999 Fine Silver Cell Harvest and Reboot

sreetips
2 Feb 202419:48

Summary

TLDRIn this video, the creator demonstrates the silver cell operation process, detailing the 13-day journey of extracting high-purity silver crystals from an anode bowl. They explain the role of the anode filter basket in trapping impurities, leaving behind 'silver cell slimes' rich in Platinum Group Metals and gold. The video showcases the setup, including a safety fuse to prevent short-circuiting, and the process of harvesting silver. It also covers the preparation of additional electrolyte by dissolving pure silver crystals and nitric acid, and the steps to ensure the purity of the harvested silver, including multiple rinses and a test for residual electrolyte.

Takeaways

  • 🌟 The video documents day 13 of a silver cell operation, resulting in approximately 1.5 kilos of high-purity silver.
  • 🔍 An anode filter basket is used to separate impurities, leaving behind 'silver cell slimes' which can be recovered for Platinum Group Metals and gold.
  • 🔌 A fuse is installed to prevent short-circuiting if the growing silver crystal contacts the anode basket.
  • 📉 The current flow through the cell decreases as impurities accumulate in the anode filter.
  • 🔋 The process involves dissolving impure silver from gold refining into granules, which are then used as feedstock in the silver cell.
  • ⚙️ An electrode bar, made of pure silver with a copper wire, is connected to the power supply to dissolve the silver and allow silver ions to travel through the electrolyte.
  • 💧 The electrolyte, initially containing 600 grams of pure silver dissolved in nitric acid, becomes depleted as the cell operates.
  • 🔄 The electrolyte is reused for a second refining process after additional pure silver is added to replenish the depleted silver ions.
  • 💦 The harvested silver crystals are thoroughly rinsed with distilled water to remove any remaining electrolyte.
  • 🔬 A test with hydrochloric acid confirms that all electrolyte has been rinsed off the silver, as no silver chloride forms.
  • 📈 The video concludes with the setup for a second run of the silver cell operation, demonstrating the process of reusing the electrolyte and starting a new batch.

Q & A

  • What is the purpose of the silver cell operation described in the script?

    -The purpose of the silver cell operation is to refine and harvest high purity silver from impure silver sources, such as that obtained from gold refining.

  • How long does it take to grow approximately 1.5 kilos of pure silver crystal?

    -It takes about 13 days to grow approximately 1.5 kilos of pure silver crystal in the described process.

  • What is the role of the anode filter basket in the silver cell operation?

    -The anode filter basket holds a Dacron cloth filter that catches impurities as the electric current dissolves the silver. These impurities, known as silver cell slimes, can be later recovered for precious metals like platinum group metals and gold.

  • Why is a fuse installed in the silver cell operation?

    -A fuse is installed to prevent a short circuit if the growing silver crystal inside the cell makes contact with the anode basket. This would otherwise release impurities into the cell and ruin the batch of silver.

  • How does the current flow affect the silver cell operation?

    -The current flow dissolves the impure silver, allowing silver ions to travel through the anode filter into the electrolyte, where they plate out as pure elemental silver. As the slimes build up, they interfere with the current flow, causing it to drop.

  • What is the composition of the electrolyte used in the silver cell operation?

    -The electrolyte is composed of silver nitrate dissolved in distilled water, which acts as a conductive medium for the silver ions to plate out as pure silver.

  • Why does the solution turn blue during the silver cell operation?

    -The solution turns blue because copper from the electrode bar dissolves into the electrolyte, indicating that the silver and copper ions are being transferred through the anode filter into the electrolyte.

  • How is the purity of the harvested silver ensured?

    -The purity of the harvested silver is ensured by the use of a Dacron filter that traps impurities, allowing only pure silver ions to plate out in the cathode. Additionally, the electrolyte is rinsed off the silver multiple times to remove any residual silver nitrate.

  • What is the significance of the copper concentration in the cell?

    -The copper concentration must be kept below 60 grams per liter to prevent it from plating out with the silver. If the concentration is too high, it can contaminate the silver harvest.

  • How is the electrolyte prepared for a second use in the silver cell operation?

    -For a second use, additional pure silver is dissolved in nitric acid and distilled water to create a new solution, which is then added to the existing electrolyte to augment it for another refining cycle.

  • What is the final step to ensure the purity of the silver after harvesting?

    -The final step to ensure the purity of the silver is to rinse it multiple times with distilled water, both cold and boiling, and then test a small sample with hydrochloric acid to check for any remaining silver nitrate, indicated by the absence of silver chloride formation.

Outlines

00:00

🔬 Silver Electrolysis Process

The script describes day 13 of a silver cell operation where the anode bowl is full of high-purity silver crystals. The process involves dissolving silver in an electric current, leaving impurities behind in the anode filter basket. A fuse is installed to prevent short-circuiting if the growing silver crystal contacts the anode basket. The current flow through the cell drops as impurities accumulate, indicating the need to harvest the silver. The process also involves adding pure silver to the impure silver as a feedstock, with the pure silver electrode bar connected to the power supply. The silver ions travel through the anode filter and plate out in the stainless steel bowl as pure elemental silver.

05:01

🧪 Preparing for Silver Electrolysis

The script explains the preparation of electrolyte for the silver cell operation. It involves dissolving 600 grams of pure silver in nitric acid, which is then depleted as the cell operates. To reuse the electrolyte, additional pure silver is added to replenish the depleted silver. The process of dissolving the silver in nitric acid is described, along with the steps to ensure all available free nitric acid is consumed. The anode electrode bar is then removed, and the power supply is turned off to prepare for harvesting the pure silver.

10:13

💧 Rinsing and Drying Silver Crystals

The script details the process of pouring off the electrolyte for reuse and harvesting the pure silver crystals. The crystals are scraped off the bowl and transferred for rinsing to remove any remaining electrolyte. Rinsing is done multiple times with both cold and boiling distilled water. A test is conducted with hydrochloric acid to ensure all electrolyte is removed. The silver is then dried off by placing it on low heat.

15:14

🔄 Reusing Electrolyte and Restarting the Cell

The script outlines the steps for reusing the filtered electrolyte and restarting the silver cell operation. Fresh anode basket and electrode bar are prepared, and the electrolyte is added to a new stainless steel bowl. The cell is charged, and the process begins anew, with the formation of pure silver crystals visible within 30 minutes. The harvested silver is weighed, yielding 1.3 kilograms of pure silver crystals, concluding the video.

Mindmap

Keywords

💡silver cell

A silver cell refers to an electrolytic cell used in the process of refining silver. In the video, the silver cell is used to convert impure silver into high purity silver by dissolving it and then allowing the silver ions to plate onto a cathode. The operation of the silver cell is central to the video's theme of silver refining.

💡anode

The anode is the positively charged electrode where oxidation occurs. In the context of the video, impure silver is placed in the anode basket, where it gets dissolved by the electric current, leaving behind impurities. The anode is crucial in the electrolytic process of silver purification.

💡cathode

The cathode is the negatively charged electrode where reduction occurs. In the video, the cathode is a stainless steel bowl where pure silver ions plate out to form high purity silver. The cathode is essential to the silver cell operation as it is where the desired product is collected.

💡Dacron cloth filter

A Dacron cloth filter is used in the anode basket to trap impurities as the silver dissolves. The filter prevents these impurities from entering the electrolyte and contaminating the silver plating process. The script mentions that the silver cell slimes, which include platinum group metals and possibly gold, are left behind by this filter.

💡electrolyte

An electrolyte is a substance that conducts electricity when dissolved in a solution, typically due to the presence of ions. In the video, the electrolyte is a silver nitrate solution that facilitates the movement of silver ions from the anode to the cathode within the silver cell.

💡impurities

Impurities refer to unwanted substances or elements mixed with the primary material. In the silver refining process described, impurities are left behind in the anode filter basket and do not plate onto the cathode, thus keeping the silver produced pure.

💡current flow

Current flow refers to the movement of electric charge through a conductor, which in this case is the silver cell. The video discusses how the current flow dissolves the silver and how it decreases as impurities build up in the anode filter, affecting the efficiency of the cell.

💡silver crystal

Silver crystal in the video refers to the high purity silver that is produced and collected in the cathode of the silver cell. The script describes the harvesting of these crystals, which are of high purity and have a distinctive crystalline form.

💡refining

Refining is the process of purifying a substance, such as silver, from a mixture or compound. The video is centered around the refining of silver from an impure form to a high purity state through the use of a silver cell.

💡nitric acid

Nitric acid is a strong acid used in the electrolyte solution to dissolve impure silver and facilitate the transfer of silver ions. The script mentions adding nitric acid to distilled water to prepare additional electrolyte for the silver cell.

💡hydrochloric acid test

A hydrochloric acid test is used to check for the presence of silver or silver nitrate by observing whether a cloud of silver chloride forms. In the video, this test is used to confirm that all electrolyte has been rinsed off the harvested silver crystals.

Highlights

Day 13 of the silver cell operation, resulting in high purity silver crystal.

Anode bowl is full of pure silver crystal, estimated to be 1.5 kilos.

Silver is dissolved by electric current, leaving impurities as silver cell slimes behind a Dacron cloth filter.

Anode filter slimes can be recovered to extract Platinum Group Metals and gold.

Installing a fuse to prevent short circuit if silver crystal contacts the anode basket.

Current flow drops as slimes build up in the anode filter, affecting the cell's operation.

Description of how the silver cell works, including the role of impure silver and electrode bars.

Silver ions travel through the anode filter and plate out as pure elemental silver in the cathode.

Electrolyte becomes depleted as the cell operates, requiring additional pure silver to be added.

Preparation of additional electrolyte by dissolving pure silver crystal in nitric acid.

Anode electrode bar is removed, and the power supply is turned off to prepare for harvesting.

Electrolyte is poured off and saved for a second use in the silver cell.

Pure silver crystal is revealed and scraped off the side of the bowl.

Rinsing the silver crystal with distilled water to remove any remaining electrolyte.

Testing the purity of the silver crystal using hydrochloric acid to check for silver chloride formation.

Drying the pure silver crystal on low heat to remove moisture.

Filtering the electrolyte and preparing it for a second refining run in the silver cell.

Rebooting the silver cell with a fresh anode basket and electrode bar.

Observing the formation of pure silver crystal within 30 minutes of the cell's operation.

Weighing the harvested pure silver crystal, yielding approximately 1.3 kilos.

Transcripts

play00:08

welcome back to my channel everyone

play00:09

sweet tips here and today is day 13 of

play00:14

the silver cell

play00:16

operation and if you look down in

play00:20

there the anode bowl is full of pure

play00:25

silver crystal that's high Purity silver

play00:30

39's fine or better

play00:34

probably uh 1.5 kilos or so I grew it in

play00:39

about 13

play00:42

days what we're going to do is we're

play00:44

going to harvest the silver out of here

play00:47

but I want to talk a little bit about

play00:49

this first before we do that if you look

play00:52

down in our anode filter basket you'll

play00:54

see that the uh silver that I feed in

play00:58

here gets

play01:01

dissolved by the electric current that

play01:03

flows in

play01:05

there and what gets left behind there's

play01:07

a Dacron cloth filter in there and what

play01:11

gets left behind is silver cell slimes

play01:16

and what that is is that's just

play01:18

like

play01:20

goop uh like mush down in there the

play01:26

impurities in this silver as the current

play01:30

flow travels through the

play01:32

uh cell the current flow dissolves this

play01:35

silver and then the impurities get left

play01:38

down in the bottom of this anode filter

play01:41

and I can uh save those that's going to

play01:44

be Platinum Group Metals maybe a little

play01:46

bit of gold some other junk in there but

play01:49

I can save that uh anode filter and

play01:51

those slimes and do a recovery on those

play01:55

slimes to get the gold and the Platinum

play01:56

Group Metals out of there I've still got

play01:59

the cell run running right now and we'll

play02:01

continue to let this

play02:03

run and while we're getting set up to

play02:08

harvest the pure silver out of the cell

play02:12

if you look up here you'll notice that

play02:14

I've got a fuse

play02:18

installed I do that on the last several

play02:21

days of the silver cell operation this

play02:23

is an inline automotive type 3 amp fuse

play02:28

and that's there in case

play02:30

the pure silver Crystal down inside the

play02:34

silver cell you can see it grows and it

play02:39

grows towards the anoe basket down there

play02:43

if that Crystal makes contact with the

play02:45

anode basket it'll short it out and burn

play02:49

a hole in that filter bag and then all

play02:51

the impurities will be released down

play02:54

into the silver cell and ruin the batch

play02:57

of silver here you can see the uh amps

play02:59

have dropped dropped off when I first

play03:01

started the cell it was up over 1 and

play03:03

1/2 amps of current flow through the

play03:06

cell and what happens is as those slimes

play03:10

built up in the anode filter anode

play03:14

basket there it interferes with the

play03:16

current flow through the cell and it

play03:21

causes the current flow to drop

play03:24

off here's a little information about

play03:27

how this cell works this is impure

play03:32

silver that comes from my gold refining

play03:35

I recover the silver from my gold

play03:38

refining melt it into these granules and

play03:41

I use this as a feed

play03:43

stock in my silver cell anode basket I

play03:47

have an electrode bar which is a bar of

play03:49

pure silver with a copper wire cast into

play03:53

it and I connect that to the power

play03:56

supply and set that on top of the impure

play04:00

silver that's in that filter basket the

play04:03

current flow dissolves the

play04:05

silver and then the silver ions travel

play04:09

through the anode filter

play04:13

itself and uh the copper does too the

play04:16

the copper gets dissolved as well and

play04:19

that's why the solution turns blue in

play04:20

here but you can see the anode basket is

play04:23

in contact with the silver nitrate

play04:28

electrolyte and the silver ions and the

play04:30

copper they travel down into the

play04:32

electrolyte there uh the electrolyte is

play04:35

conductive so it completes a circuit

play04:38

between the uh electrode bar which is

play04:41

positively

play04:44

charged and the cathode which is the

play04:47

stainless steel bowl and the silver

play04:50

travels through the electrolyte and then

play04:52

plates out in there as absolutely pure

play04:56

Elemental silver metal now what happens

play05:00

is uh as the cell operates I had 600 gam

play05:04

of pure silver dissolved in nitric acid

play05:08

in 3.5 L of liquid that's what the

play05:10

electrolyte is there was 600 gram in

play05:13

there when I started there's probably

play05:15

only about 400 gam left in that

play05:19

electrolyte because this electrolyte

play05:21

becomes depleted as the cell operates it

play05:25

plates out on the inside of the cathode

play05:28

there as High Purity silver the

play05:30

impurities get trapped in the

play05:33

filter and the silver ions and the

play05:35

copper travel down into the silver cell

play05:37

the silver plates out but the copper

play05:40

does not as long as that copper is kept

play05:43

below 60 gam per liter concentration in

play05:47

the cell then the copper will not plate

play05:50

out with the silver but if it gets high

play05:53

enough it will start to Plate out with

play05:55

that silver and then you can see I've

play05:57

got a connection here for the cathode

play05:59

and that wire goes all the way up and

play06:02

connects to the negative side of the

play06:05

power

play06:07

supply I'm going to use the electrolyte

play06:09

in that silver cell a second time but as

play06:13

I stated

play06:14

earlier some of the silver has been

play06:17

depleted out of that electrolyte so what

play06:21

I need to

play06:22

do is prepare some

play06:27

additional electrolyte I'm going to use

play06:29

about 200 g of pure

play06:32

silver I see that number down

play06:39

there all right now we're going to add

play06:41

about 200 g of pure silver Crystal from

play06:46

a

play06:47

previous silver cell Harvest just going

play06:50

to add it right in

play06:58

here

play07:11

all right that's about

play07:13

230 gram of pure silver now what we'll

play07:16

do is get our

play07:21

silver and add

play07:23

some distilled water to

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it going to add about 300 milliliters or

play07:29

so

play07:33

I've got some nitric acid back

play07:35

here this is just under 200

play07:39

millit probably 190 something like that

play07:43

I'm going to add this right on

play07:45

in and you'll see the silver will

play07:48

instantly begin to

play07:51

dissolve and we'll cover this up

play07:54

now and we're going to put this up on

play07:57

the

play07:58

heat and slowly

play08:01

dissolve this pure silver Crystal and

play08:04

then we'll use that to

play08:08

augment the second use of our

play08:11

electrolyte in the silver

play08:28

cell

play08:37

I can tell when all the available free

play08:39

Nitric has been consumed by this

play08:41

reaction because there's a little bit of

play08:44

silver left in the

play08:47

beaker all the fumes are gone and I got

play08:51

the solution at a boil so now it's safe

play08:55

to conclude that I've got all of the

play08:57

available free Nitric using used up in

play09:00

this reaction pull the anode electrode

play09:04

bar out we're going to kill the power

play09:08

supply now we'll do the same thing with

play09:11

the negative

play09:17

side now we'll take the anoid basket and

play09:20

get it out of the way just lift it right

play09:24

on up and put it in this

play09:26

container and then I just set it aside

play09:29

side for now let's cover this up so

play09:31

nothing falls down in there and I've got

play09:34

a uh a wrench

play09:36

here will drop the cathode

play09:41

connection cathode connection just a

play09:44

hose clamp with a uh copper strap that's

play09:48

got our toggle bolt in

play09:50

it now let's pull this cover

play09:54

off and

play09:57

reveal the pure silver

play10:00

Crystal down in our silver cell look at

play10:13

that now let's

play10:17

uh pour

play10:20

off the electrolyte as I stated earlier

play10:23

we're going to be using this

play10:25

electrolyte a second time so what want

play10:29

to

play10:30

do see if I can get that on the camera

play10:33

just pour it into this 5 L

play10:36

Beaker and I'm going to save it cuz I'm

play10:38

going to use it for the second run of

play10:41

the silver

play10:52

cell and there's our

play10:55

beautiful pure silver

play10:58

Crystal

play11:00

about

play11:01

1.5

play11:05

kilos now we're going to scrape the

play11:08

crystals down off the side of the

play11:27

bowl

play11:33

now we're going to transfer the pure

play11:34

silver

play11:36

into the

play11:53

speaker there's a nice looking

play11:57

Crystal highly unusual shape to

play12:18

it now what we'll do is start

play12:20

rinsing the electrolyte off of the

play12:24

silver this is a bucket full of cement

play12:26

silver it's got some copper in it and

play12:29

we'll pour off the rinses that we're

play12:32

about to do using distilled

play12:41

water just throw some distilled water in

play12:44

here and try to get the rest of this uh

play12:48

electrolyte rinsed off of our Pure

play12:57

so

play13:11

I've rinsed it about four times with

play13:15

cold distilled water I've got some

play13:18

boiling distilled water here now and

play13:19

we'll use this to do a few more

play13:27

rinses

play14:03

right this is the

play14:05

seventh

play14:08

rinse maybe eight I think I can't

play14:11

remember but I know from experience it

play14:14

takes

play14:15

about six of these rinses to get all the

play14:18

electrolyte off so we should have it all

play14:20

off here but we're going to test this

play14:23

now got a little Beaker I'm going to get

play14:26

a little bit

play14:27

of in this

play14:30

speaker and now we're going to add some

play14:32

hydrochloric acid to this and if we've

play14:36

got any silver or silver nitrate left in

play14:38

here we'll see a cloud of silver

play14:41

chloride

play14:42

forming as we pour this hydrochloric

play14:45

acid

play14:46

in and I don't

play14:48

see one trace of silver chloride so it's

play14:53

fairly safe to conclude that we've

play14:56

got all of the electrolyte r rined

play14:59

off of our pure silver Crystal now it's

play15:03

hot boiling water I'm going to move this

play15:06

out of the way

play15:08

now and we're going to bring up a

play15:12

dish and what we'll

play15:14

do is add the pure silver Crystal to

play15:18

this

play15:26

dish now we'll take this all over and

play15:30

set them on on some low heat and dry

play15:33

this

play15:39

off well we've got that silver drying

play15:43

what I'll do is filter our electrolyte

play15:46

and get it

play15:47

ready to reboot the silver

play15:50

cell I've said it twice already I'm

play15:54

using the same electrolyte for a second

play15:58

refining

play16:01

I'm adding the uh silver nitrate

play16:03

solution that we just prepared it's got

play16:07

about 200 g of pure silver in it and

play16:11

we're going to go ahead and pour this

play16:12

through the filter

play16:21

now I've got all the electrolyte pulled

play16:24

through the filter now what we'll do is

play16:27

take it over here to a fresh stainless

play16:31

steel bowl we're going to add the

play16:33

electrolyte to this stainless Bolt the

play16:36

stainless bowl is the cathode for the

play16:39

silver cell we're going to fill it up

play16:42

with electrolyte to about within a half

play16:45

an inch or so of the rim of the bowl

play16:49

I've got a little left over and I'll

play16:51

save that and we'll augment the uh

play16:53

electrolyte as the cell operates with

play16:55

that extra that I have left over now

play16:58

we're going to charge up uh a fresh

play17:01

anode basket that's a Dacron vacuum

play17:04

cleaner filter bag that I use as a

play17:07

filter going to install this now on top

play17:09

of the cell which

play17:11

submerged down in the

play17:14

electrolyte and we'll

play17:17

install our ano Electro

play17:21

bar now we've got everything uh

play17:24

assembled all fresh stuff put back

play17:27

together going to enter the

play17:29

cell and you see we got up over 2 amps

play17:33

of current

play17:35

flow the cell has been in operation for

play17:37

about 30 minutes

play17:39

now and if you look down in

play17:43

here you can

play17:45

see after 30

play17:48

minutes that we're starting to form pure

play17:50

silver crystal in there

play17:52

already see those crystals growing on

play17:55

the inside of that stainless steel

play17:57

cathode Bowl

play17:59

that's after about a half an

play18:01

hour I think our pure silver crystal is

play18:05

dried off now I've got a

play18:07

cold stainless steel

play18:11

spoon I just kind

play18:13

of run it around in here there's still

play18:16

steam coming off here that will condense

play18:19

on this

play18:20

spoon and I don't see any of that so

play18:24

it's a safe bet that we've got all of

play18:26

the uh moisture driven off out of our

play18:31

pure silver Crystal now all right let's

play18:33

get some

play18:34

weight on our Harvest

play18:37

here that's on

play18:42

grams that's 2,200 Gams going to zero

play18:45

this

play18:47

out okay let's go ahead and add our

play18:50

silver from this

play18:52

Harvest see what kind of yield we're

play18:54

going to get

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here

play19:18

all

play19:21

right looks like we got

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1.3

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kilos of pure silver Crystal from that

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Harvest and we'll take it okay this will

play19:35

conclude the video I'd like to thank

play19:38

everyone for

play19:46

watching

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Silver RefiningElectrolytic CellDIY TutorialMetallurgyPrecious MetalsAnode BasketCathode BowlSilver HarvestChemical ProcessMetal Recovery
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