Oxidizing Agents and Reducing Agents

Tyler DeWitt
18 Aug 201514:55

Summary

TLDRThis educational video delves into the concepts of oxidizing and reducing agents, essential in chemistry for understanding chemical reactions. It explains oxidation as the loss of electrons and reduction as the gain, using a diagram to illustrate electron transfer between two entities, A and B. The video clarifies that an oxidizing agent facilitates oxidation by accepting electrons, while a reducing agent enables reduction by donating electrons. It further discusses how to identify these agents in chemical equations by examining changes in oxidation numbers, providing examples to demonstrate the process clearly. The video also touches on the nuance of identifying agents within compounds, emphasizing the importance of considering the whole compound rather than just the individual atoms.

Takeaways

  • 🔬 Oxidation is the loss of electrons, while reduction is the gain of electrons.
  • 🔄 An oxidizing agent is a substance that causes another substance to be oxidized by accepting electrons.
  • 🔄 A reducing agent is a substance that causes another substance to be reduced by donating electrons.
  • 🔄 In a chemical reaction, the substance that is oxidized is the reducing agent, and the substance that is reduced is the oxidizing agent.
  • 📊 To identify oxidizing and reducing agents, one must look at the changes in oxidation numbers of the elements involved in the reaction.
  • 📈 An increase in oxidation number indicates oxidation, while a decrease indicates reduction.
  • đŸ§Ș In complex chemical equations, it's common to refer to the whole compound rather than just the individual atom when discussing oxidizing and reducing agents.
  • 🌐 The oxidizing agent gains electrons and is reduced, while the reducing agent loses electrons and is oxidized.
  • 🔬 The process of identifying oxidizing and reducing agents involves understanding the transfer of electrons between substances.
  • 📚 The script provides a methodical approach to determining oxidizing and reducing agents by examining oxidation numbers and the nature of electron transfer in chemical reactions.

Q & A

  • What is an oxidizing agent?

    -An oxidizing agent is a substance that causes another substance to lose electrons, thereby causing oxidation. It facilitates the oxidation process by accepting electrons from the substance being oxidized.

  • What is a reducing agent?

    -A reducing agent is a substance that causes another substance to gain electrons, thereby causing reduction. It facilitates the reduction process by donating electrons to the substance being reduced.

  • How can you identify an oxidizing agent in a chemical equation?

    -In a chemical equation, an oxidizing agent can be identified by looking at the changes in oxidation numbers. If a substance gains electrons and its oxidation number decreases, it is being reduced and is the oxidizing agent.

  • How can you identify a reducing agent in a chemical equation?

    -In a chemical equation, a reducing agent can be identified by looking at the changes in oxidation numbers. If a substance loses electrons and its oxidation number increases, it is being oxidized and is the reducing agent.

  • What is the relationship between oxidation and reduction in a chemical reaction?

    -Oxidation and reduction are complementary processes that occur simultaneously in a chemical reaction. Oxidation is the loss of electrons, while reduction is the gain of electrons. One substance is oxidized (loses electrons) while another is reduced (gains electrons).

  • Can you provide an example of how to determine if a substance is being oxidized or reduced?

    -Yes, in the script, calcium (Ca) is used as an example. It starts with an oxidation number of 0 and ends with +2, indicating it has lost electrons and is being oxidized. Conversely, chlorine (Cl2) starts with an oxidation number of 0 and ends with -1, indicating it has gained electrons and is being reduced.

  • What does it mean when a substance's oxidation number increases?

    -When a substance's oxidation number increases, it means the substance is losing electrons and is being oxidized. This is indicative of the substance acting as a reducing agent in the reaction.

  • What does it mean when a substance's oxidation number decreases?

    -When a substance's oxidation number decreases, it means the substance is gaining electrons and is being reduced. This is indicative of the substance acting as an oxidizing agent in the reaction.

  • How do you determine the oxidizing and reducing agents in a reaction involving compounds?

    -In reactions involving compounds, you look at the changes in oxidation numbers of the elements within the compounds. The compound that loses electrons (and thus has an element with an increased oxidation number) is the reducing agent, and the compound that gains electrons (with an element having a decreased oxidation number) is the oxidizing agent.

  • Can you explain the concept of oxidation numbers and their importance in identifying oxidizing and reducing agents?

    -Oxidation numbers are a way of keeping track of the distribution of electrons in a chemical reaction. They are used to determine if a substance is being oxidized (loses electrons, oxidation number increases) or reduced (gains electrons, oxidation number decreases). By analyzing changes in oxidation numbers, you can identify the oxidizing and reducing agents in a reaction.

  • Why is it important to understand the difference between oxidizing and reducing agents?

    -Understanding the difference between oxidizing and reducing agents is crucial for predicting the outcome of chemical reactions, especially in redox reactions. It helps in determining the changes in oxidation states, which is essential for balancing equations and understanding the electron transfer process.

Outlines

00:00

🔬 Understanding Oxidizing and Reducing Agents

This paragraph introduces the concepts of oxidizing and reducing agents, explaining their roles in chemical reactions. It starts by defining oxidation as the loss of electrons and reduction as the gain of electrons. The paragraph uses a diagram to illustrate the electron transfer from element A to element B, where A is oxidized and B is reduced. The concept of an 'agent' is introduced as a facilitator that makes these processes happen. The paragraph emphasizes the need for an oxidizing agent to accept electrons from the oxidized substance and a reducing agent to donate electrons to the reduced substance. The relationship between the oxidized substance (reducing agent) and the reduced substance (oxidizing agent) is highlighted, providing a clear distinction between the two.

05:02

đŸ§Ș Identifying Agents in Chemical Equations

The second paragraph delves into identifying oxidizing and reducing agents within chemical equations. It explains the importance of understanding electron transfer and how it relates to oxidation numbers. The paragraph guides through the process of determining which elements or compounds are acting as oxidizing or reducing agents by examining changes in oxidation numbers. Using a chemical equation as an example, the paragraph demonstrates how to identify calcium as the reducing agent (losing electrons) and chlorine as the oxidizing agent (gaining electrons). The concept is further clarified by emphasizing that the oxidized substance is the reducing agent and the reduced substance is the oxidizing agent, with a simple diagram to summarize electron transfer.

10:03

🌐 Complex Chemical Reactions and Agent Identification

The third paragraph tackles a more complex chemical equation involving multiple elements and compounds. It discusses the importance of recognizing that atoms involved in oxidation and reduction are often part of larger compounds. The paragraph explains how to determine the changes in oxidation numbers for each element and how these changes indicate whether the element is being oxidized or reduced. Using hydrogen, nitrogen, oxygen, and sulfur as examples, the paragraph illustrates which compounds are acting as oxidizing or reducing agents. It concludes by summarizing the roles of H2S as the reducing agent and HNO3 as the oxidizing agent, emphasizing the need to consider the entire compound when identifying agents in complex reactions.

Mindmap

Keywords

💡Oxidizing agents

Oxidizing agents are substances that cause another substance to lose electrons through oxidation. In the context of the video, they are depicted as 'taking' electrons from a substance, thereby facilitating the oxidation process. For example, in the chemical equation involving calcium and chlorine, chlorine (Cl2) acts as the oxidizing agent by accepting electrons from calcium, which is being oxidized.

💡Reducing agents

Reducing agents are substances that cause another substance to gain electrons through reduction. They are characterized by 'giving' electrons to another substance, thus enabling reduction. In the video's narrative, calcium serves as a reducing agent by donating electrons to chlorine, which is gaining electrons and being reduced.

💡Oxidation

Oxidation refers to the process where a substance loses electrons. It is a key concept in the video, where the loss of electrons is illustrated through the transfer of electrons from one substance to another. The video uses the example of calcium losing electrons to chlorine, highlighting the increase in oxidation state as evidence of oxidation.

💡Reduction

Reduction is the process where a substance gains electrons. It is the counterpart to oxidation and is central to the video's discussion on electron transfer. The script explains that when a substance like chlorine gains electrons, its oxidation state decreases, indicating that reduction is taking place.

💡Electron transfer

Electron transfer is the movement of electrons from one atom or molecule to another, which is fundamental to both oxidation and reduction. The video uses diagrams and chemical equations to illustrate how electrons move from the reducing agent to the oxidizing agent, such as from calcium to chlorine.

💡Oxidation numbers

Oxidation numbers are used to represent the hypothetical charge of an atom in a molecule or compound, indicating the degree of oxidation. The video emphasizes the importance of understanding changes in oxidation numbers to identify oxidation and reduction in chemical reactions, such as the increase in oxidation number for calcium and the decrease for chlorine.

💡Chemical equations

Chemical equations are symbolic representations of chemical reactions, showing the reactants and products along with the conditions of the reaction. The video uses chemical equations to demonstrate how to identify oxidizing and reducing agents by analyzing the changes in oxidation numbers of the elements involved.

💡Agents

In the context of the video, 'agents' refers to substances that facilitate chemical reactions, specifically oxidizing and reducing agents. The term is used metaphorically, comparing them to agents for movie stars that help make things happen, emphasizing their role in chemical reactions.

💡Compounds

Compounds are substances formed when two or more chemical elements are chemically bonded together. The video discusses how atoms within compounds can undergo oxidation or reduction, and how the concept of oxidizing and reducing agents can apply to the compound as a whole, not just the individual atoms.

💡Electrons

Electrons are subatomic particles that orbit the nucleus of an atom and play a crucial role in chemical bonding and reactions. The video script frequently mentions electrons, focusing on their transfer as the core mechanism behind oxidation and reduction processes.

Highlights

Oxidizing agents and reducing agents are discussed, explaining what they are and their roles in chemical reactions.

Oxidation is defined as the loss of electrons, while reduction is the gain of electrons.

An agent in chemistry is something that facilitates a chemical reaction, similar to an agent for a movie star.

An oxidizing agent is responsible for causing oxidation by accepting electrons.

A reducing agent facilitates reduction by donating electrons to another species.

The concept of oxidation and reduction is further explained with a diagram illustrating electron transfer.

The oxidizing agent is identified as the species that gains electrons, causing oxidation.

The reducing agent is the species that loses electrons, allowing reduction to occur.

A switch occurs in the roles of oxidizing and reducing agents during a chemical reaction.

The oxidizing agent takes electrons away, causing oxidation, while the reducing agent gives electrons, causing reduction.

The video provides a method to identify oxidizing and reducing agents in chemical equations by examining oxidation numbers.

An increase in oxidation number indicates oxidation, while a decrease indicates reduction.

Calcium is identified as the reducing agent in a given chemical equation due to its loss of electrons.

Chlorine is identified as the oxidizing agent because it gains electrons in the reaction.

The concept is further illustrated with a second, more complex chemical equation involving multiple elements.

In complex reactions, the focus is often on the compounds rather than individual atoms when identifying agents.

H2S is identified as the reducing agent, and HNO3 as the oxidizing agent in the complex reaction.

A summary of the rules for identifying oxidizing and reducing agents is provided, emphasizing the role of electron transfer.

Transcripts

play00:00

in this video we're going to talk about

play00:01

oxidizing agents and reducing agents

play00:03

we're going to learn what they are what

play00:05

they do and how to identify them in

play00:07

chemical equations so if we're talking

play00:10

about oxidizing agents and reducing

play00:12

agents let's just refresh our memory

play00:14

about what oxidizing and reducing okay

play00:17

so oxidation is a loss of electrons and

play00:20

reduction is a gain of electrons

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I got a diagram here and we've got two

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things a and B maybe their atoms leave

play00:30

their compounds and there are electrons

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moving from A to B okay so a a here is

play00:39

losing electrons which means that a is

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being oxidized B over here B is gaining

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electrons which means that B is being

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reduced okay so that's oxidation and

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reduction but here we're talking about

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agents oxidizing and reducing agents so

play01:01

what's an agent well the word has a

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bunch of different meanings but in this

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situation an agent makes something

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happen okay think of like the agent for

play01:15

a movie star right the help the actor

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get jobs they help the actor get into

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movies an agent makes things happen for

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that movie star okay and that's exactly

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what oxidizing and reducing agents do

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they make stuff happen an oxidizing

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agent makes oxidation happen a reducing

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agent makes reduction happen okay so

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let's talk about the things that

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something would have to do to make

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oxidation happen to make reduction

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happen let's start here with oxidation

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what does something have to do to make

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oxidation well take a look at this

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diagram here we have a it's being

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oxidized it's losing these electrons but

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it's really important to remember that

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atoms can't just

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throwaway electrons I can't just chuck

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them into space and Adam can only get

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rid of electrons if something else is

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going to take those electrons away they

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have to give the electrons to something

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else okay so we can say that in order to

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make oxidation happen something

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something else has to take the electrons

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away from the thing that's being

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oxidized so let's look at what's going

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on here to allow oxidation to happen

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okay he's trying to get rid of these

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electrons and B takes them okay so B

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takes the electrons from a oxidizing

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it's making oxidation happen by taking

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those electrons away and we've said that

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an oxidation agent an oxidizing agent

play02:55

makes oxidation so B is the oxidizing

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agent

play03:02

it makes oxidation happen by taking the

play03:06

electrons from a so that a can get rid

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of them and so that a can lose them okay

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so that's what the oxidizing agent does

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now let's talk about reduction here in

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our diagram we have B B is gaining

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electrons but you just can't gain

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electrons out of thin air if you're

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going to gain electrons something else

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has to give you those electrons so that

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you can gain so we can say that to make

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reduction happen something has to give

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electrons where the electrons coming

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from that B is gaining well they're

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coming from a right a over here gives

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electrons to be reducing allowing it to

play03:45

be reduced and since a is making this

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happen by giving the electrons to B we

play03:52

can say that a is the reducing agent

play03:55

okay so B is the oxidizing agent it's

play04:00

it's making oxidation happening by

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taking the electrons from a a is the

play04:06

reducing agent it's making reduction

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happen by giving the electrons to B okay

play04:13

so we got reducing agent and

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sighs eh and if you look at what's going

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on here there's kind of a switch that

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takes place okay the thing that is

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oxidized the thing that loses electrons

play04:26

is the reducing agent and the thing that

play04:32

is reduced that gains electrons is the

play04:36

oxidizing agent okay the thing that's

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aweso dies is the reducing agent

play04:41

the thing that is reduced is the

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oxidizing agent okay so this is one way

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to remember that we get this kind of

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flip-flop but I think a better way to

play04:53

keep it in mind

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is remembering that the oxidizing agent

play04:57

makes oxidation happen by taking

play04:59

electrons away reducing agent makes

play05:01

reduction happen but giving electrons

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okay so this is an overall view of what

play05:08

oxidizing agents and reducing agents are

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now I want to look at two chemical

play05:12

equations where we'll figure out what

play05:15

elements and compounds are the oxidizing

play05:17

agents and the reducing agents so here

play05:19

we got this chemical equation we want to

play05:21

figure out which of these elements is an

play05:23

oxidizing agent which of them is a

play05:25

reducing agent in order to figure that

play05:28

out we've got to know how oxidation and

play05:31

reduction are happening in this equation

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we have to look at how electrons are

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being transferred and to do that we got

play05:39

to look at the oxidation numbers of each

play05:42

one of these elements so I have a whole

play05:44

bunch of videos on how to write

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oxidation nerves I'm not going to show

play05:48

you how to do that here but there are a

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bunch of rules that you follow you go

play05:52

through these rules and you're able to

play05:53

write oxidation numbers for all the

play05:56

elements in a chemical equation and

play05:59

these numbers show how electrons are

play06:02

moving okay so to figure out if

play06:05

oxidation or

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action is taking place we look at the

play06:09

changes in these oxidation numbers if

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oxidation number goes up oxidation is

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taking place if the oxidation number

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goes down reduction is taking place okay

play06:21

we'll start off by looking at calcium

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here CA CA starts off is zero on the

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side of the equation and then over here

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it's plus two okay so calcium is

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oxidation number is going up which means

play06:35

that it is being oxidized

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okay so calcium here is oxidized from

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zero to plus two which means that it

play06:43

loses electrons then on the other hand

play06:47

we have CL 2 chlorine or chlorine is

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zero here but it's minus one on this

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side equation so it's oxidation number

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is going down which means that it is

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being reduced it is gaining it is

play07:01

gaining electrons okay so that's what's

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happening with movement of electrons in

play07:05

this reaction or you can kind of sum it

play07:07

up with a simple diagram like this okay

play07:11

that electrons are being transferred

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from calcium to chlorine now we know

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what's being oxidized we know it's being

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reduced let's figure out what is the

play07:21

reducing agent and what is the oxidizing

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okay so calcium here is losing electrons

play07:27

it is giving electrons to chlorine but

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by doing that it is allowing chlorine to

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become reduced is allowing chlorine to

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gain electrons so calcium is the

play07:40

reducing agent because what is oxidized

play07:43

the thing that is oxidized is the

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reducing agent and then over here

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chlorine is being reduced it gains

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electrons but by doing that it's taking

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electrons away from calcium which is

play07:57

allowing calcium to lose those electrons

play08:01

it's allowing calcium to become oxidized

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so chlorine here is the oxidizing agent

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and we can also keep this in mind that

play08:09

the thing that is reduced chlorine is

play08:11

reduced

play08:12

is the oxidizing age okay so that's how

play08:15

we figure out the reducing agents and

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the oxidizing agents are an equation

play08:19

like this we start with the oxidation

play08:21

numbers we figure out what's getting

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oxidized what's getting reduced and then

play08:25

we can apply these rules or when you

play08:26

just think about it what is helping the

play08:29

other get oxidized or get reduced okay I

play08:32

want to do one more equation now that's

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a little bit more challenging than this

play08:36

so even if this one makes total sense

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you might just want to stick around and

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watch one more it could help you out

play08:42

okay this equation here is a little bit

play08:44

more complex than the one that we just

play08:45

looked at for a couple of reasons first

play08:47

it has a bunch of different elements the

play08:50

other equation only had two elements and

play08:51

the other thing here is the elements are

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grouped together in compounds so there

play08:56

is more than one element together in

play08:59

these things that we start off with okay

play09:01

those are going to change a little bit

play09:03

the way we apply these rules here's how

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we're doing it the first thing we want

play09:07

to do is we want to get oxidation

play09:08

numbers for all the elements yeah I'm

play09:11

not going to talk about that now but you

play09:12

can watch my videos on oxidation numbers

play09:14

if you want to do this but we follow

play09:15

these rules for oxidation numbers and

play09:17

these are the numbers that we're going

play09:18

again so now we want to look at the

play09:21

changes in oxidation number for each one

play09:24

of the elements we got all these

play09:25

different elements here some of them are

play09:27

going to change and some of them are not

play09:29

okay so let's look at this first one

play09:30

here we got hydrogen hydrogen here is

play09:33

plus one then here it's plus one and

play09:36

over on the right side it's also plus

play09:38

one okay so hydrogen's oxidation number

play09:41

doesn't change at all so hydrogen's not

play09:43

getting oxidized it's not getting

play09:45

reduced so we don't have to worry about

play09:46

nitrogen here is plus five here and then

play09:50

it's plus two over here okay so we do

play09:52

see a change in oxidation number for

play09:55

nitrogen it's going down from plus five

play09:58

to plus two so if your oxidation number

play10:00

goes down it means you are getting

play10:03

reduced you're gaining electrons

play10:06

okay so nitrogen is being reduced from

play10:08

plus five to plus two then we got oxygen

play10:11

it's minus two here but then on the

play10:14

right side it's minus two and minus two

play10:16

so nothing changes with oxygen we don't

play10:18

have to worry about then we already look

play10:20

at Hydra

play10:20

we have sulfur which is minus 2 here and

play10:24

on the right side it is zero so this is

play10:27

changing from minus 2 up to zero it's

play10:30

becoming less negative which means that

play10:33

oxidation is taking place so for here is

play10:38

losing electrons is being oxidized from

play10:42

minus 2 to 0 ok now I said one of the

play10:46

things that makes us a little bit

play10:48

trickier is it the atoms that are

play10:51

getting oxidized and reduced are part of

play10:56

compounds with other elements ok now

play11:00

when we're talking about oxidizing

play11:01

agents and reducing agents and

play11:03

identifying them people are usually more

play11:06

interested in the compound than the

play11:10

individual lab ok so yeah so sulfur this

play11:14

ser sulfur is what's getting oxidized

play11:16

but generally people are more interested

play11:20

in the compound that this sulfur is part

play11:23

of they're not as interested in just the

play11:26

sulfur itself ok so I'm saying here that

play11:29

sulfur is getting oxidized it's totally

play11:31

true but we also probably want to say in

play11:35

problems like this that really h2s is

play11:38

being oxidized right sulfur is losing

play11:41

electrons but sulfur is part of h2s so

play11:44

h2 s as a whole is losing electrons so

play11:48

that's we're going to save this

play11:49

oxidizing reducing agent thing Renison

play11:51

is h2s that's getting oxidized it's

play11:55

losing electrons nitrogen this nitrogen

play11:57

atom is definitely getting reduced it's

play12:00

gaining electrons but if we're talking

play12:02

about the larger compound that nitrogen

play12:04

is part of we'll say instead that hno3

play12:09

is getting reduced here the nitrogen is

play12:13

gaining electrons but the nitrogen is

play12:15

part of a channel 3 so the whole thing

play12:17

the whole and a channel 3 is gaining

play12:20

electrons so h2s is getting oxidized

play12:22

hno3 is getting reduced because these

play12:25

atoms are part of these compounds so we

play12:28

can kind of sum this up here with a

play12:30

diagram that I

play12:32

okay the s the sulfur from h2s is giving

play12:35

electrons to the N in hno3 so now we

play12:40

have this information we can figure out

play12:42

the oxidizing agents and the reducing

play12:44

agent

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okay so h2s is getting oxidized it's

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giving its electrons to hno3 ear

play12:52

allowing hno3 to gain those electrons so

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it is allowing reduction to take place

play13:00

so h2s is the reducing agent and this

play13:04

makes sense with our rules here h2s is

play13:07

oxidized and the thing that is oxidized

play13:09

is the reducing agent and then over here

play13:12

hno3 is reduced it's taking electrons

play13:17

from h2s which allows h2s to become

play13:22

oxidized it allows it to lose those

play13:24

electrons so that means that hl3 is

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making oxidation happen so hno3 is the

play13:32

oxidizing agent we can look this rule up

play13:35

here the thing that is reduced hno3 is

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reduced the thing that is reduced is the

play13:40

oxidizing agent okay so just remember

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when you have an equation like this

play13:45

where the individual atoms that are

play13:47

getting oxidized or reduced are part of

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larger compounds when you're talking

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about oxidizing agents reducing agents

play13:54

you probably want to mention the whole

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compound instead of just the individual

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atom so that's everything you need to

play14:03

know about oxidizing agents and reducing

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agents okay the oxidizing agent allows

play14:10

oxidation to take place so it takes

play14:13

electrons from the atom or the compound

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that is being oxidized the oxidizing

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agent allows oxidation to take place it

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itself is a reduced and it gains

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electrons the reducing agent allows a

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reduction to take place by giving

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electrons to the thing that is going to

play14:34

be reduced so it itself is losing

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electrons the reducing agent is oxidized

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it's also probably useful just to

play14:42

remember this information up here

play14:44

the thing that is oxidized is the

play14:46

reducing agent and the thing that is

play14:49

reduced is the oxidizing agent

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