ÁCIDOS GRASOS ESENCIALES | ESTRUCTURA Y NOMENCLATURA OMEGA

QUÍMICA EN TODO
25 Sept 202009:25

Summary

TLDRToday's discussion focuses on essential fatty acids, distinguishing them from unsaturated fatty acids. Essential fatty acids, crucial for health, must be ingested as our body cannot synthesize them. Examples include linoleic acid (omega-6) and alpha-linolenic acid (omega-3), which are polyunsaturated with double bonds on carbons 6 and 3 respectively. The script also explains the systematic naming of fatty acids, highlighting the importance of omega-6 and omega-3 for our body's functions.

Takeaways

  • 🔬 Essential fatty acids (EFAs) are crucial nutrients that the body cannot synthesize and must be obtained through diet.
  • 🌱 There's a distinction between essential fatty acids and other unsaturated fatty acids; EFAs are a subset of unsaturated fatty acids.
  • 🚫 Deficiency in EFAs can lead to health issues ranging from mild to severe, highlighting their importance for proper body function.
  • 📚 Examples of polyunsaturated essential fatty acids include linoleic acid (omega-6) and alpha-linolenic acid (omega-3), which are 18-carbon fatty acids.
  • 🔑 The term 'essential' is also applied to certain amino acids that the body cannot produce and must be ingested through diet.
  • 🔄 The nomenclature of fatty acids is based on the position of the first double bond from the left end of the carbon chain, which is different from the IUPAC naming system.
  • 🧪 The IUPAC naming system for fatty acids starts with the carbon that includes the carboxyl group, which may differ from the omega naming system.
  • 📖 The script references a manual on page 30 for more detailed information on the topic, indicating the source of the information discussed.
  • 🌟 Oleic acid, unlike linoleic and alpha-linolenic acids, is not an essential fatty acid as the body can synthesize it.
  • 📝 The script emphasizes the importance of understanding the difference between essential and non-essential fatty acids for health and dietary purposes.

Q & A

  • What are essential fatty acids?

    -Essential fatty acids are called essential because they are crucial for health and must be obtained from the diet as the body cannot synthesize them.

  • Why are some fatty acids considered essential?

    -Some fatty acids are essential because our body lacks the ability to produce them, necessitating their intake through diet.

  • What happens if the body lacks essential fatty acids?

    -A deficiency in essential fatty acids can lead to various health issues, ranging from mild to severe, due to their critical role in bodily functions.

  • What is the difference between unsaturated and essential fatty acids?

    -Unsaturated fatty acids include both essential and non-essential types. Essential fatty acids are a subset of unsaturated fatty acids that the body cannot synthesize and must be obtained from diet.

  • What are the two main types of essential fatty acids discussed in the script?

    -The two main types of essential fatty acids discussed are linoleic acid (omega-6) and alpha-linolenic acid (omega-3).

  • Why are linoleic acid and alpha-linolenic acid important?

    -Linoleic acid and alpha-linolenic acid are important because they are essential for the body and must be obtained from dietary sources, playing vital roles in health and well-being.

  • How are omega-6 and omega-3 fatty acids named?

    -Omega-6 and omega-3 fatty acids are named based on the position of the first double bond from the end of the carbon chain, with omega-6 having the first double bond at the 6th carbon and omega-3 at the 3rd carbon.

  • What is the significance of the term 'polyunsaturated' in the context of fatty acids?

    -Polyunsaturated refers to fatty acids with more than one double bond in their carbon chain, indicating a higher degree of unsaturation.

  • What is the IUPAC name for oleic acid?

    -The IUPAC name for oleic acid is 9-octadecenoic acid, which reflects its structure with a double bond at the 9th carbon from the end of the carbon chain.

  • How does the IUPAC naming system differ from the omega naming system for fatty acids?

    -The IUPAC naming system is systematic and based on the position of the first double bond and the length of the carbon chain, while the omega naming system focuses on the position of the first double bond from the end of the chain, which is more relevant for essential fatty acids.

  • Why is it important to distinguish between essential and non-essential fatty acids?

    -It is important to distinguish between essential and non-essential fatty acids because only essential fatty acids must be obtained from diet, and their deficiency can lead to health problems, whereas non-essential fatty acids can be synthesized by the body.

Outlines

00:00

🌿 Understanding Essential Fatty Acids

The script introduces the concept of essential fatty acids (EFAs), distinguishing them from other unsaturated fatty acids. EFAs are crucial for health as the body cannot synthesize them and must obtain them through diet. The video explains the importance of EFAs, such as linoleic and alpha-linolenic acids, which are classified as omega-6 and omega-3 fatty acids, respectively. These acids are vital for preventing health issues ranging from mild to severe. The script also touches on the topic of essential amino acids, which are similarly indispensable and must be ingested through diet.

05:01

🔬 Nomenclature and Classification of Fatty Acids

This section delves into the naming conventions of fatty acids, highlighting the difference between common names and the systematic nomenclature as per IUPAC. The script explains how the position of the first double bond in the carbon chain determines the classification of fatty acids as omega-3 or omega-6. It also clarifies that while all three mentioned fatty acids (oleic, linoleic, and alpha-linolenic) are unsaturated, only linoleic and alpha-linolenic are essential. The video script uses examples to illustrate how the IUPAC naming system works, emphasizing that the position of the double bond relative to the carboxyl group is key in this naming convention.

Mindmap

Keywords

💡Essential Fatty Acids (EFAs)

Essential Fatty Acids (EFAs) are a class of fats that are crucial for human health but cannot be synthesized by the body, hence they must be obtained through diet. In the video, EFAs are highlighted as vital nutrients that, if not consumed, can lead to health issues ranging from mild to severe. Examples given include linoleic acid and alpha-linolenic acid, which are types of polyunsaturated fats.

💡Polyunsaturated Fats

Polyunsaturated fats are a type of unsaturated fat with more than one double bond in their fatty acid chain. They are important for health and are found in foods like nuts, seeds, and fish. The video script distinguishes between polyunsaturated fats and essential fatty acids, noting that while all EFAs are polyunsaturated, not all polyunsaturated fats are essential.

💡Linoleic Acid

Linoleic acid is an omega-6 fatty acid that is essential for human health as it cannot be produced by the body and must be obtained from the diet. It plays a role in brain function, as well as in maintaining the skin and hair. The video emphasizes that linoleic acid is one of the EFAs that should be included in one's diet.

💡Alpha-Linolenic Acid

Alpha-linolenic acid is an omega-3 fatty acid, which is also essential and must be obtained through diet. It is important for brain development and heart health. The video script mentions alpha-linolenic acid as another key EFA that the body cannot synthesize.

💡Omega-6 Fatty Acids

Omega-6 fatty acids are a group of polyunsaturated fats that are essential for the body. They are named so because the first double bond appears at the sixth carbon atom from the end of the carbon chain. Linoleic acid is an example of an omega-6 fatty acid, which the video script discusses as an essential component of a healthy diet.

💡Omega-3 Fatty Acids

Omega-3 fatty acids are another group of essential polyunsaturated fats where the first double bond is at the third carbon atom from the end of the carbon chain. Alpha-linolenic acid is an example of an omega-3 fatty acid, which the video script highlights as crucial for various bodily functions.

💡Insaturation

Insaturation refers to the presence of one or more double bonds in the fatty acid chain, which means the fat is not fully saturated with hydrogen atoms. Unsaturated fats, including EFAs, are important for health and are discussed in the video as they relate to the structure and health benefits of fats.

💡IUPAC Nomenclature

The International Union of Pure and Applied Chemistry (IUPAC) nomenclature is a systematic method of naming chemical compounds. In the context of the video, IUPAC nomenclature is used to officially name fatty acids, with examples provided such as oleic acid and linoleic acid, to distinguish their structures and positions of double bonds.

💡Acid Names

The video script provides examples of common and IUPAC names for fatty acids, such as 'oleic acid' and 'linoleic acid'. These names are important for understanding the scientific literature and for identifying the types of fats in dietary sources.

💡Dietary Intake

Dietary intake is a central theme in the video, emphasizing the need to consume essential fatty acids through food sources. The discussion revolves around how the lack of EFAs in the diet can lead to health problems, underscoring the importance of a balanced diet that includes these nutrients.

💡Health Implications

The video discusses the health implications of not consuming essential fatty acids, which can range from mild to severe health issues. This highlights the critical role of EFAs in maintaining overall health and the importance of understanding dietary requirements.

Highlights

Essential fatty acids are crucial and must be ingested through diet as the body cannot synthesize them.

Non-essential fatty acids can be produced by the body, whereas essential fatty acids must be obtained from diet.

Deficiency in essential fatty acids can lead to health problems ranging from mild to severe.

Examples of polyunsaturated essential fatty acids include linoleic acid and alpha-linolenic acid.

Linoleic acid is also known as omega-6, and alpha-linolenic acid as omega-3.

Arachidonic acid, another polyunsaturated fatty acid, contains 20 carbons, unlike linoleic and alpha-linolenic which contain 18.

The naming convention for fatty acids includes systematic IUPAC nomenclature and the omega nomenclature.

The IUPAC nomenclature starts the numbering from the end of the carbon chain nearest to the carboxyl group.

Omega nomenclature is based on the position of the first double bond from the end of the carbon chain.

Linoleic acid is an omega-6 fatty acid because the first double bond is at the sixth carbon.

Alpha-linolenic acid is an omega-3 fatty acid because the first double bond is at the third carbon.

Oleic acid is a monounsaturated fatty acid and is not considered essential as the body can synthesize it.

The distinction between essential and non-essential fatty acids is important for understanding their dietary requirements.

The transcript provides a detailed explanation of the chemical structure and naming of fatty acids.

Understanding the difference between IUPAC and omega nomenclature is crucial for identifying essential fatty acids.

The importance of including essential fatty acids in the diet to prevent health issues is emphasized.

The transcript serves as an educational resource for understanding the role of fatty acids in health and nutrition.

Transcripts

play00:07

pues bueno hoy hablaremos sobre ácidos

play00:09

grasos esenciales

play00:12

voy a hacer una distinción o diferencia

play00:14

entre esenciales y ácidos grasos

play00:18

insaturados

play00:19

[Música]

play00:22

vamos a empezar con la definición de

play00:24

ácidos grasos esenciales ok bueno los

play00:28

ácidos grasos esenciales llamados así

play00:31

por su importancia y sobre todo porque

play00:35

deben necesariamente ingerirse en la

play00:39

dieta debido a la incapacidad de nuestro

play00:43

organismo para sintetizar los

play00:47

por eso son esenciales

play00:50

hay ácidos grasos que nosotros ingerimos

play00:53

en la dieta

play00:55

y ácidos grasos que nuestro cuerpo

play00:58

fabrica

play01:00

entonces a aquellos ácidos grasos que

play01:04

nuestro cuerpo no puede fabricar y que

play01:06

son importantes para nosotros van a ser

play01:10

llamados esenciales lo cual quiere decir

play01:13

que solo los podemos obtener de la dieta

play01:17

de lo que consumimos

play01:19

también van a encontrar cuando toquemos

play01:22

el tema de proteínas que también hay

play01:24

aminoácidos esenciales es decir

play01:27

aminoácidos que nuestro cuerpo no puede

play01:29

fabricar y que los tiene que consumir

play01:33

necesariamente en la dieta así que aquí

play01:36

también hay ácidos grasos que si no los

play01:39

consumimos en la dieta

play01:41

van a ocasionar los problemas desde

play01:44

leves hasta graves

play01:47

ok

play01:49

bueno

play01:51

continuamos entonces

play01:56

su deficiencia se traduce en un

play01:58

padecimiento o mal funcionamiento del

play02:01

organismo lo que les acabo de mencionar

play02:04

algunos ejemplos de estos ácidos grasos

play02:07

poliinsaturados son el linoleico y el

play02:13

alfa linolénico no confundir estos

play02:16

nombres linoleico y linolénico

play02:22

no no puse aquí un ácido graso que se

play02:25

llama araquidónico

play02:28

estos dos como vamos a ver adelante

play02:30

contienen 18 carbonos el ácido

play02:35

araquidónico contiene 20 ok

play02:41

estos

play02:43

reciben otro nombre debido a otra forma

play02:48

de nombrarlos que ahorita les voy a

play02:49

explicar omega 6 sería el linoleico y

play02:54

omega 3 sería el linolénico

play02:59

el araquidónico

play03:02

también está dentro de los poli

play03:06

insaturados

play03:08

ok pero ahorita no sabe la diferencia

play03:11

entre ácidos grasos insaturados o

play03:14

poliinsaturados y los que son esenciales

play03:17

estos dos son esenciales es decir

play03:21

nuestro cuerpo no va a producir nunca el

play03:23

omega 6 y omega 3

play03:28

esa fue la definición veamos la

play03:31

estructura

play03:33

este cuadro lo tienen este en su

play03:38

en su manual recuerden que está basada

play03:41

esta clase en la página 30 eso decía al

play03:43

principio el índice no

play03:45

este y lo van a tener este cuadro dice

play03:48

ácidos grasos insaturados no dice

play03:52

esenciales

play03:54

porque aquí tenemos la instauración sin

play03:58

numerados la cadena comenzando por el

play04:00

extremo izquierdo

play04:03

aquí la insaculación se presenta en el

play04:05

carbono número 9

play04:07

si comenzamos

play04:09

en el caso del siguiente ácido la

play04:13

enumeración por el lado izquierdo la

play04:16

instauración la primera se va a

play04:18

presentar en el carbono 6 aunque que hay

play04:21

otra

play04:22

en esta nomenclatura que vamos a ver de

play04:24

los omegas tomando en cuenta en que

play04:27

carbono

play04:29

se presenta el primer doble enlace o in

play04:33

saturación en este tercero está en el 3

play04:37

bueno

play04:39

esta nomenclatura

play04:42

se usa poco exclusivamente lo usan para

play04:46

los ácidos grasos esenciales pero la

play04:50

nomenclatura

play04:52

oficial sistemática o de la iupac

play04:56

es la que vamos a ver ahorita bueno por

play05:01

ejemplo este ácido

play05:05

que el nombre común es oleico el nombre

play05:09

de la iupac es este nombre hoy te lo voy

play05:12

a decir porque se llama así

play05:16

en de la nomenclatura de yuca comienza

play05:19

con el número uno aquí en este carbono

play05:22

uno dos tres cuatro cinco seis siete

play05:26

ocho y nueve 9 coincidió con la

play05:32

numeración de acá ok

play05:34

coincidió pero para la iupac este es el

play05:38

carbono principal

play05:40

el que incluye el grupo car box y lo

play05:43

esto lo vimos ayer por lo tanto la

play05:45

insaculación está en el carbono número 9

play05:48

aquí empieza por eso se le pone tengo la

play05:51

palabra ácido luego 9 es donde está

play05:54

el doble enlace

play05:56

optar de seno opta de acá no es 18 pero

play06:02

como es un al que no por doble enlace

play06:04

termina en que no pero como eres un

play06:08

ha sido debe terminar en icod

play06:13

si no en hoy con el nombre sería ácido 9

play06:18

opta de seno y con eso es el nombre de

play06:23

la iupac bueno eso éste

play06:28

no va a ser muy importante para esta

play06:31

clase porque esto vimos algo en el

play06:36

segundo semestre

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pero nombre como un ácido oleico

play06:40

cuál es el nombre de la pac de este

play06:43

ácido

play06:44

así 2 912 opta de cada día

play06:51

bien porque tiene dos dobles enlaces ok

play06:56

uno en el nueve y otro en el 12

play07:00

el nombre común ácido linoléico

play07:05

y este ácido que está acá el último

play07:07

llamado ácido alfa linolénico

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el nombre de la iupac es ácido 9 12 15

play07:18

opta de katrien hoy ccoo

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bueno

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estos nombres pudieron apantallar y

play07:27

asombrar a algunos pero es fácil

play07:30

ponerlos cuando ya conoce las reglas

play07:32

pero bueno si alguien va para química

play07:35

verá que que luego dar nombre a estos

play07:38

compuestos no es tan complicado pero

play07:41

porque puse este este cuadro

play07:45

puse tres ejemplos pero vean que

play07:48

solamente el segundo y el tercero se les

play07:52

aplica la nomenclatura de omega

play07:56

porque es omega-6 porque el doble enlace

play08:01

en saturación está en el carbono 6

play08:04

por eso son mega 6 no importan los demás

play08:08

y este se llama omega 3 porque la

play08:12

instauración está en el carbono 3

play08:14

comenzando la numeración

play08:17

a la inversa de la iupac ok estos 2

play08:22

son esenciales

play08:25

el ácido oleico no es esencial

play08:31

recuerden si les pregunto menciones dos

play08:35

ácidos grasos esenciales aquí está el

play08:41

ácido linoleico y el ácido alfa

play08:44

linolénico

play08:46

no les explico está por que alfano

play08:49

si este con que pongan ácido linolénico

play08:55

y ácido linoléico pues bueno ya habrán

play09:00

mencionado los dos ácidos grasos

play09:02

esenciales este no es esencial este lo

play09:06

puede fabricar o sintetizar nuestro

play09:09

organismo

play09:11

es la diferencia los tres son

play09:13

insaturados pero sólo dos son esenciales

play09:17

[Música]

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الوسوم ذات الصلة
Fatty AcidsEssential NutrientsDiet ImportanceHealth BenefitsOmega-6Omega-3Linoleic AcidAlpha-Linolenic AcidNutritional ChemistryWellness Education
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