The World of Chemistry: A Matter of State
Summary
TLDREl misterio de los tres estados de la materia, gaseoso, líquido y sólido, es explorado en este guion. Se explica cómo la temperatura y la presión influyen en la transformación entre estados, demostrando con experimentos cómo el agua se convierte en vapor y viceversa. Además, se aborda la importancia de la liquefacción de gases como el metano para el almacenamiento y transporte eficiente, y se introduce el concepto de cristales como una forma altamente organizada de la materia sólida, proporcionando una visión detallada de cómo los cambios de estado están intrínsecamente ligados a la energía y el movimiento de partículas a nivel submicroscópico.
Takeaways
- 🌡️ La química comienza con la idea de que la materia puede existir en tres estados: gas, líquido y sólido, y estos estados pueden cambiar entre sí.
- 💧 Los gases son tenues y comprimibles, mientras que los líquidos son fluidos y deformables, y los sólidos son más compactos y a menudo más densos.
- 🔥 La temperatura es un factor clave en la transformación de la materia de un estado a otro, como se muestra cuando el agua se convierte en vapor al calentarse y en hielo al enfriarse.
- 💨 Al aumentar la temperatura de un gas, su presión también aumenta, lo que se demuestra al calentar un contenedor rígido y observar cómo sube la presión.
- ❄️ Al enfriar un gas, su presión disminuye, lo cual se puede ver cuando se enfría un contenedor con gas y se reduce la presión interna.
- 🌋 La transformación de la materia de un estado a otro es posible debido a cambios en la energía cinética de sus partículas a través de procesos de calentamiento y enfriamiento.
- 🚀 La liquefacción de gases como el metano mejora su capacidad de almacenamiento y transporte, ya que su volumen se reduce significativamente.
- 🔬 Los cristales son una forma de sólido altamente organizada donde los elementos químicos están ordenados en un patrón que se repite en tres dimensiones.
- 🔬 La observación de cristales como el cuarzo proporcionó una de las primeras pistas sobre la naturaleza de la materia sólida y la disposición de partículas en el estado sólido.
- 🌟 La comprensión de los estados de la materia y sus cambios es fundamental para procesos industriales, el almacenamiento de gases y la investigación científica en áreas como la cristalografía.
Q & A
¿Qué son los estados de la materia mencionados en el guion?
-Los estados de la materia mencionados son sólido, líquido y gas.
¿Qué ocurre cuando la materia cambia de un estado a otro?
-El cambio de estado ocurre por variaciones de temperatura o presión, lo que afecta el comportamiento de las partículas de la materia.
¿Qué relación hay entre la temperatura y el estado de la materia?
-La temperatura afecta la energía cinética de las partículas; al aumentar la temperatura, las partículas se mueven más rápido y pueden cambiar de sólido a líquido o de líquido a gas.
¿Qué sucede cuando el gas se enfría significativamente?
-Cuando un gas se enfría lo suficiente, las partículas pierden energía, se ralentizan y el gas se condensa en un líquido. Si se enfría más, el líquido se solidifica.
¿Qué demuestra el experimento con el balón de acero y el calentador?
-El experimento muestra que cuando el gas en el balón de acero se calienta, su presión aumenta debido al incremento de la velocidad de las partículas. Cuando se enfría, la presión disminuye.
¿Cómo se explica el colapso de la lata en el experimento?
-El colapso ocurre porque al enfriar el vapor dentro de la lata, se reduce la presión interna, lo que hace que la presión atmosférica externa aplaste la lata.
¿Qué es la licuefacción del gas natural y por qué es importante?
-La licuefacción es el proceso de enfriar el gas natural a temperaturas extremadamente bajas para convertirlo en líquido. Es importante porque reduce su volumen y facilita su almacenamiento y transporte.
¿Cómo afectan los cambios de temperatura a las propiedades de los materiales, según el experimento con las pelotas de goma?
-El enfriamiento extremo con nitrógeno líquido endureció las pelotas, volviéndolas frágiles. Al regresar a la temperatura ambiente, las pelotas recuperaron su flexibilidad.
¿Qué ocurre a nivel microscópico cuando un gas se convierte en líquido y luego en sólido?
-Las partículas de gas, al enfriarse, pierden energía, se agrupan por fuerzas de atracción y forman un líquido. Al enfriarse aún más, estas partículas se ordenan en una estructura rígida, formando un sólido.
¿Qué se menciona sobre las estructuras de los cristales y su relevancia científica?
-Los cristales tienen una estructura altamente ordenada que refleja la disposición precisa de los elementos químicos, proporcionando una visión única sobre la naturaleza de la materia en estado sólido.
Outlines
🌟 Estado de la Materia y Transformaciones
Este párrafo introduce el misterio de los tres estados de la materia: gas, líquido y sólido, y cómo estos pueden interconvertirse. Se explica que todo en nuestro mundo está en uno de estos estados y que la química comienza con esta idea fundamental. Se utiliza el Gran Salto del Río Potomac como ejemplo de cómo la roca, el agua y el aire están en diferentes estados de la materia. Se menciona que la temperatura es clave para entender estas transformaciones de estado.
🔥 El Efecto de la Temperatura y la Presión
Se explora cómo la temperatura afecta la presión y, por ende, el estado de la materia. Se realiza un experimento con un frasco de agua que se calienta hasta que el agua se transforma en vapor, aumentando la presión y causando que el frasco se hinche. Al disminuir la temperatura, el vapor se condensa en líquido y la presión disminuye, lo que hace que el frasco se encogue debido a la presión atmosférica externa. Se usa un aparato para demostrar la relación directa entre la temperatura y la presión de un gas: al aumentar la temperatura, aumenta la presión, y al disminuirla, disminuye la presión.
💧 Liquefaction de Gas y su Importancia
Se discute la importancia de la liquefaction de gases, como el metano o gas natural, para aumentar la capacidad de almacenamiento y facilitar el transporte. Se describe el proceso de liquefaction en tres pasos: enfriar el gas para congelar el vapor de agua, filtrar impurezas y enfriar aún más para convertir el gas en líquido. Se menciona que el almacenamiento de gas natural licuado (GNL) es mucho más eficiente que en su estado gaseoso y se puede transportar fácilmente. Además, se muestra cómo el nitrógeno líquido, a una temperatura extremadamente baja, puede cambiar las propiedades temporales de objetos como bolas de raquetas.
🌡 Cambios de Estado y su Impacto en la Vida Cotidiana
Se explica cómo los cambios de estado de la materia, particularmente la evaporación, afectan nuestra vida diaria, como cuando sudamos para enfriarnos. Se menciona que el proceso de evaporación requiere energía que se toma de nuestro cuerpo, lo que produce la sensación de frescura. Se introduce la idea de que estos cambios de estado tienen un origen en el comportamiento de partículas a nivel microscópico, como átomos y moléculas.
💠 Los Cristales y su Orden Microscópico
Se aborda la naturaleza altamente organizada de los cristales como una forma de sólido. Se describe cómo los cristales proporcionan una visión de cómo los átomos están organizados en la materia sólida, con arreglos repetitivos en tres dimensiones. Se destaca la belleza y la fuerza de los cristales, así como su importancia en la comprensión de la naturaleza de los elementos químicos. Se menciona la colección de cristales raros en el Museo Smithsonian y se concluye con la idea de que los cristales son una ventana a la organización de la materia.
🔬 La Naturaleza de la Materia y sus Estados
Se resume que la materia puede estar en tres estados: gas, líquido y sólido, y que los cambios de estado dependen del movimiento de partículas submicroscópicas. Se destaca que el enfriamiento disminuye el movimiento de las partículas y el calentamiento lo aumenta. Se menciona el uso de gases como el gas natural y cómo la liquefaction reduce su volumen para facilitar su almacenamiento y transporte. Finalmente, se sugiere que los cristales son una forma altamente ordenada de la materia sólida y se alude a la próxima exploración de la naturaleza de los átomos.
Mindmap
Keywords
💡Estados de la materia
💡Temperatura
💡Presión
💡Energía cinética
💡Condensación
💡Liquefacción
💡Cristales
💡Enfriamiento rápido
💡Fuerzas atractivas
💡Cambio de estado
Highlights
Everything in our world exists in one of three states: gas, liquid, or solid.
Matter can change from one state to another.
The transformation of matter's state begins with temperature.
Heating a liquid can change its state to a gas, as seen with heated water turning into steam.
As temperature decreases, the pressure inside a container also decreases, causing the can to cave in.
The relationship between temperature and pressure of a gas is direct: as temperature increases, so does pressure.
Sub-microscopic particles of a gas move faster and collide more frequently with container walls when heated.
Cooling a gas decreases its pressure, and can lead to a change of state to liquid.
Gaseous matter becomes liquid at low enough temperatures, which is crucial for storing gases like oxygen and carbon dioxide.
Liquefying natural gas increases storage capacity by over 600 times.
Liquid nitrogen at -196°C can be used for fast freezing processes without damaging materials.
The process of evaporation cools the skin when sweating by supplying heat from the body.
Bromine can be observed transitioning from gas to liquid to solid as temperature decreases.
Crystals are a highly ordered form of solid matter, providing insight into the arrangement of particles.
Crystals reveal the fundamental nature of solid matter and the behavior of chemical elements.
Matter's states are few, but the variety of substances realizing these states is vast.
The forces between atoms or molecules dictate the state of matter, such as gas for oxygen and solid for sulfur.
Transcripts
there is a mystery to this world around
us
an idea so obvious we take it for
granted but so important that all
chemistry starts from it
everything in our world exists in one of
three states
as a gas
[Music]
a liquid
or a solid but can change from one state
to another
how is this possible
what happens as a solid becomes a liquid
and a liquid a gas
in the world of chemistry it's all a
matter of state
[Music]
the great falls of the potomac river
near washington
everything in the scene around me
the rocks the flowing water the trees on
the other side even the air that i
breathe everything is matter it's
chemical
and even though we see hundreds of
different substances
millions where i to look with a
microscope
these substances fall into certain
groups or classes that we can identify
as gases
liquids and solids
these are the states of matter
gases are tenuous compressible
the space that matter fills we call that
volume is obviously occupied less
densely in gases than it is in the other
states of matter
liquids are fluid
deformable more dense than gases and
solids are more compact still often
denser and it's not only that the states
are there
we or nature can change them
why is a crystal like an iceberg
how is lava like a stream
what does a balloon have in common with
the air around it
the iceberg and the crystal are both in
the solid state
this lava and the water in the stream
are both in the liquid state
the matter inside this balloon and the
air around it are both in the gaseous
state
under certain conditions matter changes
state what makes this transformation
possible
water at one temperature is a liquid at
another temperature a gas at still
another
it is a solid
if we are to begin unraveling the secret
of matter's transformation temperature
is a clue
what is its effect on liquids and
gases let's start out by looking at the
effect temperature has on pressure what
i'm going to do
is heat this can
this is a rigid
can
has some water in the bottom up
now as the water is heated it will
change state
you're very familiar with the term steam
huh steam now is gaseous water
now as that steam is formed from that
liquid liquid to gas
it will drive out the air
that was inside that can and hopefully
we'll be able to see
some of the steam that is coming out of
the top of the can
once we have driven all the air out
what i'm going to do is put the top on
there
and we'll let the can cool
and see what happens
with the pressure
as the temperature decreases
what do you think do you think there's
enough
steam coming out there to indicate that
the all the air has been driven out all
right i'm gonna take the burner off turn
that off
we'll cap this up
all right now
as the temperature decreases
the can cools
that steam will change back into
liquid
as it does that
it will decrease the pressure inside the
can
oh you hear that
as the pressure decreases
what anything happen out here the
atmospheric pressure didn't change
it's pushing on the can just like it was
before
but since the pressure is less
as we decrease the temperature the
pressure decreases
the can starts to cave in
[Music]
there it goes
[Music]
now look at the can notice how the can
is
crushing
the reason now again is because of that
atmospheric pressure the gas of the
atmosphere
inside now the pressure was reduced
because the steam condensed
into that liquid leaving
a decreased pressure inside
the atmospheric pressure pushed in the
can
so heating a liquid can change its state
to a gas and there appears to be a
relationship between the pressure of
matter in the gaseous state and its
temperature
but what is the nature of this
relationship
we'll use this apparatus to try to
understand that relationship between the
temperature and the pressure of a gas
we have a rigid container here this is a
steel ball that's attached to this
pressure gauge
now because it's rigid the amount of gas
inside and the volume of the gas will
remain the same the only things will
vary are pressure and temperature
let's try it and see what happens
all right we'll heat it up using this
burner
so as we increase the temperature of the
gas inside the ball
what happens to the pressure
can you see that pressure what's
happening there
it's increasing isn't it the number is
getting higher
so as we increase the temperature of the
gas
we also increase the pressure
all right now what would happen if we
take the heat away and cool it well
let's see i'll take the burner away and
we'll turn off the gas
and we'll let it cool
well it's not cooling fast enough let me
help it
i've got this this ice water bath so i
stick the ice water bath up there
and we'll cool the ball
and look what happens now to the
pressure
as the temperature decreases the
pressure of a gas also decreases
so we see the relationship between the
temperature and the pressure of a gas
what is happening to the sub-microscopic
particles of a gas as they are heated
and cooled
how does this affect pressure
if we could slow down the gas particles
and focus on just a few of them they
would look like this
far apart moving randomly in straight
lines
when they collide with the walls of the
container they exert a pressure against
the walls
these moving particles possess kinetic
energy
their speed depends on their temperature
as the gas is heated and the particles
move faster
they collide with the walls of the
container more frequently
because they are moving at greater speed
they also strike the walls with greater
force
both effects the greater number of
collisions and the greater force of the
collisions contribute to the increase in
the pressure of the gas when the
temperature is increased
cooling a gas decreases the speed of the
particles
as the temperature is decreased the
kinetic energy of the particles
decreases
they slow down
they strike the walls less frequently
and with less force as we cool a gas
down to a certain point we continue to
decrease its pressure
but if we cool a gas beyond that point
something dramatic happens
the gas changes state to become a liquid
the fact that gaseous matter becomes
liquid matter at a low enough
temperature is important to us
every year we use billions of liters of
different gases
in hospitals pure oxygen helps very ill
patients breathe more easily in soft
drink factories another gas carbon
dioxide gives beverages their fizz
just plain air a mixture of mostly
nitrogen and oxygen is bottled under
high pressure for scuba divers to
breathe underwater
gases are also used in the manufacture
of integrated circuits
the processing of steel
the recovery of oil and many other
places
but the place we are probably most
familiar with is the home where we heat
and cook with a gas cold methane or
natural gas
and we would have a hard time using
natural gas if we couldn't liquefy it at
low enough temperatures
linwood basemore is chief of baltimore
gas and electric's liquid natural gas
facility the primary reason for
liquefying natural gas is
to
give us added storage capacity
capabilities of storing lng are much
greater as a liquid than as a gas
to demonstrate
methane liquefied is reduced in volume
over 600 times we we liquefy during the
summer when our system demands are low
that gas is made available then for
storage
and in the winter months when the demand
is high
we can supplement our supplies with our
own
lng
natural gas is converted to a liquid and
stored at plants like this throughout
the world
liquefaction is a three-step process
the gas comes in through pipelines in a
gaseous state but it contains impurities
like water vapor and carbon dioxide
so the first step is to cool the gas
enough to freeze out the water vapor
this is done in towers that are filled
with coils of a cold liquid similar to
antifreeze
as the natural gas passes over them
water vapor condenses and forms ice
the natural gas then goes to a filter
system that removes other impurities
now the gas is ready to be chilled to a
liquid
the liquefaction process simply
reduces molecular motion
that provides for the condensing of the
material
when we remove the sensible and latent
heat from the methane from 60 degrees
fahrenheit down to -260
molecular motion is essentially
slowed down
the red tanks in this plant contain
natural gas that is waiting to be
liquefied the white tanks contain
liquefied natural gas
the volume occupied by natural gas in
the liquid state is so reduced that one
white tank can hold 125
red tanks
we store lng in essentially what is is
just a large thermos bottle
the tanks are not refrigerated in any
way other than the auto refrigeration
supplied by the liquid within the tanks
the tanks are essentially a tank within
a tank they're
insulated
around a top and bottom
and there's no additional refrigeration
needed
one of the benefits of liquefying
natural gas is that it makes it
essentially portable
methane or natural gas in its natural
state as a gas
must be delivered via connected pipeline
from point a to point b
however in as a liquid
lng can be delivered via truck
rail or even
shipping another advantage of a
liquefied gas is its extremely low
temperature
how cold is it
in this container i have an element that
we're all familiar with but most the
time is a gas
nitrogen only this is liquid nitrogen
and here there's a couple racquetballs
notice how they balance very well
now what will happen to those balls as i
put it in that liquid nitrogen
now this liquid nitrogen is at a
temperature of minus
196 degrees celsius
so the temperature inside there now is
some
225 or so degrees below room temperature
so that ought to change the properties
of those balls that are inside there
quite a bit
well i think the balls have been there
long enough now let's see what happened
i'll put these gloves on because that
liquid nitrogen is very cold i don't
want to
burn my fingers
i'm going to take one ball out
and i'll set it right here and we'll let
that one alone
and i'll take the other one out
and just to show you what this liquid
nitrogen has done because it is so very
cold i'm going to take that ball and hit
it with this hammer
here we go
the ball shatters
so we see now that there has been a
tremendous change
in the properties of that particular
ball because of this low temperature
all right now here's the other bowl it's
warmed up now so i don't need that glove
anymore look
it's back to normal
so this fast freezing process even with
something as cold as liquid nitrogen
really doesn't harm the material it
certainly changes the properties
immediately like this spa that we
shattered but after a while when it
warms up it's back to normal
liquid nitrogen also has many practical
uses
we take fresh food at the grocery store
for granted its delivery depends on
trucks that use liquid nitrogen for
refrigeration cooling the food without
freezing it
other foods are packaged and flash
frozen using liquid nitrogen
and biochemical researchers continue to
develop cryogenic techniques for
freezing living tissue without damaging
it
this work will make it possible to store
whole organs for indefinite periods
we've seen now how matter can change
from a gas to liquid
in a process energy is emitted in a form
of heat that heat has to be taken away
and this is why we cool a gas in order
to liquefy it the reverse process is
that of heating a liquid in order to
make it go into the gaseous state
these energy changes are crucial
and they're also part of our everyday
experience
for instance we can understand now how
it is that we cool off when we sweat and
when someone puts a wet cloth on a brow
of a feverish person
what happens is that water liquid
evaporates goes to water gas
in order to accomplish that heat has to
be supplied to the liquid water
that heat must come from somewhere it
comes from my skin
that is why my skin feels cooled off
when i sweat
these energy changes that we have been
discussing
in the observable macroscopic world of
gases liquids and solids
must find their origin their causes
in the microscopic world of atoms and
molecules
let's take a look at one particular
substance as it moves through the three
states of matter
what you're looking at is a closed
container of bromine see the bromine
liquid here
red dark brown liquid and the bromine
gas filling the rest of the vessel a red
brown gas
i'm going to make use of this liquid
nitrogen again remember it's very cold
minus 196 degrees celsius
to lower
this vessel
so that the
finger end of that gets into the liquid
nitrogen
now what will happen at that temperature
is that bromine
should change
state
so the gas should go into the liquid
and the liquid should go into the solid
so we see all three phases all three
states of matter in action
all right let's wait a little bit and
see what happens now while that while
that flask
cools down
at this stage now we can see all three
states of matter
this is the bromine gas
top part up here the dark material now
is the bromine liquid
and at the very bottom is the yellow
solid of bromine
all three states of matter
we know that as we go from the gas
and decrease the temperature we go to a
liquid we decrease the temperature
further we go to the sun
on the sub-microscopic level the bromine
particles in the gaseous state are
moving quickly and chaotically
as the temperature decreases the
particles slow down until the attractive
forces between them overcome the
randomizing forces of kinetic energy
when these two forces reach a balance
the particles begin to stick together in
clumps
when the clumps become large enough
gravity pulls them down to the bottom of
the container
now the particles are in relatively
close contact attractive forces are
holding them together but they are still
moving
as the liquid becomes colder the
particles lose even more kinetic energy
this results in another change of state
the liquid becomes a solid
now the attractive forces hold the
particles in a regular and ordered form
that extends in three dimensions
crystals are one of the most beautiful
examples of this ordered arrangement of
particles
although they look like they were
fashioned with a sculptor's skill
these formations are completely natural
they come from one of the most extensive
collections of rare crystals in the
world housed in the vaults of the
smithsonian museum
many are too delicate for public display
what gives crystals their unique
appearance
dan appleman is a geologist at the
smithsonian
a crystal is a particular kind of matter
in which the chemical elements which
compose all kinds of matter are very
highly organized they're not just
organized but they're organized into a
very orderly array like a column of
soldiers an extremely ordered form of
matter is what we see when we look at a
crystal what this means is that
within a crystal the chemical elements
are arranged in a particular way to form
a building block you can think of a
building block as being like a like a
brick in a brick wall and these building
blocks within the crystal then are
stacked in a very regular arrangement in
three dimensions just like the bricks
are stacked in a wall
and in crystals unlike other forms of
matter you can sometimes see the shape
of these submicroscopic building blocks
with the naked eye
if the conditions are right the external
shape of the crystal is the same as the
shape of the particles that make it up
because of this
crystals provided one of the first clues
to the fundamental nature of solid
matter way back in the 16th century that
the
famous danish naturalist nils stenson
observed that
wherever a crystal of quartz such as
this was found
the angles between the faces were always
the same they weren't just random faces
they always had the same angles between
them and in fact quartz from anywhere in
the world from hot springs arkansas like
this huge slab or from brazil like these
beautiful amethysts
doesn't matter where the quartz comes
from what color it is what shape the
crystals are the angles between their
faces are always the same
infinitely repeating patterns of
chemical elements
the invisible world of fundamental
particles laid bare through the external
beauty of these shapes
in crystals we can also see how
particles in a solid are arranged to
create strength
this is different from other forms of
matter for example in a gas the chemical
elements are only very loosely and
weakly organized if at all and they have
very little relationship one to the
other which is why a gas can expand to
fill any volume that one wishes in a
liquid the chemical elements are a
little bit more organized there is an
attraction between the elements and so a
liquid has a volume to it but it will
flow
and fill any shape volume that you want
to pour it into because it does not have
any rigidity at all but it is more
organized than a gas a crystal is far
more organized than a liquid a crystal
has a rigid shape which will not change
because the
chemical elements that form the crystal
have a rigid arrangement with respect to
each other which does not deviate
strong and rigid but elegant and
fascinating crystals take many forms
from gemstones like the hope diamond the
largest blue diamond known in existence
to natural specimens of all shapes and
colors
crystals exert a grip upon both our
imagination and our scientific curiosity
i think the most fascinating thing about
crystals at least from the standpoint of
a scientist that wants to study matter
is the unique insight that a crystal
gives you into the nature of matter
itself into the way that chemical
elements behave toward each other
it's very hard to do this in a form of
matter such as a gas or a liquid where
the chemical elements don't really have
much to do with each other but in a
crystal the intimate association of the
elements tells you a lot about the
nature of the chemical elements
themselves just like an intimate
association between people will tell you
a lot about individuals and so i find
crystals especially fascinating because
they tell us so much about the nature of
the chemical elements themselves
to review
matter can occupy three different states
gas liquid and solid
changes of state depend on the motion of
submicroscopic particles the motion of
these particles depends on energy
cooling particles takes away energy and
slows them down
heating particles adds energy and speeds
them up
in a gas these particles move quickly
and randomly they have no set volume or
shape
in a liquid the particles slow down and
clump together
we use gases such as natural gas in many
important ways
cooling a gas into a liquid decreases
its volume dramatically this makes it
possible to store and transport it more
efficiently
[Music]
in a solid particles of matter have a
definite volume and shape they are held
in a pattern that repeats itself in
three dimensions
crystals are a highly ordered form of
solid matter
they were one of the first clues to the
arrangement of particles in the solid
state
the states of matter
are few
but the ways in which they are realized
the number of different substances
around us
are many
let me give you an example i'm breathing
oxygen the life giver
and that's obviously a gas
but here is another element sulfur
that's chemically very closely related
to oxygen
and yet it's obviously different it's a
solid at room temperature
now
there are obviously different forces at
work between the atoms or molecules of
sulfur and oxygen within these two
substances we want to know why that is
so we have to probe deeper we have to
then ask
what is the nature of the atom what is
it that makes an oxygen and a sulfur
similar or different
we will begin to look at this in the
next program
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so
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you
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