C.2 Thermal and catalytic cracking (SL)

Mike Sugiyama Jones (MSJ Chem)

7 Dec 201503:11

Summary

TLDRThis video by Msj Cam explains the processes of thermal and catalytic cracking, which are used to break down longer-chain hydrocarbons into shorter ones to meet global demand for fuels like gasoline and diesel. It covers how cracking helps compensate for supply shortages in crude oil and demonstrates reactions where hydrocarbons split into smaller molecules. The video distinguishes between thermal cracking, which uses high temperature and pressure, and catalytic cracking, which uses a zeolite catalyst at lower conditions. It also touches on the production of branched alkanes and plastics like polyethylene.

Takeaways

🛢️ Crude oil is separated into fractions based on their boiling points during fractional distillation.
📊 There is greater global demand for gasoline, naphtha, and diesel than the supply from crude oil.
🔨 Cracking is a process used to break longer-chain hydrocarbons into shorter ones to meet demand for specific products.
⚗️ In cracking, for example, C7H16 (heptane) can be broken into C2H4 (ethene) and C5H12 (pentane).
📉 The number of carbon and hydrogen atoms remains the same before and after cracking reactions.
💥 Thermal cracking is performed at high temperatures (~750°C) and high pressure (70 atmospheres) to produce unsaturated hydrocarbons.
🧪 Catalytic cracking uses a zeolite catalyst to lower temperature and pressure for the cracking process.
🏭 Thermal cracking produces a high proportion of hydrocarbons with carbon-carbon double bonds, which can be used to make plastics like polyethylene.
🚗 Catalytic cracking produces branched alkanes and aromatic hydrocarbons, such as benzene, which burn more efficiently in car engines.
🔗 Octane (C8H18) is a saturated hydrocarbon, while octene (C8H16) has a carbon-carbon double bond, making it unsaturated.

Q & A

What is the main purpose of cracking in the oil industry?
-Cracking is used to break longer chain hydrocarbons into shorter chain hydrocarbons to meet the global demand for products like gasoline, diesel fuel, and naphtha, which exceeds the supply from crude oil.
What is the difference between thermal and catalytic cracking?
-Thermal cracking is carried out at high temperatures (around 750°C) and pressures (70 atmospheres) and produces a high proportion of unsaturated hydrocarbons. Catalytic cracking, on the other hand, uses a zeolite catalyst, operates at lower temperatures and pressures, and produces more branched alkanes and aromatic hydrocarbons.
What products are formed when a longer chain hydrocarbon like C7H16 is cracked?
-When C7H16 (heptane) undergoes cracking, it forms two shorter chain hydrocarbons: C2H4 (ethene) and C5H12 (pentane).
How does cracking help balance supply and demand in the oil market?
-Cracking helps convert longer chain hydrocarbons, which are more abundant, into shorter chain hydrocarbons like gasoline and diesel, which are in higher demand but less available in their natural state.
What are unsaturated hydrocarbons, and why are they important in cracking?
-Unsaturated hydrocarbons contain carbon-to-carbon double bonds. They are important in cracking because they can be used to produce plastics, such as polyethylene, through polymerization reactions.
Why are zeolite catalysts used in catalytic cracking?
-Zeolite catalysts are used in catalytic cracking because they allow the cracking process to take place at lower temperatures and pressures, making the process more efficient and cost-effective.
What is the significance of producing branched alkanes and aromatic hydrocarbons during catalytic cracking?
-Branched alkanes and aromatic hydrocarbons, such as benzene, are important because they burn more evenly in car engines, improving fuel efficiency and reducing engine knocking.
What is an example of a polymerization reaction mentioned in the video?
-An example of a polymerization reaction is the conversion of ethene (C2H4) into polyethene (polyethylene), which is a widely used plastic material.
What is the difference between octane and oct-1-ene?
-Octane is a saturated hydrocarbon with only carbon-to-carbon single bonds, while oct-1-ene is an unsaturated hydrocarbon with a carbon-to-carbon double bond.
Why is thermal cracking done at such high temperatures and pressures?
-Thermal cracking is done at high temperatures and pressures to break the strong bonds in long-chain hydrocarbons, producing a mixture of shorter chain hydrocarbons, many of which have carbon-to-carbon double bonds (unsaturated).