphasizing the cultural and educational aspects of the content. This paragraph serves as a respectful and warm closing to the video, leaving a positive impression on the audience.

Mindmap

Keywords

πŸ’‘Electrochemistry

Electrochemistry is the branch of chemistry that deals with the relationship between electricity and chemical reactions. In the context of the video, electrochemistry is the central theme, as it explains how chemical reactions can produce electricity (as in a voltaic cell) or how electricity can drive chemical reactions (as in electrolysis).

πŸ’‘Redox Reactions

Redox, short for reduction-oxidation reactions, involves the transfer of electrons between atoms. The video emphasizes that understanding redox reactions is fundamental to grasping electrochemistry. Redox reactions are the basis for the operation of both voltaic cells and electrolytic cells.

πŸ’‘Voltaic Cell

A voltaic cell, also known as a galvanic cell, is a type of electrochemical cell that generates electrical energy from chemical reactions. The video explains that in a voltaic cell, spontaneous redox reactions occur, converting chemical energy into electrical energy. The script uses the example of a voltaic cell with zinc and copper electrodes to illustrate this concept.

πŸ’‘Electrolysis

Electrolysis is a process that uses an electric current to drive a non-spontaneous chemical reaction. The video contrasts this with a voltaic cell, where electrical energy is produced by spontaneous reactions. Electrolysis is used to decompose compounds, such as the electrolytic refining of metals.

πŸ’‘Electrodes

Electrodes are the conductive materials through which current enters or leaves an electrochemical cell. The video mentions anodes and cathodes, with the anode being the electrode where oxidation occurs (losing electrons) and the cathode where reduction occurs (gaining electrons). The script explains that in a voltaic cell, the cathode is positive and the anode is negative, while in electrolysis, the roles are reversed.

πŸ’‘Electrolyte

An electrolyte is a substance that produces an electrically conducting solution when dissolved in a polar solvent, such as water. The video explains that both voltaic and electrolytic cells use an electrolyte, which can be in the form of a liquid or a moist paste, to facilitate the flow of ions between the electrodes.

πŸ’‘Potential Difference

Potential difference, also known as voltage, is the measure of the electric potential energy per unit charge in an electric field. The video discusses how the potential difference in a voltaic cell is positive, indicating that the cell can produce electrical energy, while in electrolysis, the potential difference is negative or zero, indicating that energy is being consumed.

πŸ’‘Spontaneous Reactions

Spontaneous reactions occur naturally without the need for external energy. The video highlights that in a voltaic cell, the redox reactions are spontaneous, leading to a positive potential difference and the generation of electrical energy.

πŸ’‘Non-Spontaneous Reactions

Non-spontaneous reactions require an input of energy to occur. The video contrasts this with spontaneous reactions, explaining that in electrolysis, electrical energy is supplied to drive reactions that would not otherwise occur on their own.

πŸ’‘Cathode Reduction

At the cathode, reduction reactions occur where atoms or ions gain electrons. The video uses the example of a copper ion (Cu^2+) gaining electrons to form copper metal at the cathode in a voltaic cell, demonstrating the conversion of chemical energy to electrical energy.

πŸ’‘Anode Oxidation

At the anode, oxidation reactions occur where atoms or ions lose electrons. The video describes how zinc at the anode loses electrons to form zinc ions (Zn^2+) in a voltaic cell, contributing to the overall redox reaction that powers the cell.

Highlights

Introduction to electrochemistry in chemistry for grade 12.

Explanation of electrochemical cells, including galvanic cells and electrolytic cells.

Definition of electrochemical cells as tools that can produce electrical energy from chemical reactions or use electrical energy to drive chemical reactions.

Understanding redox reactions is essential before studying electrochemical cells.

A galvanic cell generates electrical energy due to spontaneous redox reactions.

An electrolytic cell uses electrical energy to drive non-spontaneous redox reactions.

Both galvanic and electrolytic cells use electrodes: cathodes and anodes.

Cathodes are where reduction reactions occur, and anodes are where oxidation reactions occur.

Electrolytes are used in both types of cells, which can be in liquid or aqueous form.

Differences between galvanic and electrolytic cells include the direction of energy conversion.

In a galvanic cell, the cathode is positive, and the anode is negative, while in an electrolytic cell, it is the opposite.

Reactions in a galvanic cell are spontaneous with a positive or greater than zero electromotive force (EMF), while in an electrolytic cell, reactions are non-spontaneous with an EMF less than zero.

Practical applications of galvanic cells include batteries and accumulators.

Electrolytic cells are used in metal refining and deposition processes.

Design of a galvanic cell involves two separate compartments containing electrolyte solutions and electrodes.

In a galvanic cell, zinc acts as the anode (negative electrode), and copper acts as the cathode (positive electrode).

The galvanic cell operates by the flow of electrons from the anode to the cathode, creating an electric current.

Salt bridges are used in galvanic cells to balance the charge of cations and anions.

Design of an electrolytic cell involves a single compartment with an electrolyte and two electrodes connected to a power source.

In an electrolytic cell, the electrode connected to the positive terminal of the power source is the anode, and the one connected to the negative terminal is the cathode.

The electrolytic cell forces non-spontaneous reactions by directing the flow of electrons from the cathode to the anode.

The video concludes with a summary and a thank you note in Arabic.

Transcripts

play00:00

Halo

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Assalamualaikum Halo adik-adik ketemu

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lagi dengan Kakak di channel kinematika

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di video kali ini kita akan belajar

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materi kimia kelas 12 yaitu tentang sel

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elektrokimia mana pada bagian ini yang

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akan kita bahas adalah persamaan dan

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perbedaan antara sel volta dengan sel

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elektrolisis Apa itu sel elektrokimia

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sel elektrokimia adalah suatu alat yang

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mampu menghasilkan energi listrik atau

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arus listrik dari reaksi kimia yaitu

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redoks atau menggunakan energi listrik

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untuk menjalankan reaksi kimia yaitu

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reaksi redoks nah Berarti sebelum kita

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mempelajari materi tentang sel

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elektrokimia ini kita harus paham dulu

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ya tentang materi reaksi redoks atau

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reduksi oksidasi Kemudian dari

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pengertian ini sel elektrokimia

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dibedakan menjadi dua

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Hai yang pertama adalah sel volta yaitu

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sel elektrokimia yang menghasilkan

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energi listrik atau arus listrik karena

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adanya reaksi redoks spontan

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jadi di dalam sel volta terjadi

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perubahan energi kimia menjadi energi

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listrik

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kemudian yang kedua adalah sel

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elektrolisis yaitu sel elektrokimia yang

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menguraikan suatu elektrolit karena

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adanya arus listrik jadi pada sel

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elektrolisis

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terjadi perubahan energi listrik menjadi

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energi kimia yaitu reaksi

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reduksi-oksidasi

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Oke jelas ya Nah sekarang kita akan

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membahas Apa persamaan dan perbedaan

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serta Bagaimana susunan atau rangkaian

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dari kedua sel ini kita lihat

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persamaannya dulu ya

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Persamaan sel volta dengan sel

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elektrolisis yang pertama adalah Sel

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Utara dan sel elektrolisis sama-sama

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menggunakan elektroda yaitu katoda dan

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anoda

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dimana pada katoda akan terjadi Reaksi

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reduksi dan pada anoda Terjadi reaksi

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oksidasi Nah agar mudah mengingatnya dan

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tidak terbalik kita bisa mengikatnya

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dengan kata Craw

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katoda reduksi dan dianoda oksidasi Oke

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kita lanjut persamaan yang kedua adalah

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sama-sama menggunakan elektrolit nah

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elektrolit yang digunakan dapat berupa

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larutan atau aqous maupun lelehan atau

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Liquid Oke jelas ya sekarang kita lanjut

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lagi ke perbedaan antara sel volta

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dengan sel elektrolisis perbedaan sel

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volta dengan sel elektrolisis yang

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pertama di awal tadi sudah kita bahas ya

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bahwa sel volta adalah alat sel yang

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dapat mengubah energi kimia yaitu reaksi

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redoks menjadi arus listrik sedangkan

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sel elektrolisis kebalikannya yaitu sel

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yang mengubah arus listrik atau energi

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listrik menjadi reaksi kimia yaitu

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reaksi redoks kemudian perbedaan yang

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kedua pada sel volta katoda merupakan

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kutub positif dan anoda merupakan kutub

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negatif sedangkan pada sel elektrolisis

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kebalikannya katoda merupakan kutub

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negatif dan anoda merupakan kutub

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positif nah cara mudah membedakan dan

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mengingatnya pada sel volta bisa kita

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singkat dengan Kapan volt yaitu katoda

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positif anoda negatif pada sel volta

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Kemudian pada sel elektrolisis bisa kita

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singkat dengan kenapa

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Hai yaitu katoda negatif anoda positif

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pada sel elektrolisis

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Ok lanjut ke perbedaan yang ketiga pada

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sel volta Reaksi yang terjadi merupakan

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reaksi spontan sehingga beda potensial

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listrik atau Enno selnya bernilai

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positif atau besar dari nol Sedangkan

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untuk sel elektrolisis kebalikannya ya

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yaitu reaksi tidak spontan dan nilai

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Enno selnya kecil dari nol atau bernilai

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negatif

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berikutnya perbedaan yang keempat yaitu

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pada penerapan dalam kehidupan

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sehari-hari untuk sel volta diantaranya

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pada Aki dan baterai Kemudian untuk sel

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elektrolisis penerapannya yaitu pada

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proses penyepuhan dan pemurnian logam

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Oke bisa dipahami ya sekarang kita

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lanjut lagi ke perbedaan antara

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rangkaian sel volta dengan rangkaian sel

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tips kita bahas rangkaian sel volta dulu

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rangkaian sel volta dapat dirancang

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dengan menggunakan dua tempat atau

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bagian masing-masing tempat atau bagian

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ini merupakan setengah sel yaitu tempat

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terjadinya setengah reaksi reduksi dan

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bagian satu lagi tempat terjadinya

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setengah reaksi oksidasi

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kemudian masing-masing tempat atau wadah

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ini berisi larutan elektrolit contoh

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pada wadah sebelah kiri berisi larutan

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znso4 yang mengandung ion zat N2 + dan

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ion so4 2min dan wadah yang sebelah

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kanan mengandung larutan elektrolit

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CuSO4 yang mengandung ion CO2 + dan so4

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2min

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selanjutnya kedua elektrolit ini

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masing-masing dicelupkan elektroda yaitu

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elektroda ZN dan elektroda Cu dimana

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logam ZN sebagai anoda yang merupakan

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kutub negatif slogan jauh sebagai katoda

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yang merupakan kutub positif Nah

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selanjutnya kedua elektroda ini

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dihubungkan oleh rangkaian luar yaitu

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kawat konduktor disertai voltmeter

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voltmeter berfungsi untuk mengukur

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tegangan yang dihasilkan dari proses

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reaksi redoks pada sel volta lalu

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Bagaimana prinsip kerja sehingga sel

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volta ini dapat menghasilkan arus

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listrik ingat pada sel elektrokimia

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katoda merupakan tempat terjadinya

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reaksi reduksi dan anoda tempat

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terjadinya reaksi oksidasi nah yang

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mengalami oksidasi atau pelepasan

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elektron di anoda adalah ZN ini sendiri

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jadi logam ZN ini meluruh dengan reaksi

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ZN menjadi zat N2 + 2 elektron ZN yang

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dihasilkan akan bergabung ke larutan

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elektrolit znso4

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sedangkan elektron yang dilepaskan akan

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ngalir melalui kawat konduktor menuju

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katoda selanjutnya di katoda ini ion

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ca12 akan menangkap elektron yang

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berasal dari anoda sehingga terjadilah

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Reaksi reduksi yaitu CO2 + ditambah dua

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elektron menghasilkan C nah CPU yang

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dihasilkan disini akan mengendap di

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katoda

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sekarang kita perhatikan pada wajah

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sebelah kiri jumlah kation atau jumlah

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ion positif itu semakin banyak karena

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adanya tambahan dari hasil oksidasi

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logam ZR sebaliknya pada wadah sebelah

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kanan kation atau ion CO2 + itu semakin

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berkurang karena menangkap elektron atau

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mengalami Reaksi reduksi sehingga

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mengendap menjadi logam Cu Nah untuk

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menyeimbangkan jumlah Kation dan

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anionnya maka pada sel volta juga

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terdapat rangkaian dalam yaitu setan

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garam jembatan garam adalah berupa pipa

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u yang dibalik yang berisi larutan garam

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seperti KCL nano3 atau garam lainnya nah

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pada contoh ini larutan garamnya adalah

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larutan KCL yang mengandung ion K plus

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dan ion CL Min dimana ion K plus akan

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bergerak ke arah katoda untuk

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menetralkan ion so4 2min yang berlebih

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karena berkurangnya CO2 + setelah

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tereduksi menjadi logam Cu dan ion CL

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Min akan bergerak ke arah anoda untuk

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menetralkan ion ZN 2plus yang berlebih

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dari hasil oksidasi jadi karenanya

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reaksi redoks dapat terus berlangsung

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dan terjadi aliran elektron dari anoda

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ke katoda sehingga menghasilkan arus

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listrik Oke bisa dipahami ya sekarang

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kita lanjut ke rangkaian sel

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elektrolisis sel elektrolisis dirancang

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satu wadah yang berisi elektrolit dan

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dicelupkan dua elektroda kemudian kedua

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elektroda ini dihubungkan pada sumber

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arus listrik elektroda yang terhubung

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dengan kutub positif sumber arus adalah

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anoda sedangkan elektroda yang terhubung

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dengan kutub negatif sumber arus adalah

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katoda kemudian elektron dari kutub

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negatif sumber arus akan mengalir menuju

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katoda akibatnya ion positif akan

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tertarik ke katoda dan di katoda akan

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terjadi Reaksi reduksi sementara ion

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negatif akan tertarik ke anoda dan di

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anoda akan terjadi reaksi oksidasi nah

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elektron yang dihasilkan dari reaksi

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oksidasi akan diteruskan ke kutub

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positif sumber arus jadi pada sel

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elektrolisis ini Reaksi yang terjadi

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tidak spontan ya Nah untuk menentukan

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ion yo elektroda mana yang mengalami

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Reaksi reduksi dan oksidasi akan kita

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bahas lebih lanjut pada video tentang

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sel elektrolisis ya oke sekian dulu

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untuk video kali ini terima kasih

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wassalamualaikum warahmatullahi

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wabarakatuh

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Related Tags
ElectrochemistryVoltaic CellsElectrolysisChemical ReactionsElectrical EnergyRedox ReactionsEducational ContentScience LearningChemistry ClassElectrical Current