How To Name Ionic Compounds With Transition Metals

The Organic Chemistry Tutor
7 Aug 201713:32

Summary

TLDRThis educational video script focuses on the nomenclature of ionic compounds, including binary compounds, those with polyatomic ions, and those involving transition metals that require Roman numerals. The script explains how to name simple ionic compounds like NaCl (sodium chloride) and MgBr2 (magnesium bromide), and progresses to more complex examples with polyatomic ions such as sulfate and carbonate. It also addresses the naming of compounds with variable charges, using Roman numerals to denote the oxidation state of transition metals. The script serves as a comprehensive guide for students to understand and memorize the naming conventions for ionic compounds in chemistry.

Takeaways

  • πŸ” Ionic compounds are named differently from molecular compounds, with the former being composed of metals and non-metals.
  • πŸ“š The naming of ionic compounds does not require prefixes like 'mono-', 'di-', 'tri-', etc., which are used for molecular compounds.
  • 🧩 For binary ionic compounds, the metal is named first followed by the non-metal with the suffix '-ide'.
  • 🌐 Examples include NaCl being named 'sodium chloride' and MgBr2 as 'magnesium bromide'.
  • πŸ”¬ When naming compounds with polyatomic ions, one must memorize the names of these ions as they are not derived from the periodic table.
  • πŸ“– The script suggests referring to a 'polyatomic ion sheet' or a related video for common polyatomic ions.
  • πŸ”‹ For compounds with variable charges, like transition metals, roman numerals are used to denote the charge of the metal.
  • βš–οΈ The total charge of the compound must be neutral, with the sum of the charges balancing out to zero.
  • πŸ“ Roman numerals are used to indicate the charge of metals in compounds, with examples provided for iron, copper, chromium, and tin compounds.
  • πŸ“˜ The video provides a brief tutorial on roman numerals, which are essential for naming compounds with transition metals.
  • πŸ“ Examples are given for naming compounds with multiple charges, such as 'iron(II) chloride' and 'iron(III) chloride'.

Q & A

  • What is the difference between naming ionic and molecular compounds?

    -Ionic compounds are composed of a metal and a non-metal and do not use prefixes like mono, di, tri, etc., whereas molecular compounds typically consist of two nonmetals and use these prefixes to indicate the number of atoms.

  • How do you name a binary ionic compound like NaCl?

    -For NaCl, the metal 'Na' is named as 'sodium' and the non-metal 'Cl' is named as 'chloride', resulting in the compound name 'sodium chloride'.

  • What is the name of the compound MgBr2?

    -MgBr2 is named 'magnesium bromide', where 'Mg' stands for magnesium and 'Br' is named as 'bromide'.

  • How do you name a compound with a polyatomic ion like SO4?

    -For compounds with polyatomic ions, you need to memorize the names of these ions. SO4 is named 'sulfate'.

  • What is the name of the compound Li2SO4?

    -Li2SO4 is called 'lithium sulfate', where 'Li' is lithium and 'SO4' is sulfate.

  • How do you determine the name of a compound with a transition metal and variable charges, such as FeCl2?

    -For transition metals with variable charges, you use Roman numerals to specify the charge. FeCl2 is named 'iron(II) chloride' because iron has a +2 charge to balance the two chloride ions each with a -1 charge.

  • What is the significance of Roman numerals in naming ionic compounds with transition metals?

    -Roman numerals are used to indicate the oxidation state of transition metals in ionic compounds, which helps distinguish between different compounds with the same metal but different charges.

  • How do you name a compound like CuBr?

    -CuBr is named 'copper(I) bromide', where 'Cu' is copper with a +1 charge and 'Br' is bromide.

  • What is the name of the compound Cr2S3?

    -Cr2S3 is called 'chromium(III) sulfide', where each chromium ion has a +3 charge to balance the three sulfide ions each with a -2 charge.

  • Can you provide an example of how to name a compound with multiple polyatomic ions, such as PbCO3(2-)?

    -PbCO3(2-) is named 'lead(II) carbonate', where 'Pb' is lead with a +2 charge to balance the two carbonate ions each with a -2 charge.

Outlines

00:00

πŸ§ͺ Basic Principles of Naming Ionic Compounds

This paragraph introduces the basics of naming ionic compounds, which are composed of metals and non-metals, as opposed to molecular compounds made of nonmetals. It emphasizes the importance of distinguishing between ionic and molecular compounds due to their different naming conventions. The paragraph explains how to name simple binary ionic compounds like NaCl (sodium chloride), MgBr2 (magnesium bromide), AlF3 (aluminum fluoride), and CaO (calcium oxide) by identifying the metal and non-metal elements and adding appropriate suffixes like '-ide' to the non-metal's name.

05:03

πŸ”¬ Naming Compounds with Polyatomic Ions

The second paragraph delves into the naming of ionic compounds that contain polyatomic ions, which cannot be named using the periodic table and must be memorized or referred to a polyatomic ion sheet. Examples given include Li2SO4 (lithium sulfate), Na2CO3 (sodium carbonate), Ba(OH)2 (barium hydroxide), and K2C2H3O2 (potassium acetate). The paragraph advises memorizing common polyatomic ions for ease in naming such compounds and suggests a video resource for learning these names.

10:07

🌟 Naming Compounds with Transition Metals and Variable Charges

The final paragraph addresses the naming of ionic compounds involving transition metals with variable charges, where Roman numerals are used to denote the metal's oxidation state. It explains the process of determining the charge of the metal in compounds like FeCl2 (iron(II) chloride) and FeCl3 (iron(III) chloride) by balancing the total charges of the ions. The paragraph also covers other examples such as CuBr (copper(I) bromide), CuBr2 (copper(II) bromide), Cr2S3 (chromium(III) sulfide), SnO (tin(II) oxide), SnO2 (tin(IV) oxide), PbSO4 (lead(II) sulfate), and PbCO3 (lead(IV) carbonate). It concludes with a brief tutorial on Roman numerals, which are essential for naming such compounds.

Mindmap

Keywords

πŸ’‘Ionic Compounds

Ionic compounds are formed by the electrostatic attraction between positive and negative ions, typically a metal and a non-metal. They are distinct from molecular compounds, which are composed of molecules held together by covalent bonds. In the video, the focus is on naming these compounds correctly, which is crucial for understanding their composition and properties. Examples from the script include NaCl (sodium chloride) and MgBr2 (magnesium bromide).

πŸ’‘Binary Ionic Compounds

Binary ionic compounds consist of two different elements, one being a metal and the other a non-metal, forming an ionic bond. The script explains that these compounds are named by combining the name of the metal with the suffix '-ide' for the non-metal, as seen in the examples of NaCl named as sodium chloride and MgBr2 as magnesium bromide.

πŸ’‘Polyatomic Ions

Polyatomic ions are groups of two or more atoms that have a net charge and act as a single ion. They are an essential part of complex ionic compounds and require memorization as their names are not derived from the periodic table. The script mentions that these ions have specific names, such as sulfate (SO4) and carbonate (CO3), which are crucial for correctly naming compounds containing them.

πŸ’‘Transition Metals

Transition metals are a group of elements in the periodic table known for their ability to form multiple oxidation states. The video explains that when naming ionic compounds containing transition metals, Roman numerals are used to indicate the metal's charge. This is demonstrated with FeCl2 being named iron(II) chloride and FeCl3 as iron(III) chloride.

πŸ’‘Roman Numerals

Roman numerals are used in chemistry to denote the oxidation state of elements, particularly in ionic compounds with transition metals. The script provides examples of how to use Roman numerals to distinguish between different compounds of the same metal with varying charges, such as in the case of FeCl2 (iron(II) chloride) and FeCl3 (iron(III) chloride).

πŸ’‘Oxides

Oxides are a type of compound that consists of oxygen and one other element. The script explains that oxides are named by combining the name of the other element with the suffix '-oxide'. For example, CaO is named calcium oxide, indicating the compound's composition of calcium and oxygen.

πŸ’‘Hydride

A hydride is a compound formed by the combination of hydrogen with another element. In the context of the video, hydrides are named by adding the suffix '-ide' to the name of the element combined with hydrogen, as seen in the example of Ba(OH)2, which is named barium hydroxide.

πŸ’‘Nitrides

Nitrides are compounds consisting of nitrogen and another element. The video script uses the example of Sr3N2, which is named strontium nitride, to illustrate the naming convention for nitrides, where the metal's name is followed by 'nitride'.

πŸ’‘Sulfides

Sulfides are compounds made up of sulfur combined with a metal. The script explains that sulfides are named by adding the suffix '-ide' to 'sulfur', resulting in 'sulfide'. An example given is BaS, which is named barium sulfide, following the naming pattern for sulfides.

πŸ’‘Perchlorates

Perchlorates are a type of compound containing the perchlorate ion (ClO4-). The video mentions that perchlorates are named by combining the name of the metal with 'perchlorate'. For instance, Zn(ClO4)2 is named zinc perchlorate, reflecting the presence of the perchlorate ion in the compound.

πŸ’‘Ammonium

Ammonium is a polyatomic ion with the formula NH4+. The video script explains that compounds containing the ammonium ion are named by prefixing the rest of the compound's name with 'ammonium'. An example provided is NH4NO3, which is named ammonium nitrate, indicating the presence of the ammonium ion.

Highlights

Introduction to naming ionic compounds, focusing on binary ionic compounds, those with polyatomic ions, and those with transition metals.

Explanation of how to write the name of NaCl, emphasizing the distinction between ionic and molecular compounds.

Guidelines for naming ionic compounds without using prefixes like mono, di, tri, etc.

Naming MgBr2 as magnesium bromide, illustrating the process for compounds with a single metal and non-metal.

AlF3 is named aluminum fluoride, demonstrating the naming of compounds with polyatomic ions.

CaO is named calcium oxide, showing the naming of compounds with oxygen.

Naming Sr3N2 as strontium nitride, explaining the process for compounds with transition metals.

BaS is named barium sulfide, another example of naming compounds with transition metals.

The importance of memorizing polyatomic ions for chemistry courses.

Li2SO4 is named lithium sulfate, highlighting the naming of compounds with polyatomic ions.

Na2CO3 is named sodium carbonate, further illustrating the naming of compounds with polyatomic ions.

Ba(OH)2 is named barium hydroxide, demonstrating the naming of hydroxides.

KC2H3O2 is named potassium acetate, showing the naming of compounds with organic polyatomic ions.

Zn(ClO4)2 is named zinc perchlorate, discussing the naming of perchlorates.

NH4NO3 is named ammonium nitrate, explaining the naming of ammonium compounds.

FeCl2 is named iron(II) chloride, using Roman numerals to specify the charge of transition metals.

FeCl3 is named iron(III) chloride, further demonstrating the use of Roman numerals for variable charges.

CuBr and CuBr2 are named copper(I) bromide and copper(II) bromide, respectively, showing the naming of copper compounds.

CrS and Cr2S3 are named chromium(II) sulfide and chromium(III) sulfide, respectively, illustrating the naming of chromium compounds.

SnO and SnO2 are named tin(II) oxide and tin(IV) oxide, respectively, discussing the naming of tin compounds.

Basic tutorial on Roman numerals for chemistry, including how to write numbers one through seven.

PbSO4 is named lead(II) sulfate, showing the naming of lead compounds with sulfate ions.

PbCO3 is named lead(II) carbonate, demonstrating the naming of lead compounds with carbonate ions.

Conclusion of the video, summarizing the method for naming ionic compounds.

Transcripts

play00:01

in this video we're going to focus on

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naming ionic compounds

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this is going to be binary ionic

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compounds

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those with polyatomic ions

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and those with transition metals where

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you have to incorporate the roman

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numerals

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so let's begin

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let's start with the basics how can we

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write the name of nacl so if we're given

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the chemical formula how can we write

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the name of this compound

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so it's an ionic compound

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and ionic compounds are composed of a

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metal and a non-metal you need to

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distinguish it from molecular compounds

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because the naming system is different

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for molecular compounds typically not

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all the time but most of the time it's

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consistent of two nonmetals and you have

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to use rules like monodye triad tetra

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and things like that but when you have

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an ionic compound you don't need to use

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the prefixes mono diatrite tetra so keep

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that in mind

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so what you need to do is name the first

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element

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n a is called sodium

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now the second element instead of

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calling it chlorine you're going to add

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the end in chloride

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so it's called

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sodium

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chloride

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let's try another example

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so let's say if we want to write the

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name of mgbr2

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so first use the periodic table to

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identify mg

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mg

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is called magnesium

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and then you look at the second element

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on a periodic table it's called bromine

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but

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instead of saying bromine we're going to

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add the suffix eyed so it's going to be

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bromide

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so to name it it's simply called

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magnesium

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bromide

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let's try some more examples

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alf 3

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and cao

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so al stands for aluminum

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f represents fluorine

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but we're going to say fluoride so alf 3

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is called

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aluminum

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fluoride

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now what about cao what is the name for

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that

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ca stands for calcium

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and the o represents oxygen

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but we're going to say oxide so this is

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called calcium

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oxide

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now let's try two more examples

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write the chemical names of

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sr3 n2 and bas

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so sr stands for strontium

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n

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represents nitrogen

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so this is going to be called strontium

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nitride

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now what about the last one bas

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the a is associated with the element

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barium

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s is sulfur but we're going to change it

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to sulfide

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so barium sulfide

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so that's how you can name binary ionic

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compounds

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now sometimes

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you might be given an ionic compound

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that contains a polyatomic ion

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and the periodic table won't help you

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much in this case at least for the

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polyatomic ion you simply have to commit

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it to memory if you're fortunate your

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teacher is going to give you the

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polyatomic ion sheet and so you could

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just use that look it up

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if not you have to commit it to memory

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so

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you're going to need it for the rest of

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your chemistry course i would advise you

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just to memorize it and it's just going

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to make life easier

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so let's start with li2 so4

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and na2

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co3

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so how can we name this substance

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li you could look that up in a periodic

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table that's a lithium

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now so4 is a polyatomic ion it has a

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single name

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the periodic table won't help you with

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that you need to look it up in your

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polyatomic ion sheet

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so4 is simply called sulfate

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and that is something you just have to

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know

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now there's a video

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in which i made that goes over the

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common polyatomic ions that you need to

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look for just look it up on youtube you

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should be able to find it

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and it's just

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it'll help you to like understand

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how to name certain polyatomic ions so

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it's easier for you to memorize it it

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helps you to get a better understanding

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of the naming system

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na2co3 na represents sodium

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co3 is called carbonate

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so combined it's sodium carbonate

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here's another one

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name this one baoh2

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and kc2h3oh2

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or just o2

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ba

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is barium

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and oh when you see it

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it's known as hydroxide so this is going

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to be called barium

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hydroxide

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now what about the next example

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what does k stand for

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k

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is called potassium

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and

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c2h3o2 that's a single polyatomic ion

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known as acetate

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so combine this is potassium

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acetate

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now i'm going to give you two more

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examples with polyatomic ions

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go ahead and name this one

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and also

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nh4

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no3

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zn stands for zinc

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clo4 is known as perchlorate

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so collectively

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this is zinc per chlorine

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now the last one

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it's ionic compound even though it

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doesn't have a metal inside of it

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nh4

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that's known as ammonium that's a

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polyatomic ion

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no3

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is another polyatomic ion which is

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called nitrate so combined

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this is ammonium nitrate

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consider these two compounds

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fecl2

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and fecl3

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how can we name

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these two compounds

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fe

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stands for iron

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and cl

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is going to be chloride instead of

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chlorine

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but now how is this going to be

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different from the other one because the

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other one is also iron chloride

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so we need a way

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to distinguish

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fecl2

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from fecl3

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it turns out that certain transition

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metals have multiple charges

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and so you need to use roman numerals to

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specify

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the charge of the transition metal

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there are certain metals that are not

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transition metals that also have

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multiple charges and you would still use

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the roman numeral system for it

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so what we need to do is figure out the

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charge of fe and fecl2

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now the charge of a single chloride ion

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is negative one

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and in this example

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there are two of them

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so the total negative charge is negative

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two

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therefore fe

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has to have a positive two charge to

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neutralize

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the negative two charge from the two

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chloride ions

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so therefore since the charge in fe is

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positive two

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this is called

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iron two chloride

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now in the next example

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we have three chloride ions so the total

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charge is negative three

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which means the total charge from fe has

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to be positive three

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the net charge has to add up to zero

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because there's no charge on fecl3

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so therefore this is going to be called

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iron

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3

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chloride

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and that's how you can name

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ionic compounds that

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have metals with variable charges

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let's look at another example

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cubr

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and

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cubr2

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go ahead and name these two compounds

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now let's start with cubr

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bromide has a negative one charge and

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there's only one of them

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so copper has to balance that negative

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one charge so it must have a plus one

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charge

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so therefore this is going to be called

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copper

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one

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bromide because it has a plus one charge

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now what about the second example

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what's the name for it

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well in this case we have two

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bromide ions so the total charge is

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negative two so therefore copper has to

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have a plus two charge

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to balance the two negative charges so

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it's going to be copper

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two

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bromide now what about crs

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and cr2 s3

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go ahead and try those two examples

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so let's find the charge on sulfur

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sulfur has a negative two charge

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which means in this example chromium has

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to have a plus two charge

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so this is going to be called

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chromium

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two sulfide

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now for the second example

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there's three sulfide ions

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so the total negative charge is negative

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six

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which means the total positive charge

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has to be positive six

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now there's two chromium ions

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so for the total charge to add up to

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plus six each of these chromium ions

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have to have a plus three charge so

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therefore this is going to be called

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chromium

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sulfide

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so hopefully these examples are helping

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to get a good idea of how to name these

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types of ionic compounds

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try this sno and sno2

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oxygen has a minus two charge

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so tin

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has to have a plus two charge

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so the first one is called

play11:00

tin

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ii

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oxide

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now let's move on to our next example

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so this time there's two oxide ions with

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a total negative charge of negative four

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but there's only one tin atom

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so therefore it has to have a plus four

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charge

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so this is going to be called tin

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four

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oxide

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now for those of you who need to review

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the roman numeral system here's some

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basics

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this is one

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this is two

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this represents three

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now this is five

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now if you put the i symbol to the left

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of the five

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it really means subtraction like five

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minus one so this is four

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if you put it to the right of the five

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it means addition five plus one is six

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so if you want to write seven put two

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eyes to the right of the v

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so that represents seven

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so just a basic tutorial of roman

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numerals in the course of

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this class

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you don't really need to go past seven i

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haven't seen any examples beyond that so

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if you know these numbers you should be

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good

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now let's try this one pbso4

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and pb

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co3 2.

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so4 is sulfate and it has a negative two

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charge which means pb has to have a

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positive two charge so this is going to

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be called

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lead

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to

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sulfate

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now for the last example

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carbonate

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has a minus two charge

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but there's two carbonate ions in that

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compound so the total negative charge is

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negative four

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and there's only one pb atom so it has

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to bear the entire positive 4 charge

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so this is going to be called

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lead

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4

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carbonate

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and that is it for this video

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so now you know how to name

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ionic compounds

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you

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Chemical NomenclatureIonic CompoundsPolyatomic IonsTransition MetalsRoman NumeralsChemistry TutorialNaming CompoundsChemical FormulasEducational ContentScience Learning